Mass concentration and ion composition of coarse and fine particles in an urban area in Beirut: effect of calcium carbonate on the absorption of nitric and sulfuric acids and the depletion of chloride

International audienceLevels of coarse (PM10-2.5) and fine (PM2.5) particles were determined between February 2004 and January 2005 in the city of Beirut, Lebanon. While low PM mass concentrations were measured in the rainy season, elevated levels were detected during sand storms originating from Arabian desert and/or Africa. Using ATR-FTIR and IC, it was shown that nitrate, sulfate, carbonate and chloride were the main anionic constituents of the coarse particles, whereas sulfate was mostly predominant in the fine particles in the form of (NH4)2SO4. Ammonium nitrate was not expected to be important because the medium was defined as ammonium poor. In parallel, the cations Ca2+ and Na+ dominated in the coarse, and NH4+, Ca2+ and Na+ in the fine particles. Coarse nitrate and sulfate ions resulted from the respective reactions of nitric and sulfuric acid with a relatively high amount of calcium carbonate. Both CaCO3 and Ca(NO3)2 crystals identified by ATR-FTIR in the coarse particles were found to be resistant to soaking in water for 24 h but became water soluble when they were formed in the fine particles suggesting, thereby, different growth and adsorption phenomena. The seasonal variational study showed that nitrate and sulfate ion concentrations increased in the summer due to the enhancement of photochemical reactions which facilitated the conversion of NO2 and SO2 gases into NO3- and SO42-, respectively. While nitrate was mainly due to local heavy traffic, sulfates were due to local and long-range transport phenomena. Using the air mass trajectory HYSPLIT model, it was found that the increase in the sulfate concentration correlated with wind vectors coming from Eastern and Central Europe. Chloride levels, on the other hand, were high when wind originated from the sea and low during sand storms. In addition to sea salt, elevated levels of chloride were also attributed to waste mass burning in proximity to the site. In comparison to other neighboring Mediterranean countries, relatively higher concentrations of calcium in Beirut were good indication of calcitic crustal abundance. Considering the importance of the health and climate impacts of aerosols locally and regionally, this study constitutes a point of reference for eastern Mediterranean transport modeling studies and local regulatory and policy makers

Determination of the scope of the experimental-calculation method for measuring the touch voltage

The work is devoted to the improvement of methods for determining the normalized parameters of the grounding system (GS) of operating power stations and substations. The aim of the work is determination of the scope of the experimental-calculated method for measuring the touch voltage, depending on short-circuit (SC) current value for the given dimensions of the GS and the type of soil. Methodology. The study analyzed the non-linear effect of the SC current value on the touch voltage, taking into account such factors as the GS size and the soil type. The calculation used statistical data on the GS size and the characteristics of the soil obtained by monitoring the GS state of 585 operating electrical substations with a voltage class of 110-750 kV using the induction method and the method of vertical soil sounding, respectively. For the calculation, a mathematical model of a non-equipotential GS located in a three-layer semiconductor space with plane-parallel boundaries was used, this model was developed using the method of integro-differential equations. Results. To determine the scope of the method, in this work it is proposed to use the linearity criterion, which is determined due to the ratio of the constant of reduced touch voltage to the current value. The example shows the method for determining the threshold minimum and maximum values of the measuring current of the soil, in the range between which the measurements by experimental-calculated methods are impossible. A table of threshold current values has been formed and recommendations have been developed on the possibility of using experimental-measuring methods for determining the touch voltage depending on the GS size and soil characteristics.Метою роботи є визначення області застосування експериментально-розрахункового методу вимірювання напруги дотику в залежності від значення струму короткого замикання для заданих розмірів заземлювального пристрою (ЗП) та типу ґрунту. В дослідженні було проаналізовано нелінійний вплив величини струму КЗ на напругу дотику з урахуванням таких факторів як розмір ЗП та тип ґрунту. Для розрахунку була використана математична модель нееквіпотенційного ЗП, розташованого у тришаровому напівпровідному просторі з плоско-паралельними границями поділу, що була розроблена за допомогою методу інтегро-диференційних рівнянь. Для визначення області застосування методу в роботі запропоновано використовувати критерій лінійності, який визначається через відношення сталої приведеної напруги дотику до поточного значення. Сформовано таблицю значень порогових струмів та розроблено рекомендації щодо можливості використання експериментально-вимірювальних методів визначення напруги дотику в залежності від розміру ЗП та характеристик ґрунту

Method of integro-differential equations for interpreting the results of vertical electrical sounding of the soil

The paper is devoted to the problem of determining the geoelectric structure of the soil within the procedure of testing the grounding arrangements of existing power plants and substations to the required depth in conditions of dense development. To solve the problem, it was proposed to use the Schlumbergers method , which has a greater sounding depth compared to the Wenner electrode array. The purpose of the work is to develop a mathematical model for interpreting the results of soil sounding by the Schlumberger method in the form of a four-layer geoelectric structure. Methodology. To construct a mathematical model, it is proposed to use the solution of a particular problem about the field of a point current source, which, like the observation point, is located in the first layer of a four-layer soil. Based on this expressions, a system of linear algebraic equations of the 7-th order with respect to the unknown coefficients ai and bi was compiled. On the basis of its analytical solution, an expression for the potential of the electric field was obtained for conducting VES (the point current source and the observation point are located only on the soil surface). Results. Comparison of the results of soil sounding by the Schlumberger installation and the interpretation of its results for the same points shows a sufficient degree of approximation: the maximum relative error does not exceed 9.7 % (for the second point), and the average relative error is 3.6 %. Originality. Based on the obtained expression, a test version of the program was implemented in Visual Basic for Applications to interpret the results of VES by the Schlumberger method. To check the obtained expressions, the interpretation of the VES results was carried out on the territory of a 150 kV substation of one of the mining and processing plants in the city of Kriviy Rih. Practical significance. The developed mathematical model will make it possible to increase the sounding depth, and, consequently, the accuracy of determining the standardized parameters of the grounding arrangements of power stations and substations.Робота присвячена проблематиці визначення геоелектричної структури ґрунту в межах випробування заземлювальних пристроїв діючих електричних станцій та підстанцій на необхідну глибину в умовах щільної забудови. Для вирішення проблеми запропоновано використати установку Шлюмберже, яка має більшу глибину зондування у порівнянні з установкою Веннера. За допомогою методів інтегро-диференційних рівнянь було отримано аналітичні вирази для інтерпретації результатів зондування ґрунту установкою Шлюмберже у випадку чотиришарового ґрунту. Для перевірки отриманих виразів була проведена інтерпретація результатів вертикального електричного зондування на території підстанції 150 кВ одного з гірничо-збагачувальних комбінатів: максимальна відносна похибка не перевищує 9,7 %, а середня – 3,6 %

Monolithic CIGS-Perovskite Tandem Cell for an Optimal Light Harvesting Without Current Matching

We present a novel monolithic architecture for optimal light harvesting in multijunction thin film solar cells. In the configuration we consider, formed by a perovskite (PVK) cell overlying a CIGS cell, the current extracted from the two different junctions is decoupled by the insertion of a dielectric nonperiodic photonic multilayer structure. This photonic multilayer is designed by an inverse integration approach to confine the incident sunlight above the PVK band gap in the PVK absorber layer, while increasing the transparency for sunlight below the PVK band gap for an efficient coupling into the CIGS bottom cell. To match the maximum power point voltages in a parallel connection of the PVK and CIGS cells, the latter is divided into two subcells by means of a standard three-laser scribing connection. Using realistic parameters for all the layers in the multijunction architecture we predict power conversion efficiencies of 28%. This represents an improvement of 24% and 26% over the best CIGS and PVK single-junction cells, respectively, while at the same time outperforms the corresponding current-matched standard tandem configuration by more than two percentage points.Peer ReviewedPostprint (author's final draft

Simulation of electromagnetic processes in the grounding system with a short circuit in the operating high-voltage substation

The aim of the work is a test of the developed mathematical model of electromagnetic processes of short circuit and approbation of the created software complex «LiGro» on its basis for the existing grounding system located in three-layer soil. Methodology. To improve the accuracy of calculating the normalized parameters of operating power stations and substations, the authors developed the «LiGro» software package based on the expressions obtained in for calculating the potential of the electric field of a non-equipotential grounding system (GS). To monitor the state and assess the efficiency of the GS of operating power facilities, the electromagnetic diagnostics is used. The topology of the GS was determined with the induction method by complex KNTR-1, the geoelectric structure of the soil was determined by the method of vertical electrical sounding using the Wenner installation, the interpretation of the sounding results was made by the «VEZ-4A» program. The calculation results show that for the selected substation, the model developed in the «LiGro» complex has a deviation δ2 from the experimental values Ut by an average of 8,2 %, and the model implemented in Grounding 1.0 (IEEE model) δ1 is 17,2 %. Originality. The results of the study confirm the adequacy of the developed GS model in the «LiGro» complex based on a three-layer soil model, with the experimental values of the touch voltage obtained by simulating a single-phase ground fault on a real GS in operation. The first time was made approbation of the «LiGro» software package when performing the EMD of the GS of an operating substation with a voltage class of 150 kV. Practical significance. The program software can be used by special measuring’s laboratory to determining electrical safety parameters: touch voltage, GS voltage, and GS resistance. Метою роботи є перевірка розробленої математичної моделі електромагнітних процесів короткого замикання та апробація створеного програмного комплексу «LiGro на її основі для існуючого заземлювального пристрою (ЗП), який розташовано в тришаровому ґрунті. Перевірка практичного застосування була виконана на діючий підстанції класом напруги 150 кВ з використанням вдосконаленої методики електромагнітної діагностики. Топологія ЗП була визначена індукційним методом за допомогою приладу KNTR-1, параметри ґрунту визначені чотириелектродною симетричною установкою за схемою Веннера методом вертикального електричного зондування, інтерпретація результатів зондування виконана спеціалізованою програмою VEZ-4A. Результати порівняння розрахунку показують, що для обраної підстанції модель розроблена в комплексі LiGro має відхилення від експериментальних значень в середньому на 8,2 %, а модель реалізована в Grounding 1.0 (IEEE model) – 17,2 %. Виконано розрахунок нормованих параметрів ЗП в режимі короткого замикання: напругу дотику, опір ЗП та напругу на ЗП. Встановлено, що вони не перевищують допустимого значення. Проаналізовано переваги розрахункового комплексу у порівнянні з аналогами. Отримані результати дозволяють виконати повномасштабне впровадження програмного комплексу в діагностику стану ЗП.&nbsp