3,497 research outputs found
Enhancing the patient involvement in outcomes: a study protocol of personalised outcome measurement in the treatment of substance misuse
Involving patients in treatment is becoming increasingly popular in mental health [Sales & Alves:
Personalized evaluation of psychological treatments: A review of tools and research designs, submitted]. However,
in substance misuse treatment settings, the patient perspective about treatment tends to be overlooked. This has
been cited as a key priority by Orford et al. [Addiction, 103: 875-885, 2008] who included patient feedback about
treatment as one of ten areas requiring an urgent paradigm shift in addiction research and practice.
This project will apply an innovative method to involve substance misuse patients in psychological therapies, by
asking them to suggest topics to evaluate their treatment. These topics suggested by patients can be written as a
list of personalised items, so-called as patient-generated outcome measures (PGOM). Despite its patient-friendly
features, PGOM’s have never been used in this population, which is what this project aims to overcome
Evidence for entanglement at high temperatures in an engineered molecular magnet
The molecular compound
[Fe(-oxo)(CHN)(CO)]
was designed and synthesized for the first time and its structure was
determined using single-crystal X-ray diffraction. The magnetic susceptibility
of this compound was measured from 2 to 300 K. The analysis of the
susceptibility data using protocols developed for other spin singlet
ground-state systems indicates that the quantum entanglement would remain at
temperatures up to 732 K, significantly above the highest entanglement
temperature reported to date. The large gap between the ground state and the
first-excited state (282 K) suggests that the spin system may be somewhat
immune to decohering mechanisms. Our measurements strongly suggest that
molecular magnets are promising candidate platforms for quantum information
processing
Possible mechanism for achieving glass-like thermal conductivities in crystals with off-center atoms
In the filled Ga/Ge clathrate, Eu and Sr are off-center in site 2 but Ba is
on-center. All three filler atoms (Ba,Eu,Sr) have low temperature Einstein
modes; yet only for the Eu and Sr systems is there a large dip in the thermal
conductivity, attributed to the Einstein modes. No dip is observed for Ba. Here
we argue that it is the off-center displacement that is crucial for
understanding this unexplained difference in behavior. It enhances the coupling
between the "rattler" motion and the lattice phonons for the Eu and Sr systems,
and turns on/off another scattering mechanism (for 1K < T < 20K) produced by
the presence/absence of off-center sites. The random occupation of different
off-center sites produces a high density of symmetry-breaking defects which
scatters phonons. It may also be important for improving our understanding of
other glassy systems.Comment: 4 pages, 1 figure (2 parts) -- v2: intro broadened; strengthened
arguments regarding need for additional phonon scattering mechanis
Thermoelectric properties of Co, Ir, and Os-Doped FeSi Alloys: Evidence for Strong Electron-Phonon Coupling
The effects of various transition metal dopants on the electrical and thermal
transport properties of Fe1-xMxSi alloys (M= Co, Ir, Os) are reported. The
maximum thermoelectric figure of merit ZTmax is improved from 0.007 at 60 K for
pure FeSi to ZT = 0.08 at 100 K for 4% Ir doping. A comparison of the thermal
conductivity data among Os, Ir and Co doped alloys indicates strong
electron-phonon coupling in this compound. Because of this interaction, the
common approximation of dividing the total thermal conductivity into
independent electronic and lattice components ({\kappa}Total =
{\kappa}electronic + {\kappa}lattice) fails for these alloys. The effects of
grain size on thermoelectric properties of Fe0.96Ir0.04Si alloys are also
reported. The thermal conductivity can be lowered by about 50% with little or
no effect on the electrical resistivity or Seebeck coefficient. This results in
ZTmax = 0.125 at 100 K, still about a factor of five too low for solid-state
refrigeration applications
Rejuvenation in the Random Energy Model
We show that the Random Energy Model has interesting rejuvenation properties
in its frozen phase. Different `susceptibilities' to temperature changes, for
the free-energy and for other (`magnetic') observables, can be computed
exactly. These susceptibilities diverge at the transition temperature, as
(1-T/T_c)^-3 for the free-energy.Comment: 9 pages, 1 eps figur
Anisotropic thermal expansion of Fe1.06Te and FeTe0.5Se0.5 single crystals
Heat capacity and anisotropic thermal expansion was measured for Fe1.06Te and
FeTe0.5Se0.5 single crystals. Previously reported phase transitions are clearly
seen in both measurements. In both cases the thermal expansion is anisotropic.
The uniaxial pressure derivatives of the superconducting transition temperature
in FeTe0.5Se0.5 inferred from the Ehrenfest relation have opposite signs for
in-plane and c-axis pressures. Whereas the Gruneisen parameters for both
materials are similar and only weakly temperature-dependent above ~ 80 K, at
low temperatures (in the magnetically ordered phase) the magnetic contribution
to the Gruneisen parameter in Fe1.06Te is significantly larger than electron
and phonon contributions combined
Four-well tunneling states and elastic response of clathrates
We present resonant ultrasound elastic constant measurements of the clathrate
compounds Eu8Ga16Ge30 and Sr8Ga16Ge30. The elastic response of the Eu clathrate
provides clear evidence for the existence of a new type of four-well tunneling
states, described by two nearly degenerate four level systems (FLS). The FLS's
are closely linked with the fourfold split positions of Eu known from neutron
diffraction density profiles. Using a realistic potential we estimate the
tunneling frequencies and show that the energy gap between the two FLS's is of
the same order as the Einstein oscillator frequency. This explains why the
observed harmonic oscillator type specific heat is not modified by tunneling
states. In addition the quadrupolar interaction of FLS's with elastic strains
explains the pronounced depression observed in elastic constant measurements.
In the case of the Sr clathrate, we show that the shallow dip in the elastic
constant c44 is explained using the same type of quadrupolar interaction with a
soft Einstein mode instead of a FLS.Comment: 4 pages, 4 figures; accepted for publication in Physical Review
Letter
Optical study of interactions in a d-electron Kondo lattice with ferromagnetism
We report on a comprehensive optical, transport and thermodynamic study of
the Zintl compound YbMnSb, demonstrating that it is the first
ferromagnetic Kondo lattice compound in the underscreened limit. We propose a
scenerio whereby the combination of Kondo and Jahn-Teller effects provides a
consistent explanation of both transport and optical data.Comment: 4 page
Charge Order Superstructure with Integer Iron Valence in Fe2OBO3
Solution-grown single crystals of Fe2OBO3 were characterized by specific
heat, Mossbauer spectroscopy, and x-ray diffraction. A peak in the specific
heat at 340 K indicates the onset of charge order. Evidence for a doubling of
the unit cell at low temperature is presented. Combining structural refinement
of diffraction data and Mossbauer spectra, domains with diagonal charge order
are established. Bond-valence-sum analysis indicates integer valence states of
the Fe ions in the charge ordered phase, suggesting Fe2OBO3 is the clearest
example of ionic charge order so far.Comment: 4 pages, 5 figures. Fig. 3 is available in higher resolution from the
authors. PRL in prin
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