182 research outputs found
Joint Resource Allocation for eICIC in Heterogeneous Networks
Interference coordination between high-power macros and low-power picos
deeply impacts the performance of heterogeneous networks (HetNets). It should
deal with three challenges: user association with macros and picos, the amount
of almost blank subframe (ABS) that macros should reserve for picos, and
resource block (RB) allocation strategy in each eNB. We formulate the three
issues jointly for sum weighted logarithmic utility maximization while
maintaining proportional fairness of users. A class of distributed algorithms
are developed to solve the joint optimization problem. Our framework can be
deployed for enhanced inter-cell interference coordination (eICIC) in existing
LTE-A protocols. Extensive evaluation are performed to verify the effectiveness
of our algorithms.Comment: Accepted by Globecom 201
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New technologies accelerate the exploration of non-coding RNAs in horticultural plants.
Non-coding RNAs (ncRNAs), that is, RNAs not translated into proteins, are crucial regulators of a variety of biological processes in plants. While protein-encoding genes have been relatively well-annotated in sequenced genomes, accounting for a small portion of the genome space in plants, the universe of plant ncRNAs is rapidly expanding. Recent advances in experimental and computational technologies have generated a great momentum for discovery and functional characterization of ncRNAs. Here we summarize the classification and known biological functions of plant ncRNAs, review the application of next-generation sequencing (NGS) technology and ribosome profiling technology to ncRNA discovery in horticultural plants and discuss the application of new technologies, especially the new genome-editing tool clustered regularly interspaced short palindromic repeat (CRISPR)/CRISPR-associated protein 9 (Cas9) systems, to functional characterization of plant ncRNAs
Correlating Heteroatoms Doping, Electronic Structures, and Photocatalytic Activities of Single‐Atom‐Doped Ag25(SR)18 Nanoclusters
Atomic‐level manipulation of catalysts is important for both fundamental studies and practical applications. Here, the central metal atom in an atomically precise Ag25 nanocluster (NC) is replaced with a single Pd, Pt, and Au atom, respectively, and employed as a model system to study the structure–property–activity relationship at the atomic level. While the geometric structures are well‐preserved after doping, the electronic structures of Ag25 NCs are significantly altered. The combination of Ag25 and TiO2 enhances the charge separation at the interface, exhibiting a 10 times higher hydrogen production rate in photocatalytic hydrogen evolution reaction compared to bare TiO2. Further results show that heteroatoms doping has a negative impact on performance, particularly in the cases of Pd and Au doping. Ultraviolet photoelectron spectroscopy measurements and density functional theory calculations suggest that the lower activities are due to an energy mismatch between the levels of doped NCs and TiO2. These findings not only reveal the impact of heteroatoms doping on the electronic properties and photocatalytic activities of NCs, but can also guide the design of heterometallic NCs for photocatalytic applications
Correlating Heteroatoms Doping, Electronic Structures, and Photocatalytic Activities of Single‐Atom‐Doped Ag25(SR)18 Nanoclusters
Atomic‐level manipulation of catalysts is important for both fundamental studies and practical applications. Here, the central metal atom in an atomically precise Ag25 nanocluster (NC) is replaced with a single Pd, Pt, and Au atom, respectively, and employed as a model system to study the structure–property–activity relationship at the atomic level. While the geometric structures are well‐preserved after doping, the electronic structures of Ag25 NCs are significantly altered. The combination of Ag25 and TiO2 enhances the charge separation at the interface, exhibiting a 10 times higher hydrogen production rate in photocatalytic hydrogen evolution reaction compared to bare TiO2. Further results show that heteroatoms doping has a negative impact on performance, particularly in the cases of Pd and Au doping. Ultraviolet photoelectron spectroscopy measurements and density functional theory calculations suggest that the lower activities are due to an energy mismatch between the levels of doped NCs and TiO2. These findings not only reveal the impact of heteroatoms doping on the electronic properties and photocatalytic activities of NCs, but can also guide the design of heterometallic NCs for photocatalytic applications.Heteroatoms doping alters the electronic structures of Ag25 nanoclusters (NCs), while keeping the geometric structures unchanged. In this way, the geometrical effects and the electronic effects are clearly distinguished. The photocatalytic activities of as‐prepared NCs deposited onto TiO2 are investigated. The performances follow the order of Ag25 ≥ PtAg24 > PdAg24 ≥ AuAg24.
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© 2023 WILEY‐VCH GmbHDFG
http://dx.doi.org/10.13039/501100001659China Scholarship Council
http://dx.doi.org/10.13039/501100004543Peer Reviewe
Laser-Like Emission from a Sandwiched MoTe2 Heterostructure on a Silicon Single-Mode Resonator
Molybdenum ditelluride (MoTe2) has recently shown promise as a gain material for silicon photonics. Reliable single-mode operation and material stability remain two of the major issues that need to be addressed to advance this exciting technology, however. Here, laser-like emission from a sandwiched MoTe2 heterostructure on a silicon single-mode resonator is reported. The heterostructure consists of a layer of MoTe2 sandwiched between thin films of hexagonal boron nitride. It is known that tellurium compounds are sensitive to oxygen exposure, which leads to rapid degradation of the exposed layers in air. By encapsulating the MoTe2 gain material, much improved environmental stability is observed. Using a recently introduced single-mode resonator design, better control over the mode spectrum of the cavity is exercised and single-mode operation with a wide free spectral range is demonstrated. At room temperature, a Q-factor of 4500 and a threshold of 4.2 kW cm−2 at 1319 nm wavelength are achieved. These results lend further support to the paradigm of 2D material-based integrated light sources on the silicon platform
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Light-responsive expression atlas reveals the effects of light quality and intensity in Kalanchoë fedtschenkoi, a plant with crassulacean acid metabolism.
BackgroundCrassulacean acid metabolism (CAM), a specialized mode of photosynthesis, enables plant adaptation to water-limited environments and improves photosynthetic efficiency via an inorganic carbon-concentrating mechanism. Kalanchoë fedtschenkoi is an obligate CAM model featuring a relatively small genome and easy stable transformation. However, the molecular responses to light quality and intensity in CAM plants remain understudied.ResultsHere we present a genome-wide expression atlas of K. fedtschenkoi plants grown under 12 h/12 h photoperiod with different light quality (blue, red, far-red, white light) and intensity (0, 150, 440, and 1,000 μmol m-2 s-1) based on RNA sequencing performed for mature leaf samples collected at dawn (2 h before the light period) and dusk (2 h before the dark period). An eFP web browser was created for easy access of the gene expression data. Based on the expression atlas, we constructed a light-responsive co-expression network to reveal the potential regulatory relationships in K. fedtschenkoi. Measurements of leaf titratable acidity, soluble sugar, and starch turnover provided metabolic indicators of the magnitude of CAM under the different light treatments and were used to provide biological context for the expression dataset. Furthermore, CAM-related subnetworks were highlighted to showcase genes relevant to CAM pathway, circadian clock, and stomatal movement. In comparison with white light, monochrome blue/red/far-red light treatments repressed the expression of several CAM-related genes at dusk, along with a major reduction in acid accumulation. Increasing light intensity from an intermediate level (440 μmol m-2 s-1) of white light to a high light treatment (1,000 μmol m-2 s-1) increased expression of several genes involved in dark CO2 fixation and malate transport at dawn, along with an increase in organic acid accumulation.ConclusionsThis study provides a useful genomics resource for investigating the molecular mechanism underlying the light regulation of physiology and metabolism in CAM plants. Our results support the hypothesis that both light intensity and light quality can modulate the CAM pathway through regulation of CAM-related genes in K. fedtschenkoi
Association between long-term exposure to wildfire-related PM2.5 and mortality:A longitudinal analysis of the UK Biobank
Efficient Silicon Metasurfaces for Visible Light
Dielectric metasurfaces require high refractive index contrast materials for optimum performance. This requirement imposes a severe restraint; either devices have been demonstrated at wavelengths of 700 nm and above using high-index semiconductors such as silicon, or they use lower index dielectric materials such as TiO2 or Si3N4 and operate in the visible wavelength regime. Here, we show that the high refractive index of silicon can be exploited at wavelengths as short as 532 nm by demonstrating a crystalline silicon metasurface with a transmission efficiency of 71% at this wavelength and a diffraction efficiency of 95% into the desired diffraction order. The metasurfaces consist of a graded array of silicon posts arranged in a square lattice on a quartz substrate. We show full 2π phase control, and we experimentally demonstrate polarization-independent beam deflection at 532 nm wavelength. Our results open a new way for realizing efficient metasurfaces based on silicon for the technologically all-important display applications
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