16 research outputs found
Electrical Bearing Damage, A Problem in the Nano- and Macro-Range
Rolling bearings face different damaging effects: Besides mechanical effects, current-induced bearing damage occurs in electrical drive systems. Therefore, it is of increasing interest to understand the differences leading to known electrical damage patterns. It is of utmost importance not to consider the harmful current passage in the machine element as an isolated phenomenon but to take into account the whole drive system consisting of the machine elements, the electric motor and the connected power electronics. This publication works toward providing an overview of the state-of-the-art of research regarding electrical bearing currents
Flame retardant polyester by combination of organophosphorus compounds and an NOR radical forming agent
Electrical Bearing Damage, A Problem in the Nano- and Macro-Range
Rolling bearings face different damaging effects: Besides mechanical effects, current-induced bearing damage occurs in electrical drive systems. Therefore, it is of increasing interest to understand the differences leading to known electrical damage patterns. It is of utmost importance not to consider the harmful current passage in the machine element as an isolated phenomenon but to take into account the whole drive system consisting of the machine elements, the electric motor and the connected power electronics. This publication works toward providing an overview of the state-of-the-art of research regarding electrical bearing currents
Flame retardant polyester by combination of organophosphorus compounds and an NOR radical forming agent
Polymer materials with different surface-to-volume ratios require different mechanisms of flame retardants regarding condensed phase and gas phase activity. The flame retardant formulations in poly(ethylene terephthalate) (PET) are investigated regarding a condensed phase and gas phase activity by using thermogravimetric analysis (TGA), TG-mass spectrometry (MS), TG-Fourier transform infrared (FTIR), UL94, cone calorimeter and scanning electron microscopy–energy-dispersive X-ray spectrometer measurements. The flame retardant formulations containing phosphates, phosphonates, and phosphinates as flame retardants are analyzed by using a simultaneous analysis consisting of a differential thermal analysis-TGA device which is in situ coupled to FTIR and MS. All analysis methods show a gas phase activity for the phosphonate (PCO 910), a condensed phase activity for the phosphate (3,9-bis(phenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro-5,5-undecane-3,9-dioxide, (SPDPP) and a mixed condensed and gas phase activity for the new synthesized phosphate and 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide containing flame retardant 3,9-bis(phenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro-5,5-undecane-3,9-dioxide (SPDPDOM). The fire behavior of PCO 910 can be improved by adding O,O'-Terephthaloyl-bis-N,N'-naphthalimide ester as NOR radical-forming agent (NOR-RF) reaching a total amount of 3 wt % of both active agents for a UL94 V-0 classification in PET
Synthesis of [Fe(Leq)(Lax)]n coordination polymer nanoparticles using blockcopolymer micelles
Spin-crossover compounds are a class of materials that can change their spin state from high spin (HS) to low spin (LS) by external stimuli such as light, pressure or temperature. Applications demand compounds with defined properties concerning the size and switchability that are maintained when the compound is integrated into composite materials. Here, we report the synthesis of [Fe(Leq)(Lax)]n coordination polymer (CP) nanoparticles using self-assembled polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) block copolymer (BCP) micelles as template. Variation of the solvent (THF and toluene) and the rigidity of the axial ligand Lax (Lax = 1,2-di(pyridin-4-yl)ethane) (bpea), trans-1,2-di(pyridin-4-yl)ethene (bpee), and 1,2-di(pyridin-4-yl)ethyne) (bpey); Leq = 1,2-phenylenebis(iminomethylidyne)-bis(2,4-pentanedionato)(2−)) allowed the determination of the preconditions for the selective formation of nanoparticles. A low solubility of the CP in the used solvent and a high stability of the Fe–L bond with regard to ligand exchange are necessary for the formation of composite nanoparticles where the BCP micelle is filled with the CP, as in the case of the [FeLeq(bpey)]n@BCP. Otherwise, in the case of more flexible ligands or ligands that lead to high spin complexes, the formation of microcrystals next to the CP–BCP nanoparticles is observed above a certain concentration of [Fe(Leq)(Lax)]n. The core of the nanoparticles is about 45 nm in diameter due to the templating effect of the BCP micelle, independent of the used iron complex and [Fe(Leq)(Lax)]n concentration. The spin-crossover properties of the composite material are similar to those of the bulk for FeLeq(bpea)]n@BCP while pronounced differences are observed in the case of [FeLeq(bpey)]n@BCP nanoparticles
Investigation of the Voltage-Induced Damage Progression on the Raceway Surfaces of Thrust Ball Bearings
In the course of the electrification of powertrains, rolling element bearings are increasingly subject to electrical damage. In contrast to mechanically generated pittings, voltage-induced surface damage is a continuous process. Though several approaches for the description of the damage state of a bearing are known, a generally accepted quantification for the bearing damage has not been established yet. This paper investigates surface properties, which can be used as a metric damage scale for the quantification of the electric bearing damage progression. For this purpose, the requirements for suitable surface properties are defined. Afterwards, thrust ball bearings are installed on a test rig, with constantly loaded mechanically and periodically damaged electrically in multiple phases. After each phase, the bearings are disassembled, the bearing surfaces are graded and measured for 45 different standardized surface properties. These properties are evaluated with the defined requirements. For the ones meeting the requirements, critical levels are presented, which allow for a quantified distinction between grey frosting and corrugation surfaces. These values are compared with measurements presented in the literature showing that the identified surface properties are suitable for the quantification of electrical bearing damages
Photonic composite materials from cellulose nanorods and clay nanolayers
Cellulose nano crystals (CNCs) are promising materials for energy efficient buildings related to the control of reflectivity and heat absorption/reflection of light. In this sense it is important to improve CNCs films fire retardant properties, which can be achieved by adding clays. Cellulose nanocrystals (CNCs) and nanolayers obtained from Sodium Fluorohectorite (NaFh) synthetic clay are both known to form liquid crystalline phases in aqueous suspensions. CNCs form cholesteric phases, which structure is preserved after water evaporation, while dry NaFh nanolayers aligned films collapse. In this initial work, it is shown that CNCs are compatible with NaFh clay. We demonstrate that the liquid crystalline phase of CNCs in water is not destroyed by the presence of NaFh nanolayers. The NaFh nanolayers act as planar anchoring surfaces to the cellulose nanorods and, after evaporation of the water coloured films are obtained. The precursor solutions and the photonic films were investigated by Describe several techniques
Electrical Bearing Damage, A Problem in the Nano- and Macro-Range
Rolling bearings face different damaging effects: Besides mechanical effects, current-induced bearing damage occurs in electrical drive systems. Therefore, it is of increasing interest to understand the differences leading to known electrical damage patterns. It is of utmost importance not to consider the harmful current passage in the machine element as an isolated phenomenon but to take into account the whole drive system consisting of the machine elements, the electric motor and the connected power electronics. This publication works toward providing an overview of the state-of-the-art of research regarding electrical bearing currents