Feasibility experiments on time-resolved fluorosensing applied to oil slicks

The introduction of time resolved observations can provide a very penetrating tool in the practice of laser fluorosensing. The investigations have demonstrated a relevance of multispectral, time resolved analysis for oil fingerprinting. By comparative studies on a variety of crude oils and their most significant fractions, it was found that the process of time decay in a composite oil is characterized by a few steps, which are associated with specific components in the medium light range. The average decay times of these pure fractions are markedly differentiated as to absolute values and spectral spread; as a consequence, the corresponding parameters in the resultant crude are quite sensitive to the particular mixture of these components. Measurements of the time response give then a finer discrimination between oil classes, depending on the relative content of certain fractions. Experiments were pursued with an improved fluorosensor facility, in order to test the application of time resolved fluorosensing to remote samples on water

Instability of toroidal nematics

Toroidal nematics are nematic liquid crystals confined within a circular torus and subject to planar degenerate anchoring on the boundary of the torus. They may be droplets floating in an isotropic environment or cavities carved out of a solid substrate. A universal solution of Frank's elastic free energy is an equilibrium configuration for the nematic director field, irrespective of the values of the elastic constants, whose vector lines are the coaxial parallels of the torus. We explore the local stability of this configuration and identify a range of parameters where the main drive towards instability does not come from the surface-like elastic constant $K_{24}$ being large, but from the the ratio $K_2/K_3$ of the twist to bend elastic constants being small, which also makes our study relevant to chromonic liquid crystals

Relieving nematic geometric frustration in the plane

Frustration in nematic ordered media (endowed with a director field) is treated in a purely geometric fashion in a flat, two-dimensional space. We recall the definition of quasi-uniform distortions and envision these as viable ways to relieve director fields prescribed on either a straight line or the unit circle. We prove that the only way to fill the whole plane with a quasi-uniform distortion is by means of a planar spiral. Apart from that, all relieving quasi-uniform distortions can at most be defined in a half-plane; however, in a generic sense, they are all asymptotically spirals

Towards the Perfect X-ray Beam Splitter

X-ray free-electron lasers (FEL) deliver ultrabright X-ray pulses, but not the sequences of phase-coherent pulses required for time-domain interferometry and control of quantum states. For conventional split-and-delay schemes to produce such sequences the challenge stems from extreme stability requirements when splitting Angstrom wavelength beams where tiniest path length differences introduce phase jitter. We describe an FEL mode based on selective electron bunch degradation and transverse beam shaping in the accelerator, combined with a self-seeded photon emission scheme. Instead of splitting the photon pulses after their generation by the FEL, we split the electron bunch in the accelerator, prior to photon generation, to obtain phase-locked X-ray pulses with sub-femtosecond duration. Time-domain interferometry becomes possible, enabling the concomitant program of classical and quantum optics experiments with X-rays. The scheme leads to new scientific benefits of cutting-edge FELs with attosecond and/or high-repetition rate capabilities, ranging from the X-ray analog of Fourier transform infrared spectroscopy to damage-free measurements

Biological Control of the Chagas Disease Vector Triatoma infestans with the Entomopathogenic Fungus Beauveria bassiana Combined with an Aggregation Cue: Field, Laboratory and Mathematical Modeling Assessment

Background: Current Chagas disease vector control strategies, based on chemical insecticide spraying, are growingly threatened by the emergence of pyrethroid-resistant Triatoma infestans populations in the Gran Chaco region of South America. Methodology and findings: We have already shown that the entomopathogenic fungus Beauveria bassiana has the ability to breach the insect cuticle and is effective both against pyrethroid-susceptible and pyrethroid-resistant T. infestans, in laboratory as well as field assays. It is also known that T. infestans cuticle lipids play a major role as contact aggregation pheromones. We estimated the effectiveness of pheromonebased infection boxes containing B. bassiana spores to kill indoor bugs, and its effect on the vector population dynamics. Laboratory assays were performed to estimate the effect of fungal infection on female reproductive parameters. The effect of insect exuviae as an aggregation signal in the performance of the infection boxes was estimated both in the laboratory and in the field. We developed a stage-specific matrix model of T. infestans to describe the fungal infection effects on insect population dynamics, and to analyze the performance of the biopesticide device in vector biological control. Conclusions: The pheromone-containing infective box is a promising new tool against indoor populations of this Chagas disease vector, with the number of boxes per house being the main driver of the reduction of the total domestic bug population. This ecologically safe approach is the first proven alternative to chemical insecticides in the control of T. infestans. The advantageous reduction in vector population by delayedaction fungal biopesticides in a contained environment is here shown supported by mathematical modeling.Fil: Forlani, Lucas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Bioquímicas de La Plata ; ArgentinaFil: Pedrini, Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Bioquímicas de La Plata ; ArgentinaFil: Girotti, Juan Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Bioquímicas de La Plata ; ArgentinaFil: Mijailovsky, Sergio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Bioquímicas de La Plata ; ArgentinaFil: Cardozo, Rubén Marino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Patología Experimental. Universidad Nacional de Salta. Facultad de Ciencias de la Salud. Instituto de Patología Experimental; Argentina. Provincia de Salta. Ministerio de Salud Pública. Coordinación de Gestión Epidemiológica; ArgentinaFil: Gentile, Alberto G.. Provincia de Salta. Ministerio de Salud Pública. Coordinación de Gestión Epidemiológica; ArgentinaFil: Hernández Suárez, Carlos. Universidad de Colima. Facultad de Ciencias; MéxicoFil: Rabinovich, Jorge Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Estudios Parasitológicos y de Vectores. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo. Centro de Estudios Parasitológicos y de Vectores; ArgentinaFil: Juarez, Marta Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Bioquímicas de La Plata ; Argentin

Location of the Energy Levels of the Rare-Earth Ion in BaF2 and CdF2

The location of the energy levels of rare-earth (RE) elements in the energy band diagram of BaF2 and CdF2 crystals is determined. The role of RE3+ and RE2+ ions in the capture of charge carriers, luminescence, and the formation of radiation defects is evaluated. It is shown that the substantial difference in the luminescence properties of BaF2:RE and CdF2:RE is associated with the location of the excited energy levels in the band diagram of the crystals

Invasive Crayfish moving Northwards: management challenges and policy implications at the local scale

Freshwater ecosystems in Italy, as most European countries, have been severely impacted by the invasion of alien crayfish. The two most widespread species in Trentino (NE Italy) are Procambarus clarkii and Faxionus limosus; for both species, the high elevation and cold climate of most of the Trentino territory represent a climatic barrier to their northwards spread. Procambarus clarkii is present in one small lake at 950 m asl, and Faxionus limosus in a group of 5 lakes at 450 m asl, over an area of about 80km2. the introduction of both species is associated with fish restocking, and lead to the extinction of existing populations of the native stone crayfish Austropotamobius pallipes. The Management Plan of Austropotamobius pallipes in Trentino listed the eradication/containment of these IAS populations among the conservation priorities for the native populations. The eradication campaigns of P. clarkii started in 2018 with a release/recapture campaign aimed at assessing the abundance of the populations, and continued in 2020, 2021, 2022. As a result, the capture efficiency decreased, suggesting a population reduction trend. The containment of Faxionus limosus is more difficult, given its presence in a higher number of lakes, three of which are hydrologically connected. A first containment campaign to prevent its spread in the river network is planned for summer 2023. The financial support to these activities has been granted by the local Nature 2000 networks and by the local administrations, which have also promoted the communication with citizens and stakeholders to raise consensus and collaboratio

Optimization of mid-dilution haemodiafiltration: technique and performance

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