Electronic Supporting Information from The <i>in situ</i> synthesis of PbS nanocrystals from lead(II) <i>n</i>-octylxanthate within a 1,3-diisopropenylbenzene–bisphenol A dimethacrylate sulfur copolymer

Further results from the sulfur polymer synthesis and the sulfur polymer-nanocrystal films from NMR, DSC, photography, powder XRD, XPS, EDX, SAED and UV-vis

Evidence for chromatic X-ray light-curve breaks in Swift gamma-ray burst afterglows and their theoretical implications

The power-law decay of the X-ray emission of gamma-ray burst (GRB) afterglows 050319, 050401, 050607, 050713A, 050802 and 050922C exhibits a steepening at about 1–4 h after the burst which, surprisingly, is not accompanied by a break in the optical emission. If it is assumed that both the optical and X-ray afterglows arise from the same outflow then, in the framework of the standard forward shock model, the chromaticity of the X-ray light-curve breaks indicates that they do not arise solely from a mechanism related to the outflow dynamics (e.g. energy injection) or the angular distribution of the blast-wave kinetic energy (structured outflows or jets). The lack of a spectral evolution accompanying the X-ray light-curve break shows that these breaks do not arise from the passage of a spectral break (e.g. the cooling frequency) either. Under these circumstances, the decoupling of the X-ray and optical decays requires that the microphysical parameters for the electron and magnetic energies in the forward shock evolve in time, whether the X-ray afterglow is synchrotron or inverse-Compton emission. For a steady evolution of these parameters with the Lorentz factor of the forward shock and an X-ray light curve arising cessation of energy injection into the blast wave, the optical and X-ray properties of the above six Swift afterglows require a circumburst medium with a r−2 radial stratification, as expected for a massive star origin for long GRBs. Alternatively, the chromatic X-ray light-curve breaks may indicate that the optical and X-ray emissions arise from different outflows. Neither feature (evolution of microphysical parameters or the different origin of the optical and X-ray emissions) was clearly required by pre-Swift afterglows

The Soft X-ray Imager (SXI) on-board the THESEUS mission

We summarize in this contribution the capabilities, design status, and the en- abling technologies of the Soft X-ray Imager (SXI) planned to be on-board the THESEUS mission. We describe its central role in making THESEUS a powerful machine to probe the physical conditions of the early Universe (close to the reionization era) and to explore the time-domain Universe

Cherenkov Telescope Array is well suited to follow up gravitational-wave transients

The first gravitational-wave (GW) observations will greatly benefit from the detection of coincident electromagnetic counterparts. Electromagnetic follow-ups will nevertheless be challenging for GWs with poorly reconstructed directions. GW source localization can be inefficient (i) if only two GW observatories are in operation; (ii) if the detectors’ sensitivities are highly non-uniform; (iii) for events near the detectors’ horizon distance. For these events, follow-up observations will need to cover 100–1000 deg−2 of the sky over a limited period of time, reducing the list of suitable telescopes. We demonstrate that the Cherenkov Telescope Array (CTA) will be capable of following up GW event candidates over the required large sky area with sufficient sensitivity to detect short gamma-ray bursts, which are thought to originate from compact binary mergers, out to the horizon distance of advanced LIGO/Virgo. CTA can therefore be invaluable starting with the first multimessenger detections, even with poorly reconstructed GW source directions. This scenario also provides a further scientific incentive for GW observatories to further decrease the delay of their event reconstruction

The nature of the outflow in gamma-ray bursts

The Swift satellite has enabled us to follow the evolution of gamma-ray burst (GRB) fireballs from the prompt γ-ray emission to the afterglow phase. The early-time X-ray and optical data for GRBs obtained by telescopes aboard the Swift satellite show that the source for prompt γ-ray emission, the emission that heralds these bursts, is short lived, and is distinct from the source for the long-lived afterglow emission that follows the initial burst. Using these data we determine the distance of the γ-ray source from the centre of the explosion. We find this distance to be 1015–1016 cm for most bursts, and show that this is within a factor of about 10 of the radius of the shock heated circumstellar medium (CSM) producing the X-ray photons. Furthermore, using the early γ-ray, X-ray and optical data we show that the prompt gamma-ray emission cannot be produced in internal shocks nor can it be produced in the external shock; in a more general sense γ-ray generation mechanisms based on shock physics have problems explaining the GRB data for ten Swift bursts analyzed in this work. A magnetic field dominated outflow model for GRBs has a number of attractive features, although evidence in its favour is inconclusive. Finally, the X-ray and optical data allow us to provide an upper limit on the density of the CSM of about 10 protons cm−3 at a distance of ∼5 × 1016 cm from the centre of explosion

GRB 050410 and GRB 050412: Are they really dark gamma-ray bursts?

Aims.We present a detailed analysis of the prompt and afterglow emission of GRB 050410 and GRB 050412 detected by Swift for which no optical counterpart was observed. Methods.We analysed data from the prompt emission detected by the Swift BAT and from the early phase of the afterglow obtained by the Swift narrow field instrument XRT. Results.The 15-150 keV energy distribution of the GRB 050410 prompt emission shows a peak energy at 53 -21+40 keV. The XRT light curve of this GRB decays as a power law with a slope of $\alpha=$ 1.06 $\pm$ 0.04. The spectrum is well reproduced by an absorbed power law with a spectral index $\Gamma_{\rm x}=2.4$ $\pm$ 0.4 and a low energy absorption $N_{\rm H}$ = 4 +3-2 $\times$ 1021 cm-2 which is higher than the Galactic value. The 15-150 keV prompt emission in GRB 050412 is modelled with a hard ($\Gamma$ = 0.7 $\pm$ 0.2) power law. The XRT light curve follows a broken power law with the first slope $\alpha_1$ = 0.7 $\pm$ 0.4, the break time $T_{\rm break}$ = 254 -41+79 s and the second slope $\alpha_2$ = 2.8 -0.8+0.5. The spectrum is fitted by a power law with spectral index $\Gamma_{\rm x}=1.3$ $\pm$ 0.2 which is absorbed at low energies by the Galactic column. Conclusions.The GRB 050410 afterglow light curve reveals the expected characteristics of the third component of the canonical Swift light curve. Conversely, a complex phenomenology was detected in the GRB 050412 because of the presence of the very early break. The light curve in this case can be interpreted as being the last peak of the prompt emission. The two bursts present tight upper limits for the optical emission, however, neither of them can be clearly classified as dark. For GRB 050410, the suppression of the optical afterglow could be attributed to a low density interstellar medium surrounding the burst. For GRB 050412, the evaluation of the darkness is more difficult due to the ambiguity in the extrapolation of the X-ray afterglow light curve

The Infra-Red Telescope on board the THESEUS mission

The Infra-Red Telescope (IRT) on board the Transient High Energy Sky and Early Universe Surveyor (THESEUS) ESA M5 candidate mission will play a key role in identifying and characterizing moderate to high redshift Gamma-Ray Bursts afterglows. The IRT is the enabling instrument on board THESEUS for measuring autonomously the redshift of the several hundreds of GRBs detected per year by the Soft X-ray Imager (SXI) and the X- and Gamma-Ray Imaging Spectrometer (XGIS), and thus allowing the big ground based telescopes to be triggered on a redshift pre-selected sample, and finally fulfilling the cosmological goals of the mission. The IRT will be composed by a primary mirror of 0.7 m of diameter coupled to a single camera in a Cassegrain design. It will work in the 0.7-1.8 {\mu}m wavelength range, and will provide a 10x10 arc min imaging field of view with sub-arc second localization capabilities, and, at the same time, a 5x5 arc min field of view with moderate (R up to ~500) spectroscopic capabilities. Its sensitivity, mainly limited by the satellite jitter, is adapted to detect all the GRBs, localized by the SXI/XGIS, and to acquire spectra for the majority of them

THESEUS: a key space mission for Multi-Messenger Astrophysics

The recent discovery of the electromagnetic counterpart of the gravitational wave source GW170817, has demonstrated the huge informative power of multi-messenger observations. During the next decade the nascent field of multi-messenger astronomy will mature significantly. In 2030s, third generation gravitational wave detectors will be roughly ten times more sensitive than the current ones. At the same time, neutrino detectors currently upgrading to multi km^3 telescopes, will include a 10 km^3 facility in the Southern hemisphere that is expected to be operational during the thirties. In this review, we describe the most promising high frequency gravitational wave and neutrino sources that will be detected in the next two decades. In this context, we show the important role of the Transient High Energy Sky and Early Universe Surveyor (THESEUS), a mission concept proposed to ESA by a large international collaboration in response to the call for the Cosmic Vision Programme M5 missions. THESEUS aims at providing a substantial advancement in early Universe science as well as playing a fundamental role in multi-messenger and time-domain astorphysics. It will operate in strong sinergy with future gravitational wave and neutrino detectors as well as major ground- and space-based telescopes. This review is an extension of the THESEUS white paper (Amati et al., 2017), in light of the discovery of GW170817/GRB170817A that was announced on October 16th, 2017

The THESEUS space mission concept: science case, design and expected performances

THESEUS is a space mission concept aimed at exploiting Gamma-Ray Bursts for investigating the early Universe and at providing a substantial advancement of multi-messenger and time-domain astrophysics. These goals will be achieved through a unique combination of instruments allowing GRB and X-ray transient detection over a broad field of view (more than 1sr) with 0.5–1 arcmin localization, an energy band extending from several MeV down to 0.3 keV and high sensitivity to transient sources in the soft X-ray domain, as well as on-board prompt (few minutes) follow-up with a 0.7 m class IR telescope with both imaging and spectroscopic capabilities. THESEUS will be perfectly suited for addressing the main open issues in cosmology such as, e.g., star formation rate and metallicity evolution of the inter-stellar and intra-galactic medium up to redshift ∼10, signatures of Pop III stars, sources and physics of re-ionization, and the faint end of the galaxy luminosity function. In addition, it will provide unprecedented capability to monitor the X-ray variable sky, thus detecting, localizing, and identifying the electromagnetic counterparts to sources of gravitational radiation, which may be routinely detected in the late ’20s/early ’30s by next generation facilities like aLIGO/ aVirgo, eLISA, KAGRA, and Einstein Telescope. THESEUS will also provide powerful synergies with the next generation of multi-wavelength observatories (e.g., LSST, ELT, SKA, CTA, ATHENA)

The Deep and Transient Universe in the SVOM Era: New Challenges and Opportunities - Scientific prospects of the SVOM mission

To take advantage of the astrophysical potential of Gamma-Ray Bursts (GRBs), Chinese and French astrophysicists have engaged the SVOM mission (Space-based multi-band astronomical Variable Objects Monitor). Major advances in GRB studies resulting from the synergy between space and ground observations, the SVOM mission implements space and ground instrumentation. The scientific objectives of the mission put a special emphasis on two categories of GRBs: very distant GRBs at z$>$5 which constitute exceptional cosmological probes, and faint/soft nearby GRBs which allow probing the nature of the progenitors and the physics at work in the explosion. These goals have a major impact on the design of the mission: the on-board hard X-ray imager is sensitive down to 4 keV and computes on line image and rate triggers, and the follow-up telescopes on the ground are sensitive in the NIR. At the beginning of the next decade, SVOM will be the main provider of GRB positions and spectral parameters on very short time scale. The SVOM instruments will operate simultaneously with a wide range of powerful astronomical devices. This rare instrumental conjunction, combined with the relevance of the scientific topics connected with GRB studies, warrants a remarkable scientific return for SVOM. In addition, the SVOM instrumentation, primarily designed for GRB studies, composes a unique multi-wavelength observatory with rapid slew capability that will find multiple applications for the whole astronomy community beyond the specific objectives linked to GRBs. This report lists the scientific themes that will benefit from observations made with SVOM, whether they are specific GRB topics, or more generally all the issues that can take advantage of the multi-wavelength capabilities of SVOM