57 research outputs found

    Calm before the storm? : Modelling military supply and movement

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    Food production and transport infrastructure play a large role in the outcome of a military campaign and the results of failure can have a profound effect on the whole state. Yet these are areas often poorly covered by contemporary sources. The Medieval Warfare on the Grid project is using agent-based modelling to produce quantitative data to examine the mechanisms required to move armies across a pre-industrial landscape. Though focused on the march of the Byzantine army to the Battle of Manzikert in AD1071, the results can improve our understanding of the logistical challenges faced by armies in other periods and places. The use of quantitative data from later sources provides valuable assistance to both design and validation of the models

    Avoided metallicity in a hole-doped Mott insulator on a triangular lattice

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    Charge carrier doping of a Mott insulator is known to give rise to a wide variety of exotic emergent states, from high-temperature superconductivity to various charge, spin, and orbital orders. The physics underpinning their evolution is, however, poorly understood. A major challenge is the chemical complexity associated with traditional routes to the addition or removal of carriers. Here, we study the Mott insulating CrO2_2 layer of the delafossite oxide PdCrO2_2, where an intrinsic polar catastrophe provides a clean route to induce substantial doping of the surface layer. Despite this, from scanning tunneling microscopy and angle-resolved photoemission, we find that the surface retains an insulating character, but with a modified electronic structure and the development of a short-range ordered state with a distinct (7×7)R±19.1∘(\sqrt{7}\times\sqrt{7})\mathrm{R}\pm 19.1^\circ periodicity. From density functional theory, we demonstrate how this reflects the formation of an intricate charge disproportionation that results in an insulating ground state of the surface layer that is disparate from the hidden Mott insulator found in the bulk. By applying voltage pulses to the surface layer, we induce substantial local modifications to this state, which we find relax on a time scale of tens of minutes, pointing to a glassy nature of the charge-disproportionated insulator realised here.Comment: manuscript and supplementary, 37 pages in total, 4 figures in the main text and 9 in the supplementar

    Hierarchy of Lifshitz transitions in the surface electronic structure of Sr2RuO4 under uniaxial compression

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    Funding: We gratefully acknowledge support from the Engineering and Physical Sciences Research Council (Grant Nos. EP/T02108X/1 and EP/R031924/1), the European Research Council (through the QUESTDO project, 714193), and the Leverhulme Trust (Grant No. RL-2016-006). E.A.M., A.Z., and I.M. gratefully acknowledge studentship support from the International Max-Planck Research School for Chemistry and Physics of Quantum Materials. N.K. is supported by a KAKENHI Grants-in-Aids for Scientific Research (Grant Nos.18K04715, and 21H01033), and Core-to-Core Program (No. JPJSCCA20170002) from the Japan Society for the Promotion of Science (JSPS) and by a JST-Mirai Program (Grant No. JPMJMI18A3). APM and CWH acknowledge support from the Deutsche Forschungsgemeinschaft - TRR 435 288 - 422213477 (project A10). We thank Diamond Light Source for access to Beamline I05 (Proposals SI27471 and SI28412), which contributed to the results presented here.We report the evolution of the electronic structure at the surface of the layered perovskiteSr2RuO4 under large in-plane uniaxial compression, leading to anisotropic B1g strains of Δxx − Δyy = −0.9 ± 0.1%. From angle-resolved photoemission, we show how this drives a sequence of Lifshitz transitions, reshaping the low-energy electronic structure and the rich spectrum of van Hove singularities that the surface layer of Sr2RuO4 hosts. From comparison to tight-binding modelling, we find that the strain is accommodated predominantly by bond-length changes rather than modifications of octahedral tilt and rotation angles. Our study sheds new light on the nature of structural distortions at oxide surfaces, and how targeted control of these can be used to tune density of states singularities to the Fermi level, in turn paving the way to the possible realisation of rich collective states at the Sr2RuO4 surface.PostprintPeer reviewe

    Giant valley-Zeeman coupling in the surface layer of an intercalated transition metal dichalcogenide

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    Funding: We gratefully acknowledge support from the Leverhulme Trust (Grant No. RL-2016-006 [P.D.C.K., B.E., T.A., A.R., C.B.]), the European Research Council (through the QUESTDO project, 714193 [P.D.C.K., G.R.S.]), the Engineering and Physical Sciences Research Council (Grant Nos. EP/T02108X/1 [P.D.C.K., P.A.E.M.] and EP/N032128/1 [D.A.M., G.B.]), and the Center for Computational Materials Science at the Institute for Materials Research for allocations on the MASAMUNE-IMR supercomputer system (Project No. 202112-SCKXX-0510 [R.B.V., M.S.B.]). S.B., E.A.M. and A.Z. gratefully acknowledge studentship support from the International Max-Planck Research School for Chemistry and Physics of Quantum Materials. Research conducted at MAX IV, a Swedish national user facility, is supported by the Swedish Research council under contract 2018-07152, the Swedish Governmental Agency for Innovation Systems under contract 2018-04969, and Formas under contract 2019-02496. The research leading to this result has been supported by the project CALIPSOplus under the Grant Agreement 730872 from the EU Framework Programme for Research and Innovation HORIZON 2020.Spin–valley locking is ubiquitous among transition metal dichalcogenides with local or global inversion asymmetry, in turn stabilizing properties such as Ising superconductivity, and opening routes towards ‘valleytronics’. The underlying valley–spin splitting is set by spin–orbit coupling but can be tuned via the application of external magnetic fields or through proximity coupling. However, only modest changes have been realized to date. Here, we investigate the electronic structure of the V-intercalated transition metal dichalcogenide V1/3NbS2 using microscopic-area spatially resolved and angle-resolved photoemission spectroscopy. Our measurements and corresponding density functional theory calculations reveal that the bulk magnetic order induces a giant valley-selective Ising coupling exceeding 50 meV in the surface NbS2 layer, equivalent to application of a ~250 T magnetic field. This energy scale is of comparable magnitude to the intrinsic spin–orbit splittings, and indicates how coupling of local magnetic moments to itinerant states of a transition metal dichalcogenide monolayer provides a powerful route to controlling their valley–spin splittings.PostprintPeer reviewe
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