Raman spectroscopy of BN-SWNTs

We present results on the vibrational properties of BN-SWNTs together with a study of the synthesis material by transmission electron microscopy. Phonon modes have been investigated by Raman spectroscopy with laser excitation wavelengths in the range from 363.8 to 676.44 nm. The assignment of the modes is guided by ab-initio calculations

Magnetic and magneto-optical properties of Mn\u3csub\u3e\u3ci\u3ex\u3c/i\u3e\u3c/sub\u3ePt\u3csub\u3e1–\u3ci\u3ex–y\u3c/i\u3e\u3c/sub\u3eZn\u3csub\u3e\u3ci\u3ey\u3c/i\u3e\u3c/sub\u3e

In this work we have prepared thin films of the ternary alloy MnxPt1–x–yZny by magnetron sputtering onto quartz substrates. We have found a wide range of compositions which are strongly ferromagnetic at room temperature. A transition from a cubic to tetragonal phase with decreasing Pt content is confirmed by x-ray diffraction. X-ray diffraction measurements also show a strong (001) reflection consistent with long range order along the c axis for the tetragonal phase. These films show large complex Kerr rotations (up to 0.7°) in the visible spectrum. This combined with their anisotropic structure suggests that they may be suitable for magneto-optic data storage applications

Re-treatment of whale bones - How to extract degraded fats from weakened bones?

International audience"Many whale (baleen whale or toothed whale) skeletons still contain residual lipids even after an initial osteological preparation. This paper examines the different possibilities of re-treatment. Before a conservation intervention, it was necessary to determine the materials of which bones are made up. The samples were analyzed by Raman spectroscopy. Different compounds were identified: a mineral part (apatite), an organic part (collagen) and lipids. Chromatography analysis yielded a detailed composition of the lipids. It was in fact degraded fat with saturated and unsaturated fatty acids. To remove these lipids, several techniques were identified and tested: enzymatic treatments, supercritical CO2, and green or organic solvents. Esterification catalyzed by lipases could be suitable for a degreasing treatment since the solubility of esters is higher than that of the corresponding fatty acids. The enzymatic treatment acted only on the surface and did not appear to be very efficient. The use of supercritical CO2 was even less effective. Some green solvents can partially extract lipids but prove difficult to eliminate after treatment. The best results for degreasing were achieved using organic solvents. Different solutions were evaluated at hot or ambient temperature and in simple immersion or with agitation (Soxhlet or pulsed pressure): hexane, heptane, a mixture of hexane/isopropanol, or an azeotropic mixture of methanol/chloroform. Only the mixture of methanol/chloroform succeeded in extracting the overall fat content, but this treatment degraded the organic part of the bones. The other organic solvents extracted mainly colored fat, which generally corresponded to a weight loss of 20 to 50%. The majority of fat was extracted during the first bath. Thus the treatment selected is that of immersion in heptane at ambient temperature. The degreasing of whole bones is less effective because of the film of sticky degraded fat on the bone's surface. A pre-cleaning is necessary to eliminate this film.

Crystal structure and chemical bonding in the mixed anion compound BaSF

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Grafting Polymers on Surfaces: A New Powerful and Versatile Diazonium Salt-Based One-Step Process in Aqueous Media

International audienceCovalent surface modification of conductive, semiconductive, and insulating substrates with thin organic polymers films induced by redox activation of aryl diazonium salts in the presence of vinyl monomers has been investigated in acidic aqueous media. This new process, called diazonium-induced anchoring process (DIAP), is an efficient technique to impart covalent adhesion of polyvinyl coatings onto raw inorganic or organic surfaces without any conductivity requirement. Typically, aryl diazonium salts are reduced with iron powder to give surface-active aryl radicals leading (i) to the formation of a grafted polyphenylene-like film on the substrate surface and (ii) to the initiation of the radical polymerization of the vinylic monomer in solution. The resulting radical-terminated macromolecular chains formed in solution are then able to react with the polyphenylene primer layer to form a very homogeneous thin organic film on the surface. The final organic thin coating is strongly grafted on materials surfaces, as evidenced by its persistence after a long ultrasonic treatment in a good solvent of the polymer. We speculate this process is supported by the large concentration of aryl and hydrogen radicals formed when iron powder is added in the acidic aqueous solution. The thickness of the polymer film can be controlled as a function of time, typically a few minutes, and was measured between 10 and several hundred nanometers. Infrared reflection–absorption spectroscopy (IRRAS), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and contact angle measurements were used to characterize the surface modification of metals, glass, carbon nanotubes, or polytetrafluoroethylene (PTFE). This very simple and efficient grafting method provides a powerful tool for the covalent coating of organic or inorganic surfaces possessing complex geometrical shapes

Preferred attachment of fluorine near oxygen-containing groups on the surface of double-walled carbon nanotubes

Two samples of double-walled carbon nanotubes (DWCNTs), one with well-graphitized nanotube walls and another containing oxygen at outer nanotube surfaces, were fluorinated at room temperature using gaseous BrF3. The products were comprehensively studied using transmission electron microscopy, Raman scattering, X-ray photoelectron, and near-edge X-ray absorption fine structure spectroscopies. The experimental data found twice the concentration of sidewall fluorine in the oxygenated DWCNTs. Quantum chemical modeling supported the experimental results revealing the preferable development of CF areas near the carbon atoms bonded with oxygen-containing groups. This observation demonstrates that tuning of the physical and chemical properties of carbon nanotubes can be achieved via the controlled co-modification by fluorine and oxygen functional groups

JNJ-42756493 is an inhibitor of FGFR-1, 2, 3 and 4 with nanomolar affinity for targeted therapy

Manuscrito. -- 1 h.; papel; folio. -- Fondo Universidad de Salamanca; sección Claustros; serie Borradores de claustros. -- Buena conservación. -- Fechas: 11/08/1788