1,501 research outputs found
A condition on delay for differential equations with discrete state-dependent delay
Parabolic differential equations with discrete state-dependent delay are
studied. The approach, based on an additional condition on the delay function
introduced in [A.V. Rezounenko, Differential equations with discrete
state-dependent delay: uniqueness and well-posedness in the space of continuous
functions, Nonlinear Analysis: Theory, Methods and Applications, 70 (11)
(2009), 3978-3986] is developed. We propose and study a state-dependent
analogue of the condition which is sufficient for the well-posedness of the
corresponding initial value problem on the whole space of continuous functions
. The dynamical system is constructed in and the existence of a compact
global attractor is proved
Reduced minimax filtering by means of differential-algebraic equations
A reduced minimax state estimation approach is proposed for high-dimensional models. It is based on the reduction of the ordinary differential equation with high state space dimension to the low-dimensional Differential-Algebraic Equation (DAE) and on the subsequent application of the minimax state estimation to the resulting DAE
Whole genome evaluation of horizontal transfers in the pathogenic fungus Aspergillus fumigatus
<p>Abstract</p> <p>Background</p> <p>Numerous cases of horizontal transfers (HTs) have been described for eukaryote genomes, but in contrast to prokaryote genomes, no whole genome evaluation of HTs has been carried out. This is mainly due to a lack of parametric methods specially designed to take the intrinsic heterogeneity of eukaryote genomes into account. We applied a simple and tested method based on local variations of genomic signatures to analyze the genome of the pathogenic fungus <it>Aspergillus fumigatus</it>.</p> <p>Results</p> <p>We detected 189 atypical regions containing 214 genes, accounting for about 1 Mb of DNA sequences. However, the fraction of atypical DNA detected was smaller than the average amount detected in the same conditions in prokaryote genomes (3.1% vs 5.6%). It appeared that about one third of these regions contained no annotated genes, a proportion far greater than in prokaryote genomes. When analyzing the origin of these HTs by comparing their signatures to a home made database of species signatures, 3 groups of donor species emerged: bacteria (40%), fungi (25%), and viruses (22%). It is to be noticed that though inter-domain exchanges are confirmed, we only put in evidence very few exchanges between eukaryotic kingdoms.</p> <p>Conclusions</p> <p>In conclusion, we demonstrated that HTs are not negligible in eukaryote genomes, bearing in mind that in our stringent conditions this amount is a floor value, though of a lesser extent than in prokaryote genomes. The biological mechanisms underlying those transfers remain to be elucidated as well as the biological functions of the transferred genes.</p
Electron states of mono- and bilayer graphene on SiC probed by STM
We present a scanning tunneling microscopy (STM) study of a
gently-graphitized 6H-SiC(0001) surface in ultra high vacuum. From an analysis
of atomic scale images, we identify two different kinds of terraces, which we
unambiguously attribute to mono- and bilayer graphene capping a C-rich
interface. At low temperature, both terraces show
quantum interferences generated by static impurities. Such interferences are a
fingerprint of -like states close to the Fermi level. We conclude that the
metallic states of the first graphene layer are almost unperturbed by the
underlying interface, in agreement with recent photoemission experiments (A.
Bostwick et al., Nature Physics 3, 36 (2007))Comment: 4 pages, 3 figures submitte
Single 3 transition metal atoms on multi-layer graphene systems: electronic configurations, bonding mechanisms and role of the substrate
The electronic configurations of Fe, Co, Ni, and Cu adatoms on graphene and
graphite have been studied by x-ray magnetic circular dichroism and charge
transfer multiplet theory. A delicate interplay between long-range interactions
and local chemical bonding is found to influence the adatom equilibrium
distance and magnetic moment. The results for Fe and Co are consistent with
purely physisorbed species having, however, different 3-shell occupancies on
graphene and graphite ( and , respectively). On the other hand,
for the late 3 metals Ni and Cu a trend towards chemisorption is found,
which strongly quenches the magnetic moment on both substrates.Comment: 7 pages, 4 figure
CORSiCA : a Mediterranean atmospheric and oceanographic observatory in Corsica within the framework of HyMeX and ChArMEx
Image potential states as quantum probe of graphene interfaces
Image potential states (IPSs) are electronic states localized in front of a
surface in a potential well formed by the surface projected bulk band gap on
one side and the image potential barrier on the other. In the limit of a
two-dimensional solid a double Rydberg series of IPSs has been predicted which
is in contrast to a single series present in three-dimensional solids. Here, we
confirm this prediction experimentally for mono- and bilayer graphene. The IPSs
of epitaxial graphene on SiC are measured by scanning tunnelling spectroscopy
and the results are compared to ab-initio band structure calculations. Despite
the presence of the substrate, both calculations and experimental measurements
show that the first pair of the double series of IPSs survives, and eventually
evolves into a single series for graphite. Thus, IPSs provide an elegant
quantum probe of the interfacial coupling in graphene systems.Comment: Accepted for publication in New Journal of Physic
Synthesis and Electronic Properties of D–A–D Triads Based on 3-Alkoxy-4-cyanothiophene and Benzothienothiophene Blocks
International audienc
In vitro calcification of chemically functionalized carbon nanotubes
Bone is composed of two phases. The organic phase is made of collagen fibrils assembled in broad fibers acting as a template for mineralization. The mineral phase comprises hydroxyapatite (HAP) crystals grown between and inside the collagen fibers. We have developed a biomimetic material using functionalized carbon nanotubes as scaffold to initiate in vitro mineralization. Biomimetic formation of HAP was performed on single-walled carbon nanotubes (SWCNTs) which have been grafted with carboxylic groups. Two types of nanotubes, HiPco(R) and Carbon Solutions(R), were oxidized via various acidic processes, leading to five different groups of carboxylated nanotubes, fully characterized by physical methods (thermogravimetric analysis, attenuated total reflectance infrared spectroscopy and X-ray photoelectron spectroscopy). All samples were dispersed in ultra-pure water and incubated for 2weeks in a synthetic body fluid, in order to induce the calcification of the SWCNTs. Scanning electron microscopy (SEM) and energy-dispersive X-ray analysis studies showed that Ca(2+) and PO(4)(3-) ions were deposited as round-shaped nodules (calcospherites) on the carboxylated SWCNTs. Fourier transform infrared and Raman spectroscopic studies confirmed the HAP formation, and image analysis made on SEM pictures showed that calcospherites and carboxylated SWCNTs were packed together. The size of calcospherites thus obtained in vitro from the HiPco(R) series was close to that issued from calcospherites observed in vivo. Functionalization of SWCNTs with carboxylic groups confers the capacity to induce calcification similar to woven bone
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