534 research outputs found
Probing the Electronic Structure of Bilayer Graphene by Raman Scattering
The electronic structure of bilayer graphene is investigated from a resonant
Raman study using different laser excitation energies. The values of the
parameters of the Slonczewski-Weiss-McClure model for graphite are measured
experimentally and some of them differ significantly from those reported
previously for graphite, specially that associated with the difference of the
effective mass of electrons and holes. The splitting of the two TO phonon
branches in bilayer graphene is also obtained from the experimental data. Our
results have implications for bilayer graphene electronic devices.Comment: 4 pages, 4 figure
Hydrogen trapping by VC precipitates and structural defects in a high strength Fe-Mn-C steel studied by small-angle neutron scattering
The trapping of hydrogen by VC precipitates and structural defects in high strength Fe-Mn-C steel was studied by small angle neutron scattering. No interaction between H and V in solid solution has been detected but a significant interaction between H and structural defects introduced by plastic deformation has been measured. This last effect was reversible upon outgassing of the H. Moreover a significant interaction between H and VC precipitates has been measured; 5 ppm wt. of H could be trapped in the precipitates. This is consistent with the homogeneous trapping of H within the precipitates rather than at the precipitate/matrix interface
Internal stresses in steel plate generated by shape memory alloy inserts
Neutron strain scanning was employed to investigate the internal stress fields in steel plate coupons with embedded prestrained superelastic NiTi shape memory alloy inserts. Strain fields in steel were evaluated at T = 21 °C and 130 °C on virgin coupons as well as on mechanically and thermally fatigued coupons. Internal stress fields were evaluated by direct calculation of principal stress components from the experimentally measured lattice strains as well as by employing an inverse finite element modeling approach. It is shown that if the NiTi inserts are embedded into the elastic steel matrix following a carefully designed technological procedure, the internal stress fields vary with temperature in a reproducible and predictable way. It is estimated that this mechanism of internal stress generation can be safely applied in the temperature range from −20 °C to 150 °C and is relatively resistant to thermal and mechanical fatigue. The predictability and fatigue endurance of the mechanism are of essential importance for the development of future smart metal matrix composites or smart structures with embedded shape memory alloy components
Guidelines of the French Society of Otorhinolaryngology (SFORL), short version. Extension assessment and principles of resection in cutaneous head and neck tumors
AbstractCutaneous head and neck tumors mainly comprise malignant melanoma, squamous cell carcinoma, trichoblastic carcinoma, Merkel cell carcinoma, adnexal carcinoma, dermatofibrosarcoma protuberans, sclerodermiform basalioma and angiosarcoma. Adapted management requires an experienced team with good knowledge of the various parameters relating to health status, histology, location and extension: risk factors for aggression, extension assessment, resection margin requirements, indications for specific procedures, such as lateral temporal bone resection, orbital exenteration, resection of the calvarium and meningeal envelopes, neck dissection and muscle resection
Continuous-distribution puddle model for conduction in trilayer graphene
An insulator-to-metal transition is observed in trilayer graphene based on
the temperature dependence of the resistance under different applied gate
voltages. At small gate voltages the resistance decreases with increasing
temperature due to the increase in carrier concentration resulting from thermal
excitation of electron-hole pairs. At large gate voltages excitation of
electron-hole pairs is suppressed, and the resistance increases with increasing
temperature because of the enhanced electron-phonon scattering. We find that
the simple model with overlapping conduction and valence bands, each with
quadratic dispersion relations, is unsatisfactory. Instead, we conclude that
impurities in the substrate that create local puddles of higher electron or
hole densities are responsible for the residual conductivity at low
temperatures. The best fit is obtained using a continuous distribution of
puddles. From the fit the average of the electron and hole effective masses can
be determined.Comment: 18 pages, 5 figure
Structural correlations in heterogeneous electron transfer at monolayer and multilayer graphene electrodes
As a new form of carbon, graphene is attracting intense interest as an electrode material with widespread applications. In the present study, the heterogeneous electron transfer (ET) activity of graphene is investigated using scanning electrochemical cell microscopy (SECCM), which allows electrochemical currents to be mapped at high spatial resolution across a surface for correlation with the corresponding structure and properties of the graphene surface. We establish that the rate of heterogeneous ET at graphene increases systematically with the number of graphene layers, and show that the stacking in multilayers also has a subtle influence on ET kinetics. © 2012 American Chemical Society
Spin-filtering and charge- and spin-switching effects in a quantum wire with periodically attached stubs
Spin-dependent electron transport in a periodically stubbed quantum wire in
the presence of Rashba spin-orbit interaction (SOI) is studied via the
nonequilibrium Green's function method combined with the Landauer-Buttiker
formalism. The coexistence of spin filtering, charge and spin switching are
found in the considered system. The mechanism of these transport properties is
revealed by analyzing the total charge density and spin-polarized density
distributions in the stubbed quantum wire. Furthermore, periodic spin-density
islands with high polarization are also found inside the stubs, owing to the
interaction between the charge density islands and the Rashba SOI-induced
effective magnetic field. The proposed nanostructure may be utilized to devise
an all-electrical multifunctional spintronic device.Comment: 4 pages, 4 figure
Localization of Dirac electrons by Moire patterns in graphene bilayers
We study the electronic structure of two Dirac electron gazes coupled by a
periodic Hamiltonian such as it appears in rotated graphene bilayers. Ab initio
and tight-binding approaches are combined and show that the spatially periodic
coupling between the two Dirac electron gazes can renormalize strongly their
velocity. We investigate in particular small angles of rotation and show that
the velocity tends to zero in this limit. The localization is confirmed by an
analysis of the eigenstates which are localized essentially in the AA zones of
the Moire patterns.Comment: 4 pages, 5 figure
Oxidation resistance of graphene-coated Cu and Cu/Ni alloy
The ability to protect refined metals from reactive environments is vital to
many industrial and academic applications. Current solutions, however,
typically introduce several negative effects, including increased thickness and
changes in the metal physical properties. In this paper, we demonstrate for the
first time the ability of graphene films grown by chemical vapor deposition to
protect the surface of the metallic growth substrates of Cu and Cu/Ni alloy
from air oxidation. SEM, Raman spectroscopy, and XPS studies show that the
metal surface is well protected from oxidation even after heating at 200
\degree C in air for up to 4 hours. Our work further shows that graphene
provides effective resistance against hydrogen peroxide. This protection method
offers significant advantages and can be used on any metal that catalyzes
graphene growth
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