620 research outputs found
Spin separation in digital ferromagnetic heterostructures
In a study of the ferromagnetic phase of a multilayer digital ferromagnetic
semiconductor in the mean-field and effective-mass approximations, we find the
exchange interaction to have the dominant energy scale of the problem,
effectively controlling the spatial distribution of the carrier spins in the
digital ferromagnetic heterostructures. In the ferromagnetic phase, the
majority and minority carriers tend to be in different regions of the space
(spin separation). Hence, the charge distribution of carriers also changes
noticeably from the ferromagnetic to the paramagnetic phase. An example of a
design to exploit these phenomena is given.Comment: 4 pages, 3 figures. Submitted to Phys. Rev.
Heats of formation of perchloric acid, HClO, and perchloric anhydride, ClO. Probing the limits of W1 and W2 theory
The heats of formation of HClO and ClO have been determined to
chemical accuracy for the first time by means of W1 and W2 theory. These
molecules exhibit particularly severe degrees of inner polarization, and as
such obtaining a basis-set limit SCF component to the total atomization energy
becomes a challenge. (Adding high-exponent functions to a standard
basis set has an effect on the order of 100 kcal/mol for ClO.) Wilson's
aug-cc-pV(n+d)Z basis sets represent a dramatic improvement over the standard
aug-cc-pVnZ basis sets, while the aug-cc-pVnZ+2d1f sequence converges still
more rapidly. Jensen's polarization consistent basis sets still require
additional high-exponent functions: for smooth convergence we suggest the
\{aug-pc1+3d,aug-pc2+2d,aug-pc3+d,aug-pc4\} sequence. The role of the tight
functions is shown to be an improved description of the Cl (3d) Rydberg
orbital, enhancing its ability to receive back-bonding from the oxygen lone
pairs. In problematic cases like this (or indeed in general), a single
SCF/aug-cc-pV6Z+2d1f calculation may be preferable over empirically motivated
extrapolations. Our best estimate heats of formation are HClO(g)1 kcal/mol and ClO(g)2 kcal/mol, the largest source of
uncertainty being our inability to account for post-CCSD(T) correlation
effects. While G2 and G3 theory have fairly large errors, G3X theory reproduces
both values to within 2 kcal/mol.Comment: J. Mol. Struct. (THEOCHEM), in press (WATOC'05 special issue
Post-mortem culture of Balamuthia mandrillaris from the brain and cerebrospinal fluid of a case of granulomatous amoebic meningoencephalitis, using human brain microvascular endothelial cells
The first isolation in the UK of Balamuthia mandrillaris amoebae from a fatal case of granulomatous amoebic meningoencephalitis is reported. Using primary cultures of human brain microvascular endothelial cells (HBMECs), amoebae were isolated from the brain and cerebrospinal fluid (CSF). The cultures showed a cytopathic effect at 20â28 days, but morphologically identifiable B. mandrillaris amoebae were seen in cleared plaques in subcultures at 45 days. The identification of the organism was later confirmed using PCR on Chelex-treated extracts. Serum taken while the patient was still alive reacted strongly with slide antigen prepared from cultures of the post-mortem isolate, and also with those from a baboon B. mandrillaris strain at 1 : 10 000 in indirect immunofluorescence, but with Acanthamoeba castellanii (Neff) at 1 : 160, supporting B. mandrillaris to be the causative agent. If the presence of amoebae in the post-mortem CSF reflects the condition in life, PCR studies on CSF and on biopsies of cutaneous lesions may also be a valuable tool. The role of HBMECs in understanding the interactions of B. mandrillaris with the bloodâbrain barrier is discussed
Sputum inflammatory cells from patients with allergic rhinitis and asthma have decreased inflammasome gene expression
Deficits in inflammasomes, a key element of innate immunity, confer increased susceptibility to infection. We report that sputum cells from asthmatics have decreased expression of inflammasome factors, consistent with reports of increased infection risk in asthmatics
Electronic structure and magnetism of Mn doped GaN
Mn doped semiconductors are extremely interesting systems due to their novel
magnetic properties suitable for the spintronics applications. It has been
shown recently by both theory and experiment that Mn doped GaN systems have a
very high Curie temperature compared to that of Mn doped GaAs systems. To
understand the electronic and magnetic properties, we have studied Mn doped GaN
system in detail by a first principles plane wave method. We show here the
effect of varying Mn concentration on the electronic and magnetic properties.
For dilute Mn concentration, states of Mn form an impurity band completely
separated from the valence band states of the host GaN. This is in contrast to
the Mn doped GaAs system where Mn states in the gap lie very close to the
valence band edge and hybridizes strongly with the delocalized valence band
states.
To study the effects of electron correlation, LSDA+U calculations have been
performed.
Calculated exchange interaction in (Mn,Ga)N is short ranged in contrary to
that in (Mn,Ga)As where the strength of the ferromagnetic coupling between Mn
spins is not decreased substantially for large Mn-Mn separation. Also, the
exchange interactions are anisotropic in different crystallographic directions
due to the presence or absence of connectivity between Mn atoms through As
bonds.Comment: 6 figures, submitted to Phys. Rev.
On-site Coulomb interaction and the magnetism of (GaMn)N and (GaMn)As
We use the local density approximation (LDA) and LDA+U schemes to study the
magnetism of (GaMn)As and (GaMn)N for a number of Mn concentrations and varying
number of holes. We show that for both systems and both calculational schemes
the presence of holes is crucial for establishing ferromagnetism. For both
systems, the introduction of increases delocalization of the holes and,
simultaneously, decreases the p-d interaction. Since these two trends exert
opposite influences on the Mn-Mn exchange interaction the character of the
variation of the Curie temperature (T) cannot be predicted without direct
calculation. We show that the variation of T is different for two systems.
For low Mn concentrations we obtain the tendency to increasing T in the
case of (GaMn)N whereas an opposite tendency to decreasing T is obtained
for (GaMn)As. We reveal the origin of this difference by inspecting the
properties of the densities of states and holes for both systems. The main body
of calculations is performed within a supercell approach. The Curie
temperatures calculated within the coherent potential approximation to atomic
disorder are reported for comparison. Both approaches give similar qualitative
behavior. The results of calculations are related to the experimental data.Comment: to appear in Physical Review
Spectrum of non-Hermitian heavy tailed random matrices
Let (X_{jk})_{j,k>=1} be i.i.d. complex random variables such that |X_{jk}|
is in the domain of attraction of an alpha-stable law, with 0< alpha <2. Our
main result is a heavy tailed counterpart of Girko's circular law. Namely,
under some additional smoothness assumptions on the law of X_{jk}, we prove
that there exists a deterministic sequence a_n ~ n^{1/alpha} and a probability
measure mu_alpha on C depending only on alpha such that with probability one,
the empirical distribution of the eigenvalues of the rescaled matrix a_n^{-1}
(X_{jk})_{1<=j,k<=n} converges weakly to mu_alpha as n tends to infinity. Our
approach combines Aldous & Steele's objective method with Girko's Hermitization
using logarithmic potentials. The underlying limiting object is defined on a
bipartized version of Aldous' Poisson Weighted Infinite Tree. Recursive
relations on the tree provide some properties of mu_alpha. In contrast with the
Hermitian case, we find that mu_alpha is not heavy tailed.Comment: Expanded version of a paper published in Communications in
Mathematical Physics 307, 513-560 (2011
Magnetic Interactions and Transport in (Ga,Cr)As
The magnetic, transport, and structural properties of (Ga,Cr)As are reported.
Zincblende GaCrAs was grown by low-temperature molecular beam
epitaxy (MBE). At low concentrations, x0.1, the materials exhibit unusual
magnetic properties associated with the random magnetism of the alloy. At low
temperatures the magnetization M(B) increases rapidly with increasing field due
to the alignment of ferromagnetic units (polarons or clusters) having large
dipole moments of order 10-10. A standard model of
superparamagnetism is inadequate for describing both the field and temperature
dependence of the magnetization M(B,T). In order to explain M(B) at low
temperatures we employ a distributed magnetic moment (DMM) model in which
polarons or clusters of ions have a distribution of moments. It is also found
that the magnetic susceptibility increases for decreasing temperature but
saturates below T=4 K. The inverse susceptibility follows a linear-T
Curie-Weiss law and extrapolates to a magnetic transition temperature
=10 K. In magnetotransport measurements, a room temperature resistivity
of =0.1 cm and a hole concentration of cm
are found, indicating that Cr can also act as a acceptor similar to Mn. The
resistivity increases rapidly for decreasing temperature below room
temperature, and becomes strongly insulating at low temperatures. The
conductivity follows exp[-(T/T)] over a large range of
conductivity, possible evidence of tunneling between polarons or clusters.Comment: To appear in PRB 15 Mar 200
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