111 research outputs found

    Solvent–surface interactions between nanodiamond and ethanol studied with in situ infrared spectroscopy

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    In situ Attenuated Total reflectance infrared (ATR IR) spectroscopy is used to study the interaction between ethanol vapour and oxidised nanodiamond (ND) surfaces. On initial exposure an amorphous multilayer of adsorbed ethanol is observed, but over ca. 30 min a loss in intensity of ν(OH) and δ(OH) bands indicates a preferential binding of the ethanol –OH with the ND surface. Other spectral changes indicate ordering of the ethanol molecules on the surface and their confinement within the pores of the ND structure in specific conformations. Changes in the IR spectrum also suggest that vibrational frequencies of carbonyl groups on the ND surface are affected by the adsorption of ethanol and that surface-bound water is either displaced or involved in hydrogen-bonding with ethanol

    Hubungan Karakteristik Penyuluh Pertanian Pns terhadap Keberhasilan Penyuluhan (Kasus: Kecamatan Sunggal dan Kutalimbaru Kabupaten Deli Serdang)

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    Tujuan penelitian ini adalah untuk mengetahuipelaksanaan program penyuluhan di daerah penelitian, untuk menganalisis perkembangan program penyuluhan di daerah penelitian, untuk menganalisis hubungan karakteristik penyuluh terhadapkeberhasilan penyuluhan pertanian di daerah penelitian. Daerah penelitian ditentukan secara sengaja (purposive), yakni di Kecamatan Sunggal dan Kutalimbaru Kabupaten Deli Serdang, dengan pertimbangan bahwa daerah tersebut terdapat penyuluh teladan seSumatera Utara. Metode penentuan objek penelitiandigunakan metode purposive samplingdengan metode sensusyaitu sebanyak 17 orang penyuluh PNS dan 17 orang kelompok petani.Metode analisis yang digunakan adalah metode pemberian skor dan metode analisis korelasi Spearman.Hasil penelitian menunjukkan:pelaksanaan program penyuluhan mencapai keberhasilan yangtergolong tinggi. Ada peningkatan program selama tiga tahun terakhir. Bahwa ada hubungan karakteristik umur penyuluh PNS dengan keberhasilan penyuluhan tetapi karakteristik pendidikan, lama bekerja, jumlah tanggungan,jarak bertugas, tingkat pendapatan penyuluh tidak memiliki hubungan dengan keberhasilan penyuluhan

    QUARE: 1st Workshop on Measuring the Quality of Explanations in Recommender Systems

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    QUARE - measuring the QUality of explAnations in REcommender systems - is the first workshop that aims to promote discussion upon future research and practice directions around evaluation methodologies for explanations in recommender systems. To that end, we bring together researchers and practitioners from academia and industry to facilitate discussions about the main issues and best practices in the respective areas, identify possible synergies, and outline priorities regarding future research directions. Additionally, we want to stimulate reflections around methods to systematically and holistically assess explanation approaches, impact, and goals, at the interplay between organisational and human values. The homepage of the workshop is available at: https: //sites.google.com/view/quare-2022/

    Ductility of wide-beam RC frames as lateral resisting system

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    [EN] Some Mediterranean seismic codes consider wide-beam reinforced concrete moment resisting frames (WBF) as horizontal load carrying systems that cannot guarantee high ductility performances. Conversely, Eurocode 8 allows High Ductility Class (DCH) design for such structural systems. Code prescriptions related to WBF are systematically investigated. In particular, lesson learnt for previous earthquakes, historical reasons, and experimental and numerical studies underpinning specific prescriptions on wide beams in worldwide seismic codes are discussed. Local and global ductility of WBF are then analytically investigated through (1) a parametric study on chord rotations of wide beams with respect to that of deep beams, and (2) a spectral-based comparison of WBF with conventional reinforced concrete moment resisting frames (i.e. with deep beams). Results show that the set of prescriptions given by modern seismic codes provides sufficient ductility to WBF designed in DCH. In fact, global capacity of WBF relies more on the lateral stiffness of the frames and on the overstrength of columns rather than on the local ductility of wide beams, which is systematically lower with respect to that of deep beams.Gómez-Martínez, F.; Alonso Durá, A.; De Luca, F.; Verderame, GM. (2016). Ductility of wide-beam RC frames as lateral resisting system. Bulletin of Earthquake Engineering. 14(6):1545-1569. doi:10.1007/s10518-016-9891-xS15451569146ACI (1989) Building code requirements for reinforced concrete (ACI 318-89). ACI Committee 318, American Concrete Institute, Farmington Hills, Michigan, USAACI (2008) Building code requirements for structural concrete (ACI 318-08) and commentary (318-08). ACI Committee 318, American Concrete Institute, Farmington Hills, Michigan, USAACI-ASCE (1991) Recommendations for design of beam-column connections in monolithic reinforced concrete structures (ACI 352R-91). 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    3D cable-based parallel robot simulation using PD control

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    In this paper, we present a simulator that has been developed using PD control to study 3D cable-based parallel robot with four cables. The proposed control technique is widely used for dealing with linear systems uncertainties, in this context; we investigated to use the Runge Kutta method of 4th order for solving non-linear partial differential equations of our system. The main contribution of this work is firstly: modelling of differential equations of our system. Secondly, the PD control applied to the dynamic model for different trajectories in order to test the accurate tracking of the robot to a desired trajectory. The effectiveness of the proposed control strategy is improving the robot performance in terms of tracking a desired path

    A new equation for prediction of seismic gap between adjacent buildings located on different soil types

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    This study aims to investigate the effect of soil type on the minimum separation distance for low and mid-rise reinforced concrete (RC) buildings. 3696 nonlinear time history analyses were carried out using 56 different building pairs located on 3 different soil types and 66 different earthquake records. The minimum required seismic gap distances obtained from the analysis results were compared with the minimum seismic gap estimates of DDC and simplified method in the literature. The required gap distances obtained for different soil types were examined and a new equation for modification coefficient is proposed to improve the simplified method. The outcomes show that the proposed new equation provides the required seismic gap distance values for all soil types better than the Double Difference Combination (known as DDC) method estimates. © 2022 Elsevier Lt

    Turkey

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    This study aims to evaluate seismic performance of existing low and mid-rise reinforced concrete buildings by comparing their displacement capacities and displacement demands under selected ground motions experienced in Turkey as well as demand spectrum provided in 2007 Turkish Earthquake Code for design earthquake with 10% probability of exceedance in 50 years for soil class Z3. It should be noted that typical residential buildings are designed according to demand spectrum of 10% probability of exceedance in 50 years. Three RC building sets as 2-, 4- and 7-story, are selected to represent reference low-and mid-rise buildings located in the high seismicity region of Turkey. The selected buildings are typical beam-column RC frame buildings with no shear walls. The outcomes of detailed field and archive investigation including approximately 500 real residential RC buildings established building models to reflect existing building stock. Total of 72 3-D building models are constructed from the reference buildings to include the effects of some properties such as structural irregularities, concrete strength, seismic codes, structural deficiencies, transverse reinforcement detailing, and number of story on seismic performance of low and mid-rise RC buildings. Capacity curves of building sets are obtained by nonlinear static analyses conducted in two principal directions, resulting in 144 models. The inelastic dynamic characteristics are represented by "equivalent" Single-Degree-of-Freedom (ESDOF) systems using obtained capacity curves of buildings. Nonlinear time history analysis is used to estimate displacement demands of representative building models idealized with (ESDOF) systems subjected to the selected ground motion records from past earthquakes in Turkey. The results show that the significant number of pre-modern code 4- and 7-story buildings exceeds LS performance level while the modern code 4- and 7-story buildings have better performances. The findings obviously indicate the existence of destructive earthquakes especially for 4- and 7-story buildings. Significant improvements in the performance of the buildings per modern code are also obvious in the study. Almost one third of pre-modern code buildings is exceeding LS level during records in the past earthquakes. This observation also supports the building damages experienced in the past earthquake events in Turkey
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