Mechanochemical stability of hydrogen titanate nanostructures

Structural stability of nanostructured titanates was investigated for further processing and possible applications. With the aim to investigate their mechanochemical stability we applied highenergy ball milling and studied induced phase transitions. Hydrogen titanates having two different morfologies, microcrystals and nanotubes, were taken into consideration. During mechanochemical treatment of both morphologies, we observed the phase transition from hydrogen titanate to TiO2 anatase and then to TiO2 rutile. Anatase to rutile phase transition occurred without appearance of intermediate high pressure TiO2 II typically observed in the case of mechanochemical treatment of TiO2. In the case of microcrystals, phase transition from hydrogen titanate to anatase starts after longer milling time than in the case of nanotubes, which is explained by larger particles sizes of crystalline powder. On the contrary, further phase transition from anatase to rutile was occurred faster in crystalline powder than in the case of nanotubes. The sequence of phase transitions was studied by Raman spectroscopy and X-ray powder diffraction, while morphology and crystal structure at nanoscale were analyzed by high resolution electron microscopy

A mechanochemical strategy for IRMOF assembly based on pre-designed oxo-zinc precursors.

We demonstrate a mechanochemical strategy that allowed the first successful mechanosynthesis of IRMOFs based on an oxo-centred secondary building unit (SBU). The presented study indicates that controlling the acid-base relationship between reagents is key to mechanochemical synthesis of IRMOFs, revealing a pre-assembled oxo-zinc amidate cluster as an efficient precursor for IRMOF mechanosynthesis.The authors would like to acknowledge the project operated within the Foundation for Polish Science Team Programme co-financed by the EU ‘‘European Regional Development Fund’’ TEAM/2011–7/8, and the European Union in the framework of Regional Development Fund through the Joint UW and WUT International PhD Program of Foundation for Polish Science – “Towards Advanced Functional Materials and Novel Devices” (MPD/2010/4) (D.P.) for financial support.This is the accepted manuscript. The final version was published in Chemical Communications and is available at http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/c4cc09917f#!divAbstract

Prototype Lead Tungstate Calorimeter Test for TPEX

Tests of a prototype lead tungstate calorimeter were made over two weeks at the end of September, 2019, at the DESY II Test Beam Facility in Hamburg, Germany. The purpose of these tests was to gain experience with the construction, operation, and performance of a simple lead tungstate calorimeter, and also to compare a traditional triggered readout scheme with a streaming readout approach. These tests are important for the proposed Two-Photon Exchange experiment at the DESY test beam facility and for work towards a future electromagnetic calorimeter that could be used in an Electron-Ion Collider detector. Details on all aspects of the test, the subsequent analysis, and the results are presented.Comment: 7 pages, 15 figure

A Large-Scale FPGA-Based Trigger and Dead-Time Free DAQ System for the Kaos Spectrometer at MAMI

The Kaos spectrometer is maintained by the A1 collaboration at the Mainz Microtron MAMI with a focus on the study of (e,e'K^+) coincidence reactions. For its electron-arm two vertical planes of fiber arrays, each comprising approximately 10 000 fibers, are operated close to zero degree scattering angle and in close proximity to the electron beam. A nearly dead-time free DAQ system to acquire timing and tracking information has been installed for this spectrometer arm. The signals of 144 multi-anode photomultipliers are collected by 96-channel front-end boards, digitized by double-threshold discriminators and the signal time is picked up by state-of-the-art F1 time-to-digital converter chips. In order to minimize background rates a sophisticated trigger logic was implemented in newly developed Vuprom modules. The trigger performs noise suppression, signal cluster finding, particle tracking, and coincidence timing, and can be expanded for kinematical matching (e'K^+) coincidences. The full system was designed to process more than 4 000 read-out channels and to cope with the high electron flux in the spectrometer and the high count rate requirement of the detectors. It was successfully in-beam tested at MAMI in 2009.Comment: Contributed to 17th IEEE Real Time Conference (RT10), Lisbon, 24-28 May 201

Search for Light Gauge Bosons of the Dark Sector at the Mainz Microtron

A new exclusion limit for the electromagnetic production of a light U(1) gauge boson {\gamma}' decaying to e^+e^- was determined by the A1 Collaboration at the Mainz Microtron. Such light gauge bosons appear in several extensions of the standard model and are also discussed as candidates for the interaction of dark matter with standard model matter. In electron scattering from a heavy nucleus, the existing limits for a narrow state coupling to e^+e^- were reduced by nearly an order of magnitude in the range of the lepton pair mass of 210 MeV/c^2 < m_e^+e^- < 300 MeV/c^2. This experiment demonstrates the potential of high current and high resolution fixed target experiments for the search for physics beyond the standard model.Comment: 4 pages, 7 figure