Grand canonical ensemble of a dd-dimensional Reissner-Nordstr\"om black hole in a cavity

The grand canonical ensemble of a $d$-dimensional Reissner-Nordstr\"om black hole space in a cavity is analyzed. The realization of this ensemble is made through the Euclidean path integral approach by giving the Euclidean action for the black hole with the correct topology, and boundary conditions corresponding to a cavity, where the fixed quantities are the temperature and the electric potential. One performs a zero loop approximation to find and analyze the stationary points of the reduced action. This yields two solutions for the electrically charged black hole, $r_{+1}$, which is the smaller and unstable, and $r_{+2}$, which is the larger and stable. One also analyzes the most probable configurations, which are either a stable charged black hole or hot flat space, mimicked by a nongravitating charged shell. Making the correspondence between the action and the grand potential, one can get the black hole thermodynamic quantities, such as the entropy, the mean charge, the mean energy, and the thermodynamic pressure, as well as the Smarr formula, shown to be valid only for the unstable black hole. We find that thermodynamic stability is related to the positivity of the heat capacity at constant electric potential and area of the cavity. We also comment on the most favorable thermodynamic phases and phase transitions. We then choose $d = 5$, which is singled out naturally from the other higher dimensions as it provides an exact solution for the problem, and apply all the results previously found. The case $d = 4$ is mentioned. We compare thermodynamic radii with the photonic orbit radius and the Buchdahl-Andr\'easson-Wright bound radius in $d$-dimensional Reissner-Nordstr\"om spacetimes and find they are unconnected, showing that the connections displayed in the Schwarzschild case are not generic, rather they are very restricted holding only in the pure gravitational situation.Comment: 28 pages, 5 figure

Normal modes of Proca fields in AdS spacetime

A normal mode analysis for Proca fields in the anti-de Sitter (AdS) spacetime is given. It is found that the equations for the Proca field can be decoupled analytically. This is performed by changing the basis of the vector spherical harmonics (VSH) decomposition. The normal modes and the normal mode frequencies of the Proca equation in the AdS spacetime are then analytically determined. It is also shown that the Maxwell field can be recovered by taking the massless limit of the Proca field with care so that the nonphysical gauge modes are eliminated.Comment: 6 page

Support for automatic refactoring of business logic

Software’s structure profoundly affects its development and maintenance costs. Poor software’s structure may lead to well-known design flaws, such as large modules or long methods. A possible ap- proach to reduce a module’s complexity is the Extract Method refactor- ing technique. This technique allows the decomposition of a large and complex method into smaller and simpler ones, while reducing the orig- inal method’s size and improving its readability and comprehension. The OutSystems platform is a low-code platform that allows the de- velopment of web and mobile applications that rely on a set of visual Domain-Specific Languages (DSLs). Even low-code languages when im- properly used can lead to software that has maintenance issues like long methods. Thus, the purpose of this paper is to present the research and devel- opment done to provide the OutSystems platform with a tool that au- tomatically suggests Extract Method refactoring opportunities. The re- search combines program slicing techniques with code complexity metrics to calculate the best refactoring opportunities that preserve programs’ functionality. The proposed approach was tested on typical OutSystems apps and was shown to be able to reduce the overall applications’ complexity.info:eu-repo/semantics/publishedVersio

Residual granitic soil improvement for rammed earth construction

This paper describes the research developed to evaluate the performance of stabilised residual granitic soil from the north region of Portugal. It is part of a research project designed to investigate the possibility of using this soil for rammed earth construction. Since its reduced plasticity makes the use of lime less effective, and the increasing environmental concerns with cement production can no longer be ignored, the study was focused on binders made from alkaline activation of low calcium fly ash. Therefore, the aim of this work was to determine, through a parametric analysis using laboratory tests, the optimum fly ash – based alkaline activated binder for improving granitic soil, in terms of mechanical strength. Identification of the key parameters allowed the characterisation of the most effective mixtures, which will be later used in the construction of large rammed earth wall panels that will be tested according to proper specifications

Time Limit at vV02max and V02max Slow Component in Swimming: a pilot study of University Students

The aim oftms study was to measure in swimming-pool conditions, the time to exhaustion at the minimum velocity that elicits maximal oxygen consumption (TLim-vV02max) and to verify the existence of an oxygen uptake slow component (02SC) in freestyle swimming. Ten university students performed a continuous incremental protocol for vV02max assessment. Forty-eight hours later, they swam to exhaustion at vV02max to assess TLim-vV02max and 02SC. V02 was directly measured and swimming velocity was controlled by a visual pacer. Blood lactate concentrations ([La-]) and heart rate (HR) values were also measured. Mean V02max for the incremental test was 54.2±8.2 m1.kg'l.min'l, and the correspondent vV02max was 1.19±O.08 m.S,l The mean duration ofthe TLim-vV02max test was 325±76.5 s. 02SC appeared in the allout swim at VV02max (279.0±195.2 ml.min'l) and it was found to significant1y correlate with the TLim-vV02max (r = .74, p< .05). These results demonstrated that 02SC is observed also in swimming-pool conditions and that TLim-vV02max values are in accordance with typical formulations of aerobic power training sets for swimmers.We wish to thank Prof Dr. José Soares, from the Laboratory of Exercise Physiology of our faculty, for his significant contribution.info:eu-repo/semantics/publishedVersio

Red and near-infrared absorbing dicyanomethylene squaraine cyanine dyes: photophysicochemical properties and anti-tumor photosensitizing effects

Photodynamic therapy is a medical modality developed for the treatment of several diseases of oncological and non-oncological etiology that requires the presence of a photosensitizer, light and molecular oxygen, which combined will trigger physicochemical reactions responsible for reactive oxygen species production. Given the scarcity of photosensitizers that exhibit desirable characteristics for its potential application in this therapeutic strategy, the main aims of this work were the study of the photophysical and photochemical properties and the photobiological activity of several dicyanomethylene squaraine cyanine dyes. Thus, herein, the study of their aggregation character, photobleaching and singlet oxygen production ability, and the further application of the previously synthesized dyes in Caco-2 and HepG2 cancer cell lines, to evaluate their phototherapeutic effects, are described. Dicyanomethylene squaraine dyes exhibited moderate light-stability and, despite the low singlet oxygen quantum yields, were a core of dyes that exhibited relevant in vitro photodynamic activity, as there was an evident increase in the toxicity of some of the tested dyes exclusive to radiation treatments.This research was funded by the European Investment Funds by FEDER/COMPETE/POCI under projects POCI-01-0145-FEDER-006958 (CITAB) and POCI-01-0145-FEDER-007491 (CICS-UBI) and Funds by FCT – Portuguese Foundation for Science and technology, under the projects UIDB/04033/2019 (CITAB) and UIDB/00616/2020 (CQ-VR). This work was also supported by funds from the Health Sciences Research Center (CICS-UBI) through National Funds by FCT—Foundation for Science and Technology (UID/Multi/00709/2019). The research at CQFM was supported by Project UID/NAN/50024/2019 and M-ERA-NET/0002/2015 from FCT. E. L. was supported by the FCT PhD grant SFRH/BD/147645/2019

Potential of atlantic codfish (Gadus morhua) skin collagen for skincare biomaterials

Collagen is the major structural protein in extracellular matrix present in connective tissues, including skin, being considered a promising material for skin regeneration. Marine organisms have been attracting interest amongst the industry as an alternative collagen source. In the present work, Atlantic codfish skin collagen was analyzed, to evaluate its potential for skincare. The collagen was extracted from two different skin batches (food industry by-product) using acetic acid (ASColl), confirming the method reproducibility since no significant yield differences were observed. The extracts characterization confirmed a profile compatible with type I collagen, without significant differences between batches or with bovine skin collagen (a reference material in biomedicine). Thermal analyses suggested ASColl’s native structure loss at 25 °C, and an inferior thermal stability to bovine skin collagen. No cytotoxicity was found for ASColl up to 10 mg/mL in keratinocytes (HaCaT cells). ASColl was used to develop membranes, which revealed smooth surfaces without significative morphological or biodegradability differences between batches. Their water absorption capacity and water contact angle indicated a hydrophilic feature. The metabolic activity and proliferation of HaCaT were improved by the membranes. Hence, ASColl membranes exhibited attractive characteristics to be applied in the biomedical and cosmeceutical field envisaging skincare.This work was supported by funds from the European Regional Development Fund (ERDF) under the scope of NORTE 2020, part of the PORTUGAL 2020 Partnership Agreement, through the project ATLANTIDA (Norte-01-0145-FEDER-000040) and the R&D Infrastructure TERM RES-Hub PINFRA/22190/2016 (Norte-01-0145-FEDER-022190), also funded by the Portuguese Foundation for Science and Technology (FCT). Financial support from FCT is also acknowledged for the investigator contract of C.F.M. (CEECIND/04687/2017), the PhD scholarship of A.L.A. (PD/BD/127995/2016) under Doctoral Programme Do*Mar and the PhD scholarship of R.O.S. (PD/BD/150519/2019) under Doctoral Programme in Advanced Therapies for Health, PATH

Abundância de gavião-real e gavião-real falso numa área sob impacto de reservatório no Baixo e Médio rio Xingu

In the Brazilian Amazon, two monospecific genera, the Harpy Eagle and Crested Eagle have low densities and are classified by IUCN as Near Threatened due to habitat loss, deforestation, habitat degradation and hunting. In this study, we evaluate occurrence of these large raptors using the environmental surveys database from Belo Monte Hydroelectric Power Plant. Integrating the dataset from two methods, we plotted a distribution map along the Xingu River, including records over a 276-km stretch of river. Terrestrial surveys (RAPELD method) were more efficient for detecting large raptors than standardized aquatic surveys, although the latter were complementary in areas without modules. About 53% of the records were obtained during activities of wildlife rescue/flushing, vegetation suppression or in transit. Between 2012 and 2014, four Harpy Eagles were removed from the wild; two shooting victims, one injured by collision with power lines and one hit by a vehicle. Also, seven nests were mapped. The mean distance between Harpy Eagle records was 15 km along the river channel, with a mean of 20 km between nests near the channel, which allowed us to estimate 20 possible pairs using the alluvial forest, riverine forest and forest fragments. Territories of another ten pairs will probably be affected by inundation of the Volta Grande channel, which is far from the main river. The average distance between Crested Eagle records was 16 km along the river channel. The only nest found was 1.3 km away from a Harpy Eagle nest. The remnant forests are under threat of being replaced by cattle pastures, so we recommend that permanently protected riparian vegetation borders (APP) be guaranteed, and that forest fragments within 5 km of the river be conserved to maintain eagle populations. © 2015, Instituto Internacional de Ecologia. All rights reserved

Educação Ambiental envolvendo o descarte de pilhas e baterias: uma ação do PIBID de Química na comunidade do Salobrinho

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Fungal Planet description sheets: 868-950

Novel species of fungi described in this study include those from various countries as follows: Australia, Chaetomella pseudocircinoseta and Coniella pseudodiospyri on Eucalyptus microcorys leaves, Cladophialophora eucalypti, Teratosphaeria dunnii and Vermiculariopsiella dunnii on Eucalyptus dunnii leaves, Cylindrium grande and Hypsotheca eucalyptorum on Eucalyptus grandis leaves, Elsinoe salignae on Eucalyptus saligna leaves, Marasmius lebeliae on litter of regenerating subtropical rainforest, Phialoseptomonium eucalypti (incl. Phialoseptomonium gen. nov.) on Eucalyptus grandis × camaldulensis leaves, Phlogicylindrium pawpawense on Eucalyptus tereticornis leaves, Phyllosticta longicauda as an endophyte from healthy Eustrephus latifolius leaves, Pseudosydowia eucalyptorum on Eucalyptus sp. leaves, Saitozyma wallum on Banksia aemula leaves, Teratosphaeria henryi on Corymbia henryi leaves. Brazil, Aspergillus bezerrae, Backusella azygospora, Mariannaea terricola and Talaromyces pernambucoensis from soil, Calonectria matogrossensis on Eucalyptus urophylla leaves, Calvatia brasiliensis on soil, Carcinomyces nordestinensis on Bromelia antiacantha leaves, Dendryphiella stromaticola on small branches of an unidentified plant, Nigrospora brasiliensis on Nopalea cochenillifera leaves, Penicillium alagoense as a leaf endophyte on a Miconia sp., Podosordaria nigrobrunnea on dung, Spegazzinia bromeliacearum as a leaf endophyte on Tilandsia catimbauensis, Xylobolus brasiliensis on decaying wood. Bulgaria, Kazachstania molopis from the gut of the beetle Molops piceus. Croatia, Mollisia endocrystallina from a fallen decorticated Picea abies tree trunk. Ecuador, Hygrocybe rodomaculata on soil. Hungary, Alfoldia vorosii (incl.Alfoldia gen. nov.) from Juniperus communis roots, Kiskunsagia ubrizsyi (incl. Kiskunsagia gen. nov.) from Fumana procumbens roots. India, Aureobasidium tremulum as laboratory contaminant, Leucosporidium himalayensis and Naganishia indica from windblown dust on glaciers. Italy, Neodevriesia cycadicola on Cycas sp. leaves, Pseudocercospora pseudomyrticola on Myrtus communis leaves, Ramularia pistaciae on Pistacia lentiscus leaves, Neognomoniopsis quercina (incl. Neognomoniopsis gen. nov.) on Quercus ilex leaves. Japan, Diaporthe fructicola on Passiflora edulis × P. edulis f. flavicarpa fruit, Entoloma nipponicum on leaf litter in a mixed Cryptomeria japonica and Acer spp. forest. Macedonia, Astraeus macedonicus on soil. Malaysia, Fusicladium eucalyptigenum on Eucalyptus sp. twigs, Neoacrodontiella eucalypti (incl. Neoacrodontiella gen. nov.) on Eucalyptus urophylla leaves. Mozambique, Meliola gorongosensis on dead Philenoptera violacea leaflets. Nepal, Coniochaeta dendrobiicola from Dendriobium lognicornu roots. New Zealand, Neodevriesia sexualis and Thozetella neonivea on Archontophoenix cunninghamiana leaves. Norway, Calophoma sandfjordenica from a piece of board on a rocky shoreline, Clavaria parvispora on soil, Didymella finnmarkica from a piece of Pinus sylvestris driftwood. Poland, Sugiyamaella trypani from soil. Portugal, Colletotrichum feijoicola from Acca sellowiana. Russia, Crepidotus tobolensis on Populus tremula debris, Entoloma ekaterinae, Entoloma erhardii and Suillus gastroflavus on soil, Nakazawaea ambrosiae from the galleries of Ips typographus under the bark of Picea abies. Slovenia, Pluteus ludwigii on twigs of broadleaved trees. South Africa, Anungitiomyces stellenboschiensis (incl. Anungitiomyces gen. nov.) and Niesslia stellenboschiana on Eucalyptus sp. leaves, Beltraniella pseudoportoricensis on Podocarpus falcatus leaf litter, Corynespora encephalarti on Encephalartos sp. leaves, Cytospora pavettae on Pavetta revoluta leaves, Helminthosporium erythrinicola on Erythrina humeana leaves, Helminthosporium syzygii on a Syzygium sp. barkcanker, Libertasomyces aloeticus on Aloe sp. leaves, Penicillium lunae from Musa sp. fruit, Phyllosticta lauridiae on Lauridia tetragona leaves, Pseudotruncatella bolusanthi (incl. Pseudotruncatellaceae fam. nov.) and Dactylella bolusanthi on Bolusanthus speciosus leaves. Spain, Apenidiella foetida on submerged plant debris, Inocybe grammatoides on Quercus ilex subsp. ilex forest humus, Ossicaulis salomii on soil, Phialemonium guarroi from soil. Thailand, Pantospora chromolaenae on Chromolaena odorata leaves. Ukraine, Cadophora helianthi from Helianthus annuus stems. USA, Boletus pseudopinophilus on soil under slash pine, Botryotrichum foricae, Penicillium americanum and Penicillium minnesotense from air. Vietnam, Lycoperdon vietnamense on soil. Morphological and culture characteristics are supported by DNA barcodes