Two-Element PIFA Array Structure for Polarization Diversity in UMTS Mobile Phones

In this paper, we demonstrate the possibility to strongly modify the radiated fields of a UMTS handset by using a phased two-element PIFA array. The structure is composed of a 100x40 mm2 metallic ground plane acting as the Printed Circuit Board (PCB) of the mobile phone. Two UMTS PIFAs are located at the top edge of this PCB. They are fed by a double Quasi-Lumped Coupler able to provide a 360° phase difference between its two outputs. By properly choosing the DC bias of the double QuasiLumped Coupler, we can set a specific phase difference between the two PIFAs. In this way the two-element array is able to radiate different electromagnetic fields. Simulated and measured radiation patterns in the two main planes of the chassis are presented for different phase differences. It is especially revealed that the novel twoantenna structure is able to radiate vertically-polarized electric fields in the azimuthal plane of the phone and horizontally-polarized electric fields in the same plane when changing the phase shift between the antennas from 0° to 180°. Potential applications are polarization-diversity techniques and Specific Absorption Rate reduction for handsets

HNO Binding in a Heme Protein: Structures, Spectroscopic Properties, and Stabilities

HNO can interact with numerous heme proteins, but atomic level structures are largely unknown. In this work, various structural models for the first stable HNO heme protein complex, MbHNO (Mb, myoglobin), were examined by quantum chemical calculations. This investigation led to the discovery of two novel structural models that can excellently reproduce numerous experimental spectroscopic properties. They are also the first atomic level structures that can account for the experimentally observed high stabilities. These two models involve two distal His conformations as reported previously for MbCNR and MbNO. However, a unique dual hydrogen bonding feature of the HNO binding was not reported before in heme protein complexes with other small molecules such as CO, NO, and O2. These results shall facilitate investigations of HNO bindings in other heme proteins

Coupling and uncoupling mechanisms in the methoxythreonine mutant of cytochrome P450cam: a quantum mechanical/molecular mechanical study

The Thr252 residue plays a vital role in the catalytic cycle of cytochrome P450cam during the formation of the active species (Compound I) from its precursor (Compound 0). We investigate the effect of replacing Thr252 by methoxythreonine (MeO-Thr) on this protonation reaction (coupling) and on the competing formation of the ferric resting state and H2O2 (uncoupling) by combined quantum mechanical/molecular mechanical (QM/MM) methods. For each reaction, two possible mechanisms are studied, and for each of these the residues Asp251 and Glu366 are considered as proton sources. The computed QM/MM barriers indicate that uncoupling is unfavorable in the case of the Thr252MeO-Thr mutant, whereas there are two energetically feasible proton transfer pathways for coupling. The corresponding rate-limiting barriers for the formation of Compound I are higher in the mutant than in the wild-type enzyme. These findings are consistent with the experimental observations that the Thr252MeO-Thr mutant forms the alcohol product exclusively (via Compound I), but at lower reaction rates compared with the wild-type enzyme

Correlation of specific absorption rates in the human head due to multiple independent sources, Loughborough Antennas & Propagation Conference, Loughborough, 16th - 17th November 2009

Loughborough Antennas & Propagation Conference, Loughborough, 16th - 17th November 2009This paper examines how the SAR in the head is combined when exposed to the field due to multiple sources. The mechanisms when the sources have the same and different frequencies are discussed. FDTD simulation results are included when an anatomically realistic head is excited by various sources including: plane waves, vertically and horizontally orientated dipoles positioned in front and by the side of the head. Results are presented for two sources over the frequency range 0.5 to 4GHz

Analysis of the transmitted field amplitude and averaged SAR increase due to mobile terminal - flat phantom multiple interactions

International audienc

Various optimization problems of electromagnetic power absorption in homogeneous and heterogeneous phantoms

International audienc