695 research outputs found
Magnetic properties of a novel Pr Fe Ti phase
In a systematic study of the (Pr1âxTix)Fe5 alloy series, the (Pr0.65Ti0.35)Fe5 alloy has been
found to have a dominant phase with either the rhombohedral Th2Zn17 structure or the
newly discovered Nd2(Fe,Ti)19 (S. J. Collocott, R. K. Day, J. B. Dunlop, and R. L. Davis,
in Proceedings of the Seventh International Symposium on Magnetic Anisotropy and
Coercivity in RâT Alloys, Canberra, July 1992, p. 437) structure, depending on the
annealing procedure. Powderâxârayâdiffraction patterns and scanning electron
microscopy show that the sample annealed at a temperature of 850â°C followed by
1000â°C has the 2:17 structure whereas annealing at 1000â°C directly leads to the new
2:19 structure. Energyâdispersive xâray analysis yields Pr:Fe:Ti ratios of 10.7:86.2:3.1
for the Pr2(Fe,Ti)17 phase and 9.2:85.9:4.9 for the Pr2(Fe,Ti)19 phase.
57
Fe Mössbauer
spectroscopy (at 295 K) gives values for the average
57
Fe hyperfine field of 15.7 T for the
2:17 phase and 17.5 T for the 2:19 phase, respectively
A pilot study of the S-MAP (Solutions for Medications Adherence Problems) intervention for older adults prescribed polypharmacy in primary care: Study protocol
Background: Adhering to multiple medications as prescribed is challenging for older patients (aged â„ 65 years) and a difficult behaviour to improve. Previous interventions designed to address this have been largely complex in nature but have shown limited effectiveness and have rarely used theory in their design. It has been recognised that theory ('a systematic way of understanding events or situations') can guide intervention development and help researchers better understand how complex adherence interventions work. This pilot study aims to test a novel community pharmacy-based intervention that has been systematically developed using the Theoretical Domains Framework (12-domain version) of behaviour change. Methods: As part of a non-randomised pilot study, pharmacists in 12 community pharmacies across Northern Ireland (n = 6) and London, England (n = 6), will be trained to deliver the intervention to older patients who are prescribed â„ 4 regular medicines and are non-adherent (self-reported). Ten patients will be recruited per pharmacy (n = 120) and offered up to four tailored one-to-one sessions, in the pharmacy or via telephone depending on their adherence, over a 3-4-month period. Guided by an electronic application (app) on iPads, the intervention content will be tailored to each patient's underlying reasons for non-adherence and mapped to the most appropriate solutions using established behaviour change techniques. This study will assess the feasibility of collecting data on the primary outcome of medication adherence (self-report and dispensing data) and secondary outcomes (health-related quality of life and unplanned hospitalisations). An embedded process evaluation will assess training fidelity for pharmacy staff, intervention fidelity, acceptability to patients and pharmacists and the intervention's mechanism of action. Process evaluation data will include audio-recordings of training workshops, intervention sessions, feedback interviews and patient surveys. Analysis will be largely descriptive. Discussion: Using pre-defined progression criteria, the findings from this pilot study will guide the decision whether to proceed to a cluster randomised controlled trial to test the effectiveness of the S-MAP intervention in comparison to usual care in community pharmacies. The study will also explore how the intervention components may work to bring about change in older patients' adherence behaviour and guide further refinement of the intervention and study procedures. Trial registration: This study is registered at ISRCTN: https://doi.org/10.1186/ISRCTN7383153
Magnetic properties of Gd(Fe1âxCox)9Ti2 alloys
Four samples of Gd(Fe1âxCox)9Ti2 with x=0.0, 0.1, 0.2, and 0.3 were prepared by
conventional arc melting followed by annealing at 1000â°C for 3 days.
Powderâxârayâdiffraction patterns of these samples show that all of the samples have
a dominant phase with the tetragonal CeMn6Ni5 structure. Traces of TiFe2 are also
present.
57
Fe Mössbauer spectra have been collected at 80 and 295 K.
Xârayâdiffraction patterns and Mössbauer spectra on magnetically aligned samples
indicate that the easy axis of magnetization is the crystallographic c axis. The Curie
temperature increases monotonically with increasing cobalt concentration. The average
hyperfine field at 80 K reaches a maximum of 26.8(5) T for xâ0.2
Neutron diffraction and Mössbauer study of the magnetic structure of YFe6Sn6
We have used time-of-flight (TOF) neutron powder diffraction, and both
57
Fe and
119
Sn
Mössbauer spectroscopy over the temperature range 2â600 K to determine the magnetic
ordering mode of the Fe sublattice in YFe6Sn6. The crystal structure is orthorhombic
(space group Immm). The Fe sublattice orders antiferromagnetically with a NĂ©el
temperature of 558(5) K. The TOF neutron diffraction patterns obtained at 4 and 293 K
show that the antiferromagnetic ordering of the Fe sublattice is along [100] with a
propagation vector q=[010]. The magnetic space group is IPmâČmâČmâČ. This magnetic
structure is confirmed by our
119 Sn Mössbauer spectra
57-Fe Mossbauer study of magnetic ordering in superconducting K_0.85Fe_1.83Se_2.09 single crystals
The magnetic ordering of superconducting single crystals of
K_0.85Fe_1.83Se_2.09 has been studied between 10K and 550K using 57-Fe
Mossbauer spectroscopy. Despite being superconducting below T_sc ~30K, the iron
sublattice in K_0.85Fe_1.83Se_2.09 clearly exhibits magnetic order from well
below T_sc to its N\'eel temperature of T_N = 532 +/- 2K. The iron moments are
ordered perpendicular to the single crystal plates, i.e. parallel to the
crystal c-axis. The order collapses rapidly above 500K and the accompanying
growth of a paramagnetic component suggests that the magnetic transition may be
first order, which may explain the unusual temperature dependence reported in
recent neutron diffraction studies.Comment: 6 pages, 4 figures Submitted to Phys.Rev.
Neutron diffraction study of the magnetic order in NdMn2Ge1.6Si0.4
Here we report a detailed investigation of NdMn2Ge1.6Si0.4; this forms part of our investigation of the magnetic order across the NdMn2Ge2âxSix (x = 0â2.0) series by magnetometry, x-ray diffraction and neutron diffraction over the temperature range 6â465 K. On decreasing the temperature from 465 K, NdMn2Ge1.6Si0.4 exhibits four magnetic transitions: (i) from paramagnetism to intralayer antiferromagnetism AFl at TIntraN ~ 430 K; (ii) AFl to canted ferromagnetism Fmc at TInterC ~ 330 K; (iii) Fmc to conical magnetic ordering of the Mn sublattice Fmi at Tcc ~ 178 K and (iv) Fmi(Mn) to Fmi(Mn)+F(Nd) at TNdC ~ 72 K
Mineralogia e quĂmica de um Latossolo cĂąmbico desenvolvido de rocha pelĂtica do grupo BambuĂ, MG.
Foram realizados analises quimica e mineralogica das fracoes argila e silte de amostras de um perfil de solo com tres camadas distintas: uma superficies xantizada, uma camada de subsuperficie vermelha e um horizonte C apresentado variegados amarelos e vermelhos. Os minerais de maior ocorrencia sao caulinita, mica/vermiculita e goethita. A cor do solo esta relacionada a proporcao hematita/goethita (determinada pela espectroscopia Mossbauer). A substituicao isomorfica de ferro por aluminio na goethita aumenta uniformemente, de 20 a 40 mol%, da base para o topo de perfil; SiO2 decresce uniformemente e ha, ainda, uma tendencia de o Fe 2+ ser continuamente oxidado, na medida em que mica se transforma em vermiculita. O aparecimento de hematita na camada vermelha nao pode ser explicado quantitativamente pela hipotese de que os silicatos sejam a unica fonte de ferro, a menos que haja uma consideravel reducao de volume de camada siltosa amarela do horizonte C para as camadas vermelhas do horizonte B. Os dados sugerem uma transformacao reversivel goethita hematita, em resposta as condicoes ambientais
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