Phase behavior of grafted chain molecules: Influence of head size and chain length

Constant pressure Monte Carlo simulations of a coarse grained off-lattice model for monolayers of amphiphilic molecules at the air/water interface are presented. Our study focusses on phase transitions within a monolayer rather than on self aggregation. We thus model the molecules as stiff chains of Lennard-Jones spheres with one slightly larger repulsive end bead (head) grafted to a planar surface. Depending on the size of the head, the temperature and the pressure, we find a variety of phases, which differ in tilt order (including tilt direction), and in positional order. In particular, we observe a modulated phase with a striped superstructure. The modulation results from the competition between two length scales, the head size and the tail diameter. As this mechanism is fairly general, it may conceivably also be relevant in experimental monolayers. We argue that the superstructure would be very difficult to detect in a scattering experiment, which perhaps accounts for the fact that it has not been reported so far. Finally the effect of varying the chain length on the phase diagram is discussed. Except at high pressures and temperatures, the phase boundaries in systems with longer chains are shifted to higher temperatures.Comment: To appear in J. Chem. Phy

Heat exchanger method, ingot casting; fixed abrasive method, multi-wire slicing, phase 2. Silicon sheet growth development for the large area sheet task of the low cost silicon solar array project

A crack-free silicon ingot has been cast in a graded, semiconductor purity silica crucible. More than 90% single crystallinity has been achieved in 2.5 kg cast ingots. The impurities on the surface of the melt have been reduced with the use of a rapid heat-up cycle and absence of graphite retainers. Solar cells fabricated out of HEM cast material have shown conversion efficiency up to 14% under AM1 Xenon source illumination. Considerable progress has been achieved in casting square cross-section ingots. The growth in the corners has been obtained but the problem area is in fabricating a custom-made graded crucible. Kerf loss was reduced to 6.2 mil, 0.155 mm in slicing 4 cm x 4 cm cross-section with 100% yield. The abrasive life of plated impregnated blades was increased by hardening the electroless nickel layer. In an effort to prevent diamond pull-out and thereby improve the abrasive life, the plated layer was increased from 0.3 mil, 7.5 ..mu..m to 0.5 mil, 12.5 ..mu..m. The extra thickness buried the diamonds. A thinner copper sheath for impregnation and a thicker nickel coating to prevent diamond pull-out is expected to improve the abrasive life. Higher feed forces increased the cutting rates but resulted in deeper surface damage

Multi-qubit entanglement engineering via projective measurements

So far, various multi-photon entangled states have been observed experimentally by using different experimental set-ups. Here, we present a scheme to realize many SLOCC-inequivalent states of three and four qubits via projective measurements on suitable entangled states. We demonstrate how these states can be observed experimentally in a single set-up and study the feasibility of the implementation with present-day technology

Spectral Estimates and Non-Selfadjoint Perturbations of Spheroidal Wave Operators

We derive a spectral representation for the oblate spheroidal wave operator which is holomorphic in the aspherical parameter $\Omega$ in a neighborhood of the real line. For real $\Omega$, estimates are derived for all eigenvalue gaps uniformly in $\Omega$. The proof of the gap estimates is based on detailed estimates for complex solutions of the Riccati equation. The spectral representation for complex $\Omega$ is derived using the theory of slightly non-selfadjoint perturbations.Comment: 33 pages, LaTeX, 3 figures, typo in Lemma 4.1 corrected (published version

Silicon ingot casting: Heat exchanger method. Multi-wire slicing: Fixed abrasive slicing technique, phase 3

In the area of ingot casting the proof of concept of heat exchanger method (HEM) was established. It was also established that HEM cast silicon yielded solar cell performance comparable to Czochralski grown material. Solar cells with conversion efficiencies of up to 15% were fabricated. It was shown that square cross-section ingots can be cast. In the area of crystal slicing, it was established that silicon can be sliced efficiently with the fixed abrasive slicing technique approach. This concept was carried forward to 10 cm diameter workpiece

Silicon ingot casting: Heat Exchange Method (HEM). Multi-wire slicing: Fixed Abrasive Slicing Technique (FAST). Phase 3 and phase 4: Silicon sheet growth development for the large area sheet task of the low-cost solar array project

Several areas of silicon sheet growth development are addressed including: silicon ingot casting, heat exchanger method, multiwire slicing, and fixed abrasive slicing technique

Granulin Knock Out Zebrafish Lack Frontotemporal Lobar Degeneration and Neuronal Ceroid Lipofuscinosis Pathology

Loss of function mutations in granulin (GRN) are linked to two distinct neurological disorders, frontotemporal lobar degeneration (FTLD) and neuronal ceroid lipofuscinosis (NCL). It is so far unknown how a complete loss of GRN in NCL and partial loss of GRN in FTLD can result in such distinct diseases. In zebrafish, there are two GRN homologues, Granulin A (Grna) and Granulin B (Grnb). We have generated stable Grna and Grnb loss of function zebrafish mutants by zinc finger nuclease mediated genome editing. Surprisingly, the grna and grnb single and double mutants display neither spinal motor neuron axonopathies nor a reduced number of myogenic progenitor cells as previously reported for Grna and Grnb knock down embryos. Additionally, grna-/-;grnb-/- double mutants have no obvious FTLD- and NCL-related biochemical and neuropathological phenotypes. Taken together, the Grna and Grnb single and double knock out zebrafish lack any obvious morphological, pathological and biochemical phenotypes. Loss of zebrafish Grna and Grnb might therefore either be fully compensated or only become symptomatic upon additional challenge