Microscopic reversibility of quantum open systems

The transition probability for time-dependent unitary evolution is invariant under the reversal of protocols just as in the classical Liouvillian dynamics. In this article, we generalize the expression of microscopic reversibility to externally perturbed large quantum open systems. The time-dependent external perturbation acts on the subsystem during a transient duration, and subsequently the perturbation is switched off so that the total system would thermalize. We concern with the transition probability for the subsystem between the initial and final eigenstates of the subsystem. In the course of time evolution, the energy is irreversibly exchanged between the subsystem and reservoir. The time reversed probability is given by the reversal of the protocol and the initial ensemble. Microscopic reversibility equates the time forward and reversed probabilities, and therefore appears as a thermodynamic symmetry for open quantum systems.Comment: numerical demonstration is correcte

Fluctuation theorem for currents in open quantum systems

A quantum-mechanical framework is set up to describe the full counting statistics of particles flowing between reservoirs in an open system under time-dependent driving. A symmetry relation is obtained which is the consequence of microreversibility for the probability of the nonequilibrium work and the transfer of particles and energy between the reservoirs. In some appropriate long-time limit, the symmetry relation leads to a steady-state quantum fluctuation theorem for the currents between the reservoirs. On this basis, relationships are deduced which extend the Onsager-Casimir reciprocity relations to the nonlinear response coefficients.Comment: 19 page

Dermatillomania: Strategies for developing protective biomaterials/cloth

Dermatillomania or skin picking disorder (SPD) is a chronic, recurrent, and treatment resistant neuropsychiatric disorder with an underestimated prevalence that has a concerning negative impact on an individual’s health and quality of life. The current treatment strategies focus on behavioral and pharmacological therapies that are not very effective. Thus, the primary objective of this review is to provide an introduction to SPD and discuss its current treatment strategies as well as to propose biomaterial-based physical barrier strategies as a supporting or alternative treatment. To this end, searches were conducted within the PubMed database and Google Scholar, and the results obtained were organized and presented as per the following categories: prevalence, etiology, conse-quences, diagnostic criteria, and treatment strategies. Furthermore, special attention was provided to alternative treatment strategies and biomaterial-based physical treatment strategies. A total of six products with the potential to be applied as physical barrier strategies in supporting SPD treatment were shortlisted and discussed. The results indicated that SPD is a complex, underestimated, and underemphasized neuropsychiatric disorder that needs heightened attention, especially with regard to its treatment and care. Moreover, the high synergistic potential of biomaterials and nanosystems in this area remains to be explored. Certain strategies that are already being utilized for wound healing can also be further exploited, particularly as far as the prevention of infections is concerned

Thermodynamic large fluctuations from uniformized dynamics

Large fluctuations have received considerable attention as they encode information on the fine-scale dynamics. Large deviation relations known as fluctuation theorems also capture crucial nonequilibrium thermodynamical properties. Here we report that, using the technique of uniformization, the thermodynamic large deviation functions of continuous-time Markov processes can be obtained from Markov chains evolving in discrete time. This formulation offers new theoretical and numerical approaches to explore large deviation properties. In particular, the time evolution of autonomous and non-autonomous processes can be expressed in terms of a single Poisson rate. In this way the uniformization procedure leads to a simple and efficient way to simulate stochastic trajectories that reproduce the exact fluxes statistics. We illustrate the formalism for the current fluctuations in a stochastic pump model

Green-Kubo formula for heat conduction in open systems

We obtain an exact Green-Kubo type linear response result for the heat current in an open system. The result is derived for classical Hamiltonian systems coupled to heat baths. Both lattice models and fluid systems are studied and several commonly used implementations of heat baths, stochastic as well as deterministic, are considered. The results are valid in arbitrary dimensions and for any system sizes. Our results are useful for obtaining the linear response transport properties of mesoscopic systems. Also we point out that for systems with anomalous heat transport, as is the case in low-dimensional systems, the use of the standard Green-Kubo formula is problematic and the open system formula should be used.Comment: 4 page

Dynamical fluctuations for semi-Markov processes

We develop an Onsager-Machlup-type theory for nonequilibrium semi-Markov processes. Our main result is an exact large time asymptotics for the joint probability of the occupation times and the currents in the system, establishing some generic large deviation structures. We discuss in detail how the nonequilibrium driving and the non-exponential waiting time distribution influence the occupation-current statistics. The violation of the Markov condition is reflected in the emergence of a new type of nonlocality in the fluctuations. Explicit solutions are obtained for some examples of driven random walks on the ring.Comment: Minor changes, accepted for publication in Journal of Physics

The chronology of Late Pleistocene thermal contraction cracking derived from sand wedge OSL dating in central and southern France

Much of France remained unglaciated during the Late Quaternary and was subjected to repeated phases of periglacial activity. Numerous periglacial features have been reported but disentangling the environmental and climatic conditions they formed under, the timing and extent of permafrost and the role of seasonal frost has remained elusive. The primary sandy infillings of relict sand-wedges and composite-wedge pseudomorphs record periglacial activity. As they contain well-bleached quartz-rich aeolian material they are suitable for optically stimulated luminescence dating (OSL). This study aims to reconstruct when wedge activity took place in two regions of France; Northern Aquitaine and in the Loire valley. Results from single-grain OSL measurements identify multiple phases of activity within sand wedges which suggest that wedge activity in France occurred at least 11 times over the last 100 ka. The most widespread events of thermal contraction cracking occurred between ca. 30 and 24 ka (Last Permafrost Maximum) which are concomitant with periods of high sand availability (MIS 2). Although most phases of sand-wedge growth correlate well with known Pleistocene cold periods, the identification of wedge activity during late MIS 5 and the Younger Dryas strongly suggests that these features do not only indicate permafrost but also deep seasonal ground freezing in the context of low winter insolation. These data also suggest that the overall young ages yielded by North-European sand-wedges likely result from poor record of periglacial periods concomitant with low sand availability and/or age averaging inherent with standard luminescence methods

Two-step polarization reversal in biased ferroelectrics

Polarization reversal in polycrystalline ferroelectrics is shown to occur via two distinct and sequential domain reorientation steps. This reorientation sequence, which cannot be readily discriminated in the overall sample polarization, is made apparent using time-resolved high-energy x-ray diffraction. Upon application of electric fields opposite to the initial poling direction, two unique and significantly different time constants are observed. The first (faster time constant) is shown to be derived by the release of a residual stress due to initial electrical biasing and the second (slower time constant) due to the redevelopment of residual stress during further domain wall motion. A modified domain reorientation model is given that accurately describes the domain volume fraction evolution during the reversal process.open1