Influence of Zn excess on compositional, structural and vibrational properties of Cu2ZnSn0.5Ge0.5Se4 thin films and their effect on solar cell efficiency

This Accepted Manuscript will be available for reuse under a CC BY-NC-ND licence after 24 months of embargo periodThe effect of Zn content on compositional, structural and vibrational properties of Cu2ZnSn1-xGexSe4 (CZTGSe, x ~ 0.5) thin films is studied. Kesterite layer is deposited by co-evaporation onto 5 × 5 cm2 Mo/SLG substrate followed by a thermal treatment at maximum temperature of 480 °C, obtaining areas with different composition and morphology which are due to the sample position in the co-evaporation system and to the non-uniform temperature distribution across the substrate. Kesterite layers with higher Zn amounts are characterized by lower Cu and Ge contents; however, a uniform Ge distribution through the absorber layer is detected in all cases. The excess Zn concentration leads to the formation of ZnSe secondary phase on the surface and in the bulk of the absorber as determined by Raman spectroscopy. When higher Ge content and no ZnSe are present in the absorber layer, a compact structure is formed with larger grain size of kesterite. This effect could explain the higher Voc of the solar cell. The Zn content does not affect the bandgap energy significantly (Eg near 1.3 eV), although the observed effect of Zn excess in CZTGSe results in a decreased device performance from 6.4 to 4.2%. This investigation reveals the importance of the control of the off-stoichiometric CZTGSe composition during the deposition process to enhance solar cells propertiesThis work was supported by Spanish Ministry of Science, Innovation and Universities Project WINCOST (ENE2016-80788-C5-2-R) and European Project INFINITE CELL (H2020-MSCA-RISE-2017-777968). ARP also acknowledges financial support from Community of Madrid within Youth Employment Program (PEJD-2017-PRE/IND-4062). MG acknowledges the financial support from ACCIÓ-Generalitat de Catalunya within the TECNIOspring Plus fellowship (TECSPR18-1-0048

A novel heat-pulse probe for measuring soil thermal conductivity: Field test under different tillage practices

Accurate soil thermal conductivity (λ) measurements are needed in experimental agri-environmental research. This study design and build of new heat-pulse probe (HPP) based on transient state technology to measure λ. The HPP consists of three main components: an electronic control system, a measurement chamber, and sample rings. The performance of the new HPP for in-situ λ measurements is compared to estimates from measurable soil physical properties (pedotransfer function). Tests were conducted in clay loam and loam soils at three depths. λ measurements by the HPP were affected by tillage practice, fertilizer treatment, soil depth, and soil type. No significant differences in λ measurements by the HPP and estimates from a pedotransfer function were found between tillage practices. There were positive correlations between their values at three soil depths: R2 = 0.92 at 0–5 cm depth, and R2 = 0.88 at both 5–10 and 10–15 cm depths. The standard deviation from the HPP measurements were 0.061, 0.077, and 0.080 W·m−1·K−1 at 0–5, 5–10, and 10–15 cm depths, respectively. In contrast, the pedotransfer function estimates had standard deviations of 0.085, 0.660, and 0.083 W·m−1·K−1, respectively. It was found that conventional tillage increases temperature flow in soils compared to no-tillage because of decreasing soil bulk density (ρb) and consequently higher porosity. The proposed HPP is a low-cost and energy-efficient device, with wide applicability under a range of conditions. It is highly recommended for measuring λ clay loam and loam soils; however, more research is needed to determine its value with other soil types

Medio siglo en la evolución de los paisajes naturales y agrarios de Sierra Nevada (España)

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A half-century of landscape evolution in the Sierra Nevada (Spain)

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A Conceptual Model for Planning and Management of Areas of Public Space and Meeting in Colombia

A refined investigation of new trends in urban analysis assuming a sustainable design of Areas of Public Space and Meeting (APSM) is a fundamental response to the challenges of inclusive and efficient cities. Even though the APSM are districts regarded as urban structuring systems, there is a lack of territorial planning instruments and conceptual models aimed at explaining their long-term dynamics. Based on these premises, we developed a conceptual model that articulates relevant variables of interest for the planning and management of APSM. The construction of the model includes the review and analysis of the literature and the validation process based on a consultation with a panel of experts on the subject. Our findings demonstrate that the existing research does not address the APSM issue adequately, and the methodologies proposed so far do not lead to accurate and comprehensive analyses of urban complexity in light of sustainability targets. There are only isolated, disjointed, and partial approaches to variables of interest, making it difficult to carry out holistic studies. Our technical and scientific proposal offers a framework for an exhaustive evaluation of these areas. The model has been structured according to the assumptions of urban sustainability and can be applied to diverse urban environments in South America

Cardiac electrical defects in progeroid mice and Hutchinson-Gilford progeria syndrome patients with nuclear lamina alterations

Hutchinson–Gilford progeria syndrome (HGPS) is a rare genetic disease caused by defective prelamin A processing, leading to nuclear lamina alterations, severe cardiovascular pathology, and premature death. Prelamin A alterations also occur in physiological aging. It remains unknown how defective prelamin A processing affects the cardiac rhythm. We show age-dependent cardiac repolarization abnormalities in HGPS patients that are also present in the Zmpste24-/- mouse model of HGPS. Challenge of Zmpste24-/- mice with the ß-adrenergic agonist isoproterenol did not trigger ventricular arrhythmia but caused bradycardia-related premature ventricular complexes and slow-rate polymorphic ventricular rhythms during recovery. Patch-clamping in Zmpste24-/- cardiomyocytes revealed prolonged calcium-transient duration and reduced sarcoplasmic reticulum calcium loading and release, consistent with the absence of isoproterenol-induced ventricular arrhythmia. Zmpste24-/- progeroid mice also developed severe fibrosis-unrelated bradycardia and PQ interval and QRS complex prolongation. These conduction defects were accompanied by overt mislocalization of the gap junction protein connexin43 (Cx43). Remarkably, Cx43 mislocalization was also evident in autopsied left ventricle tissue from HGPS patients, suggesting intercellular connectivity alterations at late stages of the disease. The similarities between HGPS patients and progeroid mice reported here strongly suggest that defective cardiac repolarization and cardiomyocyte connectivity are important abnormalities in the HGPS pathogenesis that increase the risk of arrhythmia and premature death.Peer ReviewedPostprint (published version

Structural Volatility in Chile: A Policy Report

This paper identifies Chile`s economic weaknesses and offers policy recommendations for increasing stability. Current problems include weak international financial links, a Central Bank mandate that is ill-designed to deal with terms of trade shocks, a propensity to waste scarce liquidity in the banking system; and limited development of financial markets. The paper`s policy recommendations include improving external financial links, molding terms of trade contingencies into anti-cyclical policies, Improving liquidity aggregation through and within the banking sector during crises, and improving the liquidity and immediacy of domestic financial instruments

Why are Prices Sticky? Evidence from Business Survey Data

This paper offers new insights on the price setting behaviour of German retail firms using a novel dataset that consists of a large panel of monthly business surveys from 1991-2006. The firm-level data allows matching changes in firms' prices to several other firm-characteristics. Moreover, information on price expectations allow analyzing the determinants of price updating. Using univariate and bivariate ordered probit specifications, empirical menu cost models are estimated relating the probability of price adjustment and price updating, respectively, to both time- and state- dependent variables. First, results suggest an important role for state-dependence; changes in the macroeconomic and institutional environment as well as firm-specific factors are significantly related to the timing of price adjustment. These findings imply that price setting models should endogenize the timing of price adjustment in order to generate realistic predictions concerning the transmission of monetary policy. Second, an analysis of price expectations yields similar results providing evidence in favour of state-dependent sticky plan models. Third, intermediate input cost changes are among the most important determinants of price adjustment suggesting that pricing models should explicitly incorporate price setting at different production stages. However, the results show that adjustment to input cost changes takes time indicating "additional stickiness" at the last stage of processing

Effect of Barley on Liver Histology of Rainbow Trout, Oncorhynchus mykiss

[EN] This study investigated the effects of the incorporation of barley instead of wheat to study fish growth and biometrics parameters, body composition, retention efficiency and liver histology of rainbow trout Oncorhynchus mykiss. Experimental diets were used containing different barley concentrations (0-16%) randomly assigned to four groups per treatment. Results showed a significant change on liver histological parameters. Liver cell vacuolization was significantly lower on fish fed with 16B diets compared to control diet and revealed some degeneration. Those fish also showed more regular hepatocytes than in control diet.This work has been co-funded with FEDER and INIA funds (call 2012, BOE-2012-13337).Pinedo-Gil, J.; Martín-Diana, AB.; Caballero-Cansino, MJ.; Sanz-Calvo, MÁ.; Jover Cerda, M.; Tomas-Vidal, A. (2017). Effect of Barley on Liver Histology of Rainbow Trout, Oncorhynchus mykiss. Journal of Aquaculture & Marine Biology. 5(3). https://doi.org/10.15406/jamb.2017.05.00123S5