The behaviour of reinforced concrete slabs in fire

In this paper a robust model is presented based on the previous layer procedure developed by the author to also take into account the effects of concrete spalling on the behaviour of concrete slabs under fire conditions. In this study, a detailed analysis of a uniformly loaded reinforced concrete slab subject to different degrees of concrete spalling under a standard fire regime is first carried out. Further, a series of analysis of floor slabs with different degrees of concrete spalling is also performed on a generic reinforced concrete building. A total of 16 cases have been analysed using different degrees of spalling on the slabs, with different extents and positions of localised fire compartments. It is clear that adjacent cool structures provide considerable thermal restraint to the floor slabs within the fire compartment. And it is evident that the compressive membrane force within the slabs is a major player in reducing the impact of concrete spalling on the structural behaviour of floor slabs in fire. (C) 2010 Elsevier Ltd. All rights reserved

Shareholder Activism: Evidence from China’s Split Share Structure Reform

本文旨在研究新兴资本市场中，机构投资者作为公司治理的积极参与者所发挥的作用。2005年发生在中国的股权分置改革为我们提供了一个理想的研究背景。在这次股权分置改革之前，上市公司的股权被高度集中在一个或者几个大股东手上，通常为国有股或者创始人家族持股，他们所持有的股份均为非流通股。与此同时，上市公司的一小部分股份被流通股股东所持有，而他们当中最大的股东是机构投资者。在这股权分置改革过程中，两类股东将会协商谈判，非流通股大股东将会对流通股股东给予赔偿来换取其非流通股获得流通的权利。为了研究机构投资者在这谈判过程中，是否发挥了作为积极有效的股东角色的作用。我们对机构投资者与赔偿方案进行了回归，来分析这...The purpose of this paper is to investigate the function of institutional investors as active participants in the corporate governance of targeted companies in emerging capital markets. In 2005, the split share structure reform initiated in China and its negotiating character present us with an ideal research environment. Before the reform, the ownership structure of public companies was highly co...学位：金融硕士院系专业：王亚南经济研究院_金融学学号：2772014115463

Mechanochemical synthesis and characterization of nanodimensional iron–cobalt spinel oxides

Iron–cobalt spinel oxide nanoparticles, CoxFe3−xO4 (x = 1, 2), of sizes below 10 nm have been prepared by combining chemical precipitation with high-energy ball milling. For comparison, their analogues obtained by thermal synthesis have also been studied. The phase composition and structural properties of the obtained materials have been investigated by means of X-ray diffraction, Mössbauer spectroscopy, infrared spectroscopy, temperature-programmed reduction and magnetization measurements. X-ray diffraction shows that after 1 h of mechanical treatment ferrites are formed. The measurement techniques employed indicate that longer milling induces an increase in crystal size while crystal defects decrease with treatment time. Magnetization and reduction properties are affected by the particles size, the iron/cobalt ratio and the synthesis conditions

Spark plasma sintering synthesis of Ni1−xZnxFe2O4 ferrites: Mössbauer and catalytic study

Nickel-zinc ferrite nanoparticles, Ni1-xZnxFe2O4 (x ¼ 0, 0.2, 0.5, 0.8, 1.0) were prepared by combination of chemical precipitation and spark plasma sintering (SPS) techniques and conventional thermal treatment of the obtained precursors. The phase composition and structural properties of the obtained materials were investigated by X-ray diffraction and Mössbauer spectroscopy and their catalytic activity in methanol decomposition was tested. A strong effect of reaction medium leading to the transformation of ferrites to a complex mixture of different iron containing phases was detected. A tendency of formation of Fe-carbide was found for the samples synthesized by SPS, while predominantly iron-nickel alloys ware registered in TS obtained samples. The catalytic activity and selectivity in methanol decomposition to CO and methane depended on the current phase composition of the obtained ferrites, which was formed by the influence of the reaction medium

Finite element crack width computations with a thermo-hygro-mechanical-hydration model for concrete

The paper presents an overview of a finite element approach for the analysis of the thermo-hygro-mechanical-hydration behaviour of concrete structures. The thermo-hygro component considers the mass balance equation of moisture as well as the enthalpy balance equation, and uses two primary variables, namely the capillary pressure and temperature. Heat of hydration is simulated using the approach of Schlinder and Folliard. The basic mechanical model simulates directional cracking, rough crack closure and crushing using a plastic-damage-contact approach. Hydration dependency is introduced into the mechanical constitutive model. The material data from the Concrack benchmark (CEOS.fr,2013) are considered with the model. This includes data on adiabatic temperature changes during curing, changing elastic properties during curing, shrinkage and creep. The model, as implemented in the finite element program LUSAS, is used to analyse the Concrack benchmark beam RL1. Particular attention is paid to crack openings and the difference between predicted crack openings from analyses with and without time dependent effects. It is concluded that ignoring time dependent effects can result in a significant under-estimate of crack openings in the working load range

A plastic-damage-contact constitutive model for concrete with smoothed evolution functions

A new 3D finite element concrete model is described. The model brings together two recently developed sub-models for simulating cracking and crack contact behaviour, both of which use smoothed evolution functions, with a triaxial plasticity model component. A number of examples are presented that validate the model using a range of plain and reinforced concrete test data. These examples demonstrate that the model is numerically robust, has good equilibrium convergence performance and is objective with respect to mesh grading and increment size. The examples also illustrate the model’s ability to predict peak loads, failure modes and post-peak responses

The proper generalized decomposition for the simulation of delamination using cohesive zone model

The use of cohesive zone models is an efficient way to treat the damage, especially when the crack path is known a priori. This is the case in the modeling of delamination in composite laminates. However, the simulations using cohesive zone models are expensive in a computational point of view. When using implicit time integration scheme or when solving static problems, the non-linearity related to the cohesive model requires many iterations before reaching convergence. In explicit approaches, the time step stability condition also requires an important number of iterations. In this article, a new approach based on a separated representation of the solution is proposed. The Proper Generalized Decomposition is used to build the solution. This technique, coupled with a cohesive zone model, allows a significant reduction of the computational cost. The results approximated with the PGD are very close to the ones obtained using the classical finite element approach

Role of the Various Surface Sites and Species in CO Hydrogenation Over Alumina-supported Co-Pd Catalysts

The paper is focused on evaluation of active centres and impact of adsorbed species on (10%Co+0.5%Pd)/Al2O3 catalyst system performance aiming selectivity optimization. Application of different sets of precursor pretreatment and reduction resulted in catalysts exhibiting high CO conversion or high methane selectivity. A sample of high selectivity was prepared by pretreatment in hydrogen and the performance was determined by lower amount of strongly adsorbed CO, strongly adsorbed carbonate species, and higher amount of reduced metal and bimetallic particles. A more active system was formed by pretreatment in air leading to larger amount of unreduced metal and CO-bridged species on the surface, stable coverage of hydroxyl groups on the support, and medium-strength sites for adsorption of carbonates. Ratios of hydrogen to carbon monoxide adsorption (H/СО) and of strongly to weakly adsorbed СО species appeared as important criteria for catalyst efficiency together with supported metal state, amount of unreduced ions, bimetallic particle formation, and alumina’s ability to adsorb CO and CO2. This work is licensed under a Creative Commons Attribution 4.0 International License

Nanosized iron and iron–cobalt spinel oxides as catalysts for methanol decomposition

Nanosized iron and mixed iron–cobalt oxides supported on activated carbon materials and their bulk analogues prepared by thermal synthesis are studied by X-rays diffraction, Mo¨ssbauer spectroscopy, magnetic measurements and temperature programmed reduction. Their catalytic behavior in methanol decomposition to H2, CO and methane is tested. Phase transformations in the metal oxides affected by the reaction medium are also investigated. Changes in the reaction mechanism of the methanol decomposition after the metal oxides deposition on the support as compared to the bulk phases are discussed