3 research outputs found
Synchronization of spatiotemporal semiconductor lasers and its application in color image encryption
Optical chaos is a topic of current research characterized by
high-dimensional nonlinearity which is attributed to the delay-induced
dynamics, high bandwidth and easy modular implementation of optical feedback.
In light of these facts, which adds enough confusion and diffusion properties
for secure communications, we explore the synchronization phenomena in
spatiotemporal semiconductor laser systems. The novel system is used in a
two-phase colored image encryption process. The high-dimensional chaotic
attractor generated by the system produces a completely randomized chaotic time
series, which is ideal in the secure encoding of messages. The scheme thus
illustrated is a two-phase encryption method, which provides sufficiently high
confusion and diffusion properties of chaotic cryptosystem employed with unique
data sets of processed chaotic sequences. In this novel method of cryptography,
the chaotic phase masks are represented as images using the chaotic sequences
as the elements of the image. The scheme drastically permutes the positions of
the picture elements. The next additional layer of security further alters the
statistical information of the original image to a great extent along the
three-color planes. The intermediate results during encryption demonstrate the
infeasibility for an unauthorized user to decipher the cipher image. Exhaustive
statistical tests conducted validate that the scheme is robust against noise
and resistant to common attacks due to the double shield of encryption and the
infinite dimensionality of the relevant system of partial differential
equations.Comment: 20 pages, 11 figures; Article in press, Optics Communications (2011
Thermally activated peroxydisulfate in the presence of additives: A clean method for the degradation of pollutants
The kinetics and mechanism of the thermal activation of peroxydisulfate, in the temperature range from 60 to 80 degrees C, was investigated in the presence and absence of sodium formate as an additive to turn the oxidizing capacity of the reaction mixture into a reductive one. Trichloroacetic acid, TCA, whose degradation by a reductive mechanism is well reported in the literature, was used as a probe. The chemistry of thermally activated peroxydisulfate is described by a reaction scheme involving free radical generation. The proposed mechanism is evaluated by a computer simulation of the concentration profiles obtained under different experimental conditions. In the presence of formate, SO(4)(center dot-) radicals yield CO(2)(center dot-), which are the main species available for degrading TCA. Under the latter conditions, TCA is more efficiently depleted than in the absence of formate, but otherwise identical conditions of temperature and [S(2)O(8)(2-)]. We therefore conclude that activated peroxydisulfate in the presence of formate as an additive is a convenient method for the mineralization of substrates that are refractory to oxidation. such as perchlorinated hydrocarbons and TCA. This method has the advantage that leaves no toxic residues. (C) 2009 Elsevier Ltd. All rights reserved.ANPCyT, Argentina[PICT 2003 14508