The influence of potassium on core and geodynamo evolution

We model the thermal evolution of the core and mantle using a parametrized convection scheme, and calculate the entropy available to drive the geodynamo as a function of time. The cooling of the core is controlled by the rate at which the mantle can remove heat. Rapid core cooling favours the operation of a geodynamo but creates an inner core that is too large; slower cooling reduces the inner core size but makes a geodynamo less likely to operate. Introducing potassium into the core retards inner core growth and provides an additional source of entropy. For our nominal model parameters, a core containing approximate to 400 ppm potassium satisfies the criteria of present-day inner core size, surface heat flux, mantle temperature and cooling rate, and positive core entropy production.We have identified three possibilities that may allow the criteria to be satisfied without potassium in the core. (1) The core thermal conductivity is less than half the generally accepted value of 50 W m(-1) K-1. (2) The core solidus and adiabat are significantly colder and shallower than results from shock experiments and ab initio simulations indicate. (3) The core heat flux has varied by no more than a factor of 2 over Earth history. All models we examined with the correct present-day inner core radius have an inner core age of < 1.5 Gyr; prior to this time the geodynamo was sustained by cooling and radioactive heat production within a completely liquid core

Ecological effects and environmental fate of solid rocket exhaust

Specific target processes were classified as to the chemical, chemical-physical, and biological reactions and toxic effects of solid rocket emissions within selected ecosystems at Kennedy Space Center. Exposure of Citris seedlings, English peas, and bush beans to SRM exhaust under laboratory conditions demonstrated reduced growth rates, but at very high concentrations. Field studies of natural plant populations in three diverse ecosystems failed to reveal any structural damage at the concentration levels tested. Background information on elemental composition of selected woody plants from two terrestrial ecosystems is reported. LD sub 50 for a native mouse (peromysous gossypinus) exposed to SRM exhaust was determined to be 50 ppm/g body weight. Results strongly indicate that other components of the SRM exhaust act synergically to enhance the toxic effects of HCl gas when inhaled. A brief summary is given regarding the work on SRM exhaust and its possible impact on hatchability of incubating bird eggs

Can indices of ecological evenness be used to measure consensus?

In the context of group decision making with fuzzy preferences, consensus measures are employed to provide feedback and help guide automatic or semi-automatic decision reaching processes. These measures attempt to capture the intuitive notion of how much inputs, individuals or groups agree with one another. Meanwhile, in ecological studies there has been an ongoing research effort to define measures of community evenness based on how evenly the proportional abundances of species are distributed. The question hence arises as to whether there can be any cross-fertilization from developments in these fields given their intuitive similarity. Here we investigate some of the models used in ecology toward their potential use in measuring consensus. We found that although many consensus characteristics are exhibited by evenness indices, lack of reciprocity and a tendency towards a minimum when a single input is non-zero would make them undesirable for inputs expressed on an interval scale. On the other hand, we note that some of the general frameworks could still be useful for other types of inputs like ranking profiles and that in the opposite direction consensus measures have the potential to provide new insights in ecology

Quasideterminant solutions of a non-Abelian Hirota-Miwa equation

A non-Abelian version of the Hirota-Miwa equation is considered. In an earlier paper [Nimmo (2006) J. Phys. A: Math. Gen. \textbf{39}, 5053-5065] it was shown how solutions expressed as quasideterminants could be constructed for this system by means of Darboux transformations. In this paper we discuss these solutions from a different perspective and show that the solutions are quasi-Pl\"{u}cker coordinates and that the non-Abelian Hirota-Miwa equation may be written as a quasi-Pl\"{u}cker relation. The special case of the matrix Hirota-Miwa equation is also considered using a more traditional, bilinear approach and the techniques are compared

On a direct approach to quasideterminant solutions of a noncommutative KP equation

A noncommutative version of the KP equation and two families of its solutions expressed as quasideterminants are discussed. The origin of these solutions is explained by means of Darboux and binary Darboux transformations. Additionally, it is shown that these solutions may also be verified directly. This approach is reminiscent of the wronskian technique used for the Hirota bilinear form of the regular, commutative KP equation but, in the noncommutative case, no bilinearising transformation is available.Comment: 11 page

Evaluating unsupervised methods to size and classify suspended particles using digital in-line holography

Substantial information can be gained from digital in-line holography of marine particles, eliminating depth-of-field and focusing errors associated with standard lens-based imagingmethods.However, for the technique to reach its full potential in oceanographic research, fully unsupervised (automated) methods are required for focusing, segmentation, sizing, and classification of particles. These computational challenges are the subject of this paper, in which the authors draw upon data collected using a variety of holographic systems developed at Plymouth University, United Kingdom, from a significant range of particle types, sizes, and shapes. A new method for noise reduction in reconstructed planes is found to be successful in aiding particle segmentation and sizing. The performance of an automated routine for deriving particle characteristics (and subsequent size distributions) is evaluated against equivalent size metrics obtained by a trained operative measuring grain axes on screen. The unsupervised method is found to be reliable, despite some errors resulting from oversegmentation of particles. A simple unsupervised particle classification system is developed and is capable of successfully differentiating sand grains, bubbles, and diatoms from within the surfzone. Avoiding miscounting bubbles and biological particles as sand grains enables more accurate estimates of sand concentrations and is especially important in deployments of particle monitoring instrumentation in aerated water. Perhaps the greatest potential for further development in the computational aspects of particle holography is in the area of unsupervised particle classification. The simple method proposed here provides a foundation upon which further development could lead to reliable identification of more complex particle populations, such as those containing phytoplankton, zooplankton, flocculated cohesive sediments, and oil droplets

Expanding the scope of alkyne-mediated bioconjugations utilizing unnatural amino acids

The importance of bioconjugates within the field of chemistry drives the need for novelmethodologies for their preparation. Well-defined and stable bioconjugates are easily accessible via the utilization of unnatural amino acids (UAAs). As such, we have synthesized and incorporated two new UAAs into green fluorescent protein, and optimized a novel Cadiot-Chodkiewicz bioconjugation, effectively expanding the toolbox of chemical reactions that can be employed in the preparation of bioconjugates