Electrokinetic Control of Viscous Fingering

We present a theory of the interfacial stability of two immiscible electrolytes under the coupled action of pressure gradients and electric fields in a Hele-Shaw cell or porous medium. Mathematically, our theory describes a phenomenon of "Vector Laplacian Growth", in which the interface moves in response to the gradient of a vector-valued potential function through a generalized mobility tensor. Physically, we extend classical Saffman-Taylor problem to electrolytes by incorporating electrokinetic phenomena. A surprising prediction is that viscous fingering can be controlled by varying the injection ratio of electric current to flow rate. Beyond a critical injection ratio, stability depends only upon the relative direction of flow and current, regardless of the viscosity ratio. Possible applications include porous materials processing, electrically enhanced oil recovery, and electrokinetic remediation of contaminated soils.Comment: * Fixed a few typos * Added new discussion of possible liquid pairs * Added new reference

Freezing point depression and freeze-thaw damage by nano-fuidic salt trapping

A remarkable variety of organisms and wet materials are able to endure temperatures far below the freezing point of bulk water. Cryo-tolerance in biology is usually attributed to "anti-freeze" proteins, and yet massive supercooling ($< -40^\circ$C) is also possible in porous media containing only simple aqueous electrolytes. For concrete pavements, the common wisdom is that freeze-thaw damage results from the expansion of water upon freezing, but this cannot explain the large pressures ($> 10$~MPa) required to damage concrete, the observed correlation between pavement damage and de-icing salts, or the damage of cement paste loaded with benzene (which contracts upon freezing). In this Letter, we propose a different mechanism -- nanofluidic salt trapping -- which can explain the observations, using simple mathematical models of dissolved ions confined to thin liquid films between growing ice and charged surfaces. Although trapped salt lowers the freezing point, ice nucleation in charged pores causes enormous disjoining pressures via the rejected ions, until their removal by precipitation or surface adsorption at a lower temperatures releases the pressure and allows complete freezing. The theory is able to predict the non-monotonic salt-concentration dependence of freeze-thaw damage in concreter and provides a general framework to understand the origins of cryo-tolerance.Comment: 5 figure

Accommodating energy price volatility in life cycle cost analysis of asphalt pavements

Energy price is related to more than half of the total life cycle cost of asphalt pavements. Furthermore, the fluctuation related to price of energy has been much higher than the general inflation and interest rate. This makes the energy price inflation an important variable that should be addressed when performing life cycle cost (LCC) studies re- garding asphalt pavements. The present value of future costs is highly sensitive to the selected discount rate. Therefore, the choice of the discount rate is the most critical element in LCC analysis during the life time of a project. The objective of the paper is to present a discount rate for asphalt pavement projects as a function of interest rate, general inflation and energy price inflation. The discount rate is defined based on the portion of the energy related costs during the life time of the pavement. Consequently, it can reflect the financial risks related to the energy price in asphalt pavement projects. It is suggested that a discount rate sensitivity analysis for asphalt pavements in Sweden should range between –20 and 30%

Modification of as-cast Al-Mg/B4C composite by addition of Zr

Zirconium was used in Al-Mg/B4C composite to improve compocasting efficiency by increasing particle incorporation. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) results revealed that by addition of zirconium a reaction layer containing Zr, Al, B and C is formed on the interface of B4C-matrix. X-ray diffraction (XRD) analysis of extracted particles unveiled that the ZrB2 phase is the main constituent of this layer. Formation of ZrB2 is an exothermic reaction which can rise temperature locally around particles and agglomerates. Rising temperature around agglomerates in conjunction with turbulent flow of melt facilitates agglomerates wetting and dissolving into molten aluminum. As the result, final product contains more uniformly distributed B4C particles. Besides enhancing compocasting efficiency, addition of Zr and formation of reaction layer by improving particle matrix bonding quality, led to increase in ultimate tensile strength and elongation of the composite around 8% and 30%, respectively. SEM observations of the fracture surfaces confirmed that a proper bonding presents at the interface of particles and matrix in presence of Zr.Peer ReviewedPostprint (author's final draft

Introduction to Iran's Judicial System

The function of the courts in the Iranian post-Islamic revolution constitutional law may be analyzed by reference to a number of different considerations of procedural reforms: the abolition of pre-revolution courts; the establishment of new courts such as the clerical and the revolutionary one; the matter of radical changes due to procedural criminal law aiming to "Islamicize" the judicial system; and the classes of situations in which court's jurisdiction may be raised. On the other hand, the introduction of Islamic decisive factors as the basis for judgments resulting in the obvious challenges to the international norms, the nature characteristics and effects of the remedies and sanctions they may award, and many other matters can be listed in the substantive evolutions. A comprehensive analysis would be unbearably wordy and recurring. However, a brief preliminary survey may help to provide a clearer image of the judiciary in Iran. Keywords: Iran; Human Rights; Islam; Judiciar

Wettability and osteoblast cell response modulation through UV laser processing of nylon 6,6

With an ageing population the demand for cheap, efficient implants is ever increasing. Laser surface treatment offers a unique means of varying biomimetic properties to determine generic parameters to predict cell responses. This paper details how a KrF excimer laser can be employed for both laser-induced patterning and whole area irradiative processing to modulate the wettability characteristics and osteoblast cell response following 24 hour and 4 day incubation. Through white light interferometry (WLI) it was found that the surface roughness had considerably increased by up to 1.5 µm for the laser-induced patterned samples and remained somewhat constant at around 0.1 µm for the whole area irradiative processed samples. A sessile drop device determined that the wettability characteristics differed between the surface treatments. For the patterned samples the contact angle, θ, increased by up to 25° which can be attributed to a mixed-state wetting regime. For the whole area irradiative processed samples θ decreased owed to an increase in polar component, γP. For all samples θ was a decreasing function of the surface energy. The laser whole area irradiative processed samples gave rise to a distinct correlative trend between the cell response, θ and γP. However, no strong relationship was determined for the laser-induced patterned samples due to the mixed-state wetting regime. As a result, owed to the relationships and evidence of cell differentiation one can deduce that laser whole area irradiative processing is an attractive technology for employment within regenerative medicine to meet the demands of an ageing population