Beyond categorization: new directions for theory development about entrepreneurial internationalization

Categorizations emphasizing the earliness of internationalization have long been a cornerstone of international entrepreneurship research. Here we contend that the prominence of categories has not been commensurate with theory development associated with them. We draw on categorization theory to explain why earliness-based categories are persistent, and argue that a greater focus on notions related to opportunity can open new avenues of research about the entrepreneurial internationalization of business. We propose and discuss three directions for opportunity-based research on entrepreneurial internationalization, involving context, dynamics and variety

Entrepreneurial orientation and international performance: the moderating effect of decision-making rationality

This research examines how entrepreneurial orientation (EO) influences international performance (IP) of the firm taking into account the moderating effect of decision-making rationality (DR) on the EO–IP association. Such an investigation is significant because it considers the interplay of strategic decision-making processes supported by the bounded rationality concept in the entrepreneurship field. Drawing from a study on activities of 216 firms in the United States and United Kingdom, the evidence suggests that DR positively moderates the EO–IP association. The findings suggest that managers can improve IP by combining EO with rational (analytical) processes in their strategic decisions

Transfer dehydrogenation of 1-Phenylethanol over Pd/C under mild conditions: effect of reaction conditions and optimization of catalytic performance

The catalytic activity of 5 wt% Pd/C has been evaluated using the liquid phase transfer dehydrogenation of 1-phenylethanol as a model reaction. The reaction parameters such as catalyst loading and stirring rate have been optimized to determine the required conditions to carry out the reaction under kinetic regime control. By performing the reaction under different temperatures, the value of apparent activation energy has been determined as being 61 kJ/mol. Furthermore, the influence of thermal treatment of 5 wt% Pd/C catalyst on its catalytic performance for the liquid phase transfer dehydrogenation of 1-phenylethanol has been investigated in a temperature range of 110–200 °C. The results reveal that the catalyst activity is strongly dependent on the ratio between Pd/PdO species. The fresh and used catalysts were characterized using a range of characterization techniques (XRPD, XPS, TEM, SEM-EDX, and BET) in order to investigate structure–activity relationships. The 5 wt% Pd/C exhibit high conversion (90%) and selectivity (91%) toward acetophenone under mild conditions. Moreover, the reusability tests have been carried out, and the results show that the catalyst preserves 80% of its initial catalytic activity after five cycles indicating the high stability of the 5 wt% Pd/C catalyst in the liquid phase transfer dehydrogenation of 1-phenylethanol. The influence of reaction conditions on the catalytic activity is also discussed

Problem-solving dissension and international entry mode performance

Purpose: The purpose of this paper is to examine international decision making, information processing, and related performance implications. The authors aim to explore the relationship between international decision making and problem-solving dissensions related to entry mode decisions. In addition, they aim to investigate the effects of dissension on entry mode performance, and the moderating effect of the foreign direct investment (FDI) vs non-FDI decision as it relates to dissension- mode performance. Despite their significance from an information processing perspective, these issues have not been sufficiently explored in international entry mode research. Design/methodology/approach: This research presents data collected from 233 privately owned internationalized Chinese firms. The analysis in this investigation includes hierarchical ordinary least squares regression. Findings: The findings suggest an inverse U-shaped relationship between dissension and entry mode performance, as opposed to a linear one, and a moderating effect of FDI vs non-FDI decisions on this curvilinear dissension-performance association. These findings support and refine the rationale of the information processing perspective. Originality/value: These findings add realistic elements to the alleged “ rational ” international decision-making doctrine assumed in previous entry mode literature. The findings show the importance of the heterogeneity of information processing in entry mode strategic decision-making processes (SDMPs), and its effects on specific decision types. The authors believe that this is the first empirical study to use an information processing perspective to examine the effects of SDMPs on entry mode performance

Catalytic transformation of renewables (Olefin, bio‐sourced, et al.)

The objective of this Special Issue is to provide new diverse contributions that can demonstrate recent applications in biomass transformation using heterogeneous catalysts. In recent decades, a wide variety of biomass-derived chemicals have emerged as key platform chemicals for the production of fine chemicals and liquid fuels using heterogeneous catalysts as the preferred option for most of the developed and proposed catalytic processes. A range of heterogeneous catalysts have been evaluated for effective biomass conversion, such as supported metal nanoparticles, mixed metal oxides and zeolites, where the control of particle size, porosity, acid-basic and redox properties is crucial for providing active, stable and selective heterogeneous catalysts. Moreover, the crucial role of the solvent, choice of reactor design and final chemical processes for controlling activity, selectivity and deactivation phenomena has been demonstrate

Pd/ZnO catalysts for direct CO2 hydrogenation to methanol

The direct hydrogenation of CO2 into methanol is crucial for providing a means of CO2 fixation and a way to store cleanly produced hydrogen in a more energy-dense and transportable form. Here we have prepared two series of Pd/ZnO catalysts, both by immobilisation of PVA-protected Pd colloids and by Pd impregnation of PdCl2 to investigate structure activity relationships for direct CO2 hydrogenation. Very different performances were found for the different preparation methods, and the Pd loading and pre-reduction of the catalysts were shown to be important factors for optimising methanol yield. The crucial factor for high methanol yield is the formation of a Pd–Zn alloy, either during the reaction itself, or better by high temperature pre-reduction. The formation of the alloy greatly reduces CO production by the reverse water gas shift reaction. The catalysts prepared by sol-immobilisation were relatively stable to thermal treatment. In contrast, the impregnated catalysts were much less thermally stable, due to the presence of remnant chloride on the surface of the catalyst, which was absent for the case of sol immobilisation preparation. The results illustrate the importance of controlling the PdZn particle size and its surface structure for the catalysts to achieve high methanol selectivity (60%, the rest being CO) and conversion (11%) at 250 °C and 20 bar. Selectivity for sol-immobilised catalysts decreases from 60% at 3 nm average diameter, to 20% at 7 nm

A Career in Catalysis: Laura Prati

This account celebrates the long and successful scientific career of Laura Prati, recalling her most important scientific achievements since the beginning of her work as a researcher in inorganic chemistry. Laura went through many aspects of liquid-phase heterogeneous catalysis, taking her first steps in the field of catalysts synthesis, where she pursued the development of innovative strategies for preparing catalysts until laying the foundations of the colloidal synthesis of metal nanoparticles, with particular interest in gold. Her investigations in colloids for catalysis had a natural outcome on catalysts synthesis and optimization. In her career, she dealt with liquidphase oxidation reactions, with particular attention to biomass valorization processes. According to this, she could not help to deal also with hydrogenation and hydrogenolysis reactions, to which she dedicated herself, especially in the more recent years. Her discoveries have influenced many researchers in the area of heterogeneous catalysis and design of materials

Optimization of sol-immobilized bimetallic Au–Pd/TiO2 catalysts: reduction of 4-nitrophenol to 4-aminophenol for wastewater remediation

A sol-immobilization method is used to synthesize a series of highly active and stable AuxPd1−x/TiO2 catalysts (where x = 0, 0.13, 0.25, 0.5, 0.75, 0.87 and 1) for wastewater remediation. The catalytic performance of the materials was evaluated for the catalytic reduction of 4-nitrophenol, a model wastewater contaminant, using NaBH4 as the reducing agent under mild reaction conditions. Reaction parameters such as substrate/metal and substrate/reducing agent molar ratios, reaction temperature and stirring rate were investigated. Structure-activity correlations were studied using a number of complementary techniques including X-ray powder diffraction, X-ray photoelectron spectroscopy and transmission electron microscopy. The sol-immobilization route provides very small Au–Pd alloyed nanoparticles, with the highest catalytic performance shown by the Au0.5Pd0.5/TiO2 catalyst.This article is part of a discussion meeting issue ‘Science to enable the circular economy’

The effect of carbon nanofibers surface properties in hydrogenation and dehydrogenation reactions

In this study, carbon nanofiber-supported Pd nanoparticles were used in the hydrogenation of cinnamaldehyde and in the dehydrogenation of cinnamyl alcohol. The different graphitisation of the surface of the nanofibers and the amount of oxygen functionalisation significantly affected both activity and selectivity to the various reaction products. In particular, a decrease in nanoparticle dimensions and oxygen content resulted in an increase in overall activity for both of the studied reactions. Moreover, the selectivity to hydrocinnamaldehyde enhanced with increasing surface oxygen content in the cinnamaldehyde hydrogenation, while the selectivity to cinnamaldehyde was higher with low-functionalised nanofibers in the cinnamyl alcohol dehydrogenation. Finally, the most active catalyst proved also to be stable in consecutive runs