Intonation Awareness

Young instrumentalists are taught to press buttons or keys to make pitches sound from their instruments, but that doesn\u27t always ensure that they are in the center of the pitch. It also doesn\u27t ensure that they are in tune with those around them. It is important to improve awareness that pitch is not only physical, but conceptual as well. It is important that instrumentalists know how to center pitch and make adjustments while playing their individual instruments, to compensate for tendencies of said instrument. There are many ways to practice this. I met with four flutists three times to try to help them with this process. They sang, used tuners, and created a journal. All of this helped increase awareness of playing in tune. In the end, they found out what adjustments they needed to make individually to get the pitch closer to the center

L'"identità" di scienza e filosofia in Ugo Spirito

"Io sono stato discepolo di Giovanni Gentile - così risuonarono le solenni parole di tale professione di fede nella grigia ma non sorda aula universitaria-, e per quanto la mia modestissima statura non sia paragonabile alla levatura del Gentile, io voglio continuare a dirmi discepolo di Giovanni Gentile". La gran parte del Corso fu dedicata a una densa e articolata "introduzione genetica" all'attualismo - ossia a una storia della filosofia dal punto di vista dell'attualismo stesso -, nonché a una puntuale analisi critica di testi crociani sul rapporto filosofiascienza

An improved synthesis, crystal structures, and metallochromism of salts of [Ru(tolyl-terpy)(CN)(3)](-)

The previously reported complex [Ru(ttpy)(CN)(3)] [ttpy = 4'(p-tolyl)-2,2':6',2"-terpyridine] is conveniently synthesised by reaction of ttpy with Ru(dmso)(4)Cl-2 to give [Ru(ttpy)(dmso)Cl-2], which reacts in turn with KCN in aqueous ethanol to afford [Ru(ttpy)(CN)(3)] which was isolated and crystallographically characterised as both its (PPN)(+) and K+ salts. The K+ salt contains clusters containing three complex anions and three K+ cations connected by end-on and side-on cyanide ligation to the K+ ions. The solution speciation behaviour of [Ru(ttpy)(CN)(3)] was investigated with both Zn2+ and K+ salts in MeCN, a solvent sufficiently non-competitive to allow the added metal cations to associate with the complex anion via the externally-directed cyanide lone pairs. UV-Vis spectroscopic titration of (PPN)[Ru(ttpy)(CN)(3)] with Zn(ClO4)(2) showed a blue shift of 2900 cm (1) in the (MLCT)-M-1 absorption manifold due to the ` metallochromism' effect; a series of distinct binding events could be discerned corresponding to formation of 4:1, 1:1 and then 1:3 anion: cation adducts, all with high formation constants, as the titration proceeded. In contrast titration of (PPN)[Ru(ttpy)(CN)(3)] with the more weakly Lewis-acidic KPF6 resulted in a much smaller blue-shift of the 1MLCT absorptions, and the titration data corresponded to formation of 1:1 and then 2: 1 cation: anion adducts with weaker stepwise association constants of the order of 10(4) and then 10(3) M (1). Although association of [Ru(ttpy)(CN)(3)] resulted in a blue-shift of the (MLCT)-M-1 absorptions, the luminescence was steadily quenched, as raising the (MLCT)-M-3 level makes radiationless decay via a lowlying (MC)-M-3 state possible. (C) 2010 Elsevier B. V. All rights reserved

Quantiles, expectiles and splines

A time-varying quantile can be fitted by formulating a time series model for the corresponding population quantile and iteratively applying a suitably modified state space signal extraction algorithm. It is shown that such quantiles satisfy the defining property of fixed quantiles in having the appropriate number of observations above and below. Like quantiles, time-varying expectiles can be estimated by a state space signal extraction algorithm and they satisfy properties that generalize the moment conditions associated with fixed expectiles. Because the state space form can handle irregularly spaced observations, the proposed algorithms can be adapted to provide a viable means of computing spline-based non-parametric quantile and expectile regressions

Formation and structural chemistry of the unusual cyanide-bridged dinuclear species [Ru-2(NN)(2)(CN)(7)](3-)(NN=2,2 '-bipyridine or 1,10-phenanthroline)

Crystallisation of simple cyanoruthenate complex anions [Ru(NN)(CN)(4)](2) (NN = 2,2'-bipyridine or 1,10-phenanthroline) in the presence of Lewis-acidic cations such as Ln(III) or guanidinium cations results, in addition to the expected [Ru(NN)(CN)(4)](2) salts, in the formation of small amounts of salts of the dinuclear species [Ru-2(NN)(2)(CN)(7)](3). These cyanide-bridged anions have arisen from the combination of two monomer units [Ru(NN)(CN)(4)](2) following the loss of one cyanide, presumably as HCN. The crystal structures of [Nd(H2O)(5.5)][Ru-2(bipy)(2)(CN)(7)] center dot 11H(2)O and [Pr(H2O)(6)][Ru-2(phen)(2)(CN)(7)] center dot 9H(2)O show that the cyanoruthenate anions form Ru-CN-Ln bridges to the Ln(III) cations, resulting in infinite coordination polymers consisting of fused Ru(2)Ln(2)(mu-CN)(4) squares and Ru(4)Ln(2)(mu-CN)(6) hexagons, which alternate to form a one-dimensional chain. In [CH6N3](3)[Ru-2(bipy)(2)(CN)(7)] center dot 2H(2)O in contrast the discrete complex anions are involved in an extensive network of hydrogen-bonding involving terminal cyanide ligands, water molecules, and guanidinium cations. In the [Ru-2(NN)(2)(CN)(7)](3) anions themselves the two NN ligands are approximately eclipsed, lying on the same side of the central Ru-CN-Ru axis, such that their peripheries are in close contact. Consequently, when NN = 4,4'-Bu-t(2)-2,2'-bipyridine the steric bulk of the t-butyl groups prevents the formation of the dinuclear anions, and the only product is the simple salt of the monomer, [CH6N3](2)[Ru((t)Bu(2)bipy)(CN)(4)] center dot 2H(2)O. We demonstrated by electrospray mass spectrometry that the dinuclear by-product [Ru-2(phen)(2)(CN)(7)](3) could be formed in significant amounts during the synthesis of monomeric [Ru(phen)(CN)(4)](2) if the reaction time was too long or the medium too acidic. In the solid state the luminescence properties of [Ru-2(bipy)(2)(CN)(7)](3) (as its guanidinium salt) are comparable to those of monomeric [Ru(bipy)(CN)(4)](2), with a (MLCT)-M-3 emission at 581 nm

Mass Transfer Mechanisms during Dehydration of Vegetable Food: Traditional and Innovative Approaches

Lettera di accettazione in dat

Study of different technological strategies for sugar reduction in muffin addressed for children

Abstract To exceed in sugar consumption is one of the main causes of overweight and obesity, especially for children and adolescent. However, sugar reduction, especially in baked goods, is challenging due to its effect not only on sensorial properties but also for other quality parameters. Multiple technological strategies to obtain muffins at low sugar content addressed for children were studied. Specifically, the inhomogeneous spatial distribution of sucrose (1, 3 and 5 layers of food formula at different sugar content), the taste enhancement by vanillin addition (0, 1 and 2%) and the use of different particle size of sugar (200, 400 and 600 μm) were investigated through a Box-Behnken design. Physical attributes were negatively affected by spatial distribution due to the substantial role of sucrose in the expansion of muffins. Indeed, maximum height of homogeneous muffins was of 37.8 ± 3.9 mm, while in inhomogeneous samples reached values of ≈ 30 mm. The low expansion of inhomogeneous muffins was also attested by porosity fraction which notably decreased from 68.2% in 1-layer muffin to 58.4% and 65.6% in 3-layers and 5-layers muffins, respectively. The perception of sweetness was improved for the inhomogeneous muffins and with a mass fraction of added vanillin at 1% confirming its great potential as taste enhancer, especially when using particle size of sugar less than 400 μm. Based on sensorial and physical data, stratified muffins with 3 layers, a mass fraction of added vanillin at 1% and sugar particle size in the range between 200 and 600 μm, showed excellent results. The proposed strategy could be used to design and develop innovative muffins designed for children contributing in the reduction of sugar intake in the daily diet

N 1,N 2-Bis­(2,6-di­methyl­phen­yl)-N 1-hydroxyformamidine N,N′-bis­(2,6-dimethyl­phen­yl)-N-oxidoformamidinium dichloro­methane solvate

The title compound, 2C17H20N2O·CH2Cl2, was obtained by N-oxidation of the parent formamidine with m-chloro-peroxy­benzoic acid (m-CPBA). This is the first use of the above-mentioned synthetic route for the preparation of hydroxy­amidines. The title compound crystallizes as a cyclic dimer resulting from the presence of O—H⋯O and N—H⋯N hydrogen bonds