Three-phase coexistence with sequence partitioning in symmetric random block copolymers

We inquire about the possible coexistence of macroscopic and microstructured phases in random Q-block copolymers built of incompatible monomer types A and B with equal average concentrations. In our microscopic model, one block comprises M identical monomers. The block-type sequence distribution is Markovian and characterized by the correlation \lambda. Upon increasing the incompatibility \chi\ (by decreasing temperature) in the disordered state, the known ordered phases form: for \lambda\ > \lambda_c, two coexisting macroscopic A- and B-rich phases, for \lambda\ < \lambda_c, a microstructured (lamellar) phase with wave number k(\lambda). In addition, we find a fourth region in the \lambda-\chi\ plane where these three phases coexist, with different, non-Markovian sequence distributions (fractionation). Fractionation is revealed by our analytically derived multiphase free energy, which explicitly accounts for the exchange of individual sequences between the coexisting phases. The three-phase region is reached, either, from the macroscopic phases, via a third lamellar phase that is rich in alternating sequences, or, starting from the lamellar state, via two additional homogeneous, homopolymer-enriched phases. These incipient phases emerge with zero volume fraction. The four regions of the phase diagram meet in a multicritical point (\lambda_c, \chi_c), at which A-B segregation vanishes. The analytical method, which for the lamellar phase assumes weak segregation, thus proves reliable particularly in the vicinity of (\lambda_c, \chi_c). For random triblock copolymers, Q=3, we find the character of this point and the critical exponents to change substantially with the number M of monomers per block. The results for Q=3 in the continuous-chain limit M -> \infty are compared to numerical self-consistent field theory (SCFT), which is accurate at larger segregation.Comment: 24 pages, 19 figures, version published in PRE, main changes: Sec. IIIA, Fig. 14, Discussio

Array data acquisition with wireless LAN telemetry as applied to shallow water tomography in the Barents Sea

This report describes the application of a new technique of digital radio telemetry, based on a recently available wireless Local Area Network Ethernet adapter, to the need for realtime transmission of data from a vertical line array (VLA) of hydrophones to a nearby ship. The report is technical in nature and discusses the design and performance of the system as used during the Barents Sea Polar Front Experiment in August 1992. A key feature of the use of LAN technology in a "telemetry" application is the availability of Transmission Control Protocol (TCP) software for Ethernet hardware that greatly eases the task of achieving error free digital data over a radio link prone to dropouts.Funding was provided by the Long Beach Naval Regional Contracting Center Detachment under Contract N00123-92-C-007l and the Office of Naval Research under Contract N000l4-9l-J-1246

Preliminary acoustic and oceanographic observations from the winter Primer experiment

A joint acoustics and physical oceanography experiment was conducted in the winter of 1997 on the shell break and continental slope south of New England in the Middle Atlantic Bight (figure 1). This experiment, Primer4, provided a seasonal contrast to the previous summer Primer3 experiment and had the same goals and tasks: to study the thermohaline variability and structure of the shelfbreak front and its effects on acoustic propagation. To accomplish the linked oceanographic and acoustic objectives of this experiment, a combination of measurements (fig 2) were made. Seasoar hydrography, shipboard ADCP measurements, Satellite IR sea surface temperature field observations, and AXT drops were employed to study the larger scale oceanographic fields. To study the finer scale, which includes internal waves, a number of rapid-sampling thermistor strings and current meters, including a moored, upward looking ADCP, were deployed. The acoustics components consisted of three 400 Hz tomography transceivers, a 224 Hz source and two hydrophone arrays. To study the geoacoustic parameters in the bottom a number of SUS charges were also deployed. The field setup was approximately the same for both the summer 1996 and winter 1997 experiments; however the weather conditions and the thermal structure of the mixed layer were radically different. This report is dedicated to the data from the Winter 1997 Primer4 experiment.Funding was provided by the Offce of Naval Research under Contract No. NOOOl4-98-10413

Laser welding of tailored blanks made of Al-Si-coated 22MnB5 steel using a filler wire and a variable energy distribution laser optics

Laser welding of Al-Si-coated steels for hot stamping in automotive applications is problematic due to the mixing of the coating layers inside the molten pool that weakens the resulting weld seam. In this case, the most common welding procedure to overcome this issue consists in removing the Al-Si layer through laser ablation prior to the joining. This method continues to be the most widely used by major producers of tailor welded blanks, although in situ ablation of the Al-Si coating can be costly and time consuming. In this work, a novel approach consisting in joining as-received (i.e., not decoated) materials using a filler wire and an innovative variable energy distribution laser optics is introduced and tested on tailor welded blanks made of 22MnB5. Tensile tests of specimens obtained from a 3(3) full factorial design of experiment have shown an average value of ultimate tensile strength of 1523 MPa, which is much higher than the one usually observed in as-received welded then hot-stamped conditions and aligned with hot-stamped base material values. Hardness test results (494-543 HV0.5) were in the typical hot-stamped base material range of values as well, while SEM-EDS analyses detected no ferrite inclusions inside the fusion zone. Variations of the main process parameters have been considered on an iso-thickness and iso-material configuration, empirically demonstrating the stability and reliability of the proposed methodology as well as its suitability for production purposes

A State-Dependent Quantification of Climate Sensitivity Based On Paleodata of the Last 2.1 Million Years

The evidence from both data and models indicates that specific equilibrium climate sensitivity S[X]—the global annual mean surface temperature change (ΔTg) as a response to a change in radiative forcing X (ΔR[X])—is state dependent. Such a state dependency implies that the best fit in the scatterplot of ΔTg versus ΔR[X] is not a linear regression but can be some nonlinear or even nonsmooth function. While for the conventional linear case the slope (gradient) of the regression is correctly interpreted as the specific equilibrium climate sensitivity S[X], the interpretation is not straightforward in the nonlinear case. We here explain how such a state-dependent scatterplot needs to be interpreted and provide a theoretical understanding—or generalization—how to quantify S[X] in the nonlinear case. Finally, from data covering the last 2.1 Myr we show that—due to state dependency—the specific equilibrium climate sensitivity which considers radiative forcing of CO2 and land ice sheet (LI) albedo, math formula, is larger during interglacial states than during glacial conditions by more than a factor 2

Judging distance across texture discontinuities

Sinai et al (1998 Nature 395 497 - 500) showed that less distance is perceived along a ground surface that spans two differently textured regions than along a surface that is uniformly textured. We examined the effect of texture continuity on judged distance using computer-generated displays of simulated surfaces in five experiments. Discontinuities were produced by using different textures, the same texture reversed in contrast, or the same texture shifted horizontally. The simulated surface was either a ground plane or a frontoparallel plane. For all textures and both orientations, less distance was judged in the discontinuous conditions than in continuous conditions. We propose that when a surface contains a texture discontinuity, a small area adjacent to the perceived boundary is excluded from judged distances

Comparison of Early Model Forecasts With Satellite Data

The evaluation of hurricane forecast skill requires ensembles of historical forecasts. The purpose of this article is not to undertake such an evaluation, but rather to demon strate the current status of satellite physical retrievals and their potential to provide valu able information for such evaluations and contribute to model improvements. Predictions The hurricane in the ECMWF forecast, though, deviates by two to three degrees east of the best track, and makes landfall between Ala bama and Florida about 12 hours late. These differences in the hurricane track and accu mulated precipitation may reflect inadequa cies in the large-scale circulation provided in the initial conditions, or imperfect model physical parameterizations, but also may be due to the system&apos;s lack of predictability. Developments in Hurricane Forecasts Advances in spaceborne observations and numerical weather prediction (NWP) models provide new opportunities for improving hurricane forecasts. Apart from their impor tance for NWR global atmospheric models of hurricanes and their forecasts represent an important and unique test bed of model formulations. Recent developments that include moving from synoptic-scale-resolving to mesoscaleresolving global models show some very encouraging results. In addition to increasing resolution and including more physically based parameterizations on mesoscale effects in conventional general circulation models, cloud-scale-resolving global models-in which the cloud dynamics and mesoscale processes are explicitly resolved-also are being devel oped and could be used as a parallel approach to more realistically simulate hurricanes in global models in the future. Better resolution of the hurricane struc ture and larger-scale steering circulation, along with improved initial conditions pro vided by high-resolution satellite data and sophisticated data assimilation systems, could lead to better detection, monitoring, under standing, and prediction of the genesis and development of hurricanes that have such a devastating impact on society