Influence of order-disorder transitions on oxygen permeability through selected nonstoichiometric perovskite-type oxides

New results on the oxygen permeability of perovskite-type oxides SrCo0.8B'0.2O3¿¿ (with B'=Cr, Fe, Co and Cu) and La0.6Sr0.4CoO3¿¿ are presented. The occurrence of order-disorder transitions at elevated temperatures (790¿940°C) in these phases has been confirmed by DSC measurements and, in some cases, by X-ray powder diffraction of samples either slowly cooled or quenched from high temperature after annealing in different atmospheres. The oxygen permeability found upon exposing opposite sides of sealed disc specimens to a stream of air and of helium, respectively, increases sharply (between 5¿6 orders of magnitude up to 0.3¿3×10¿7 mol cm¿2s¿1) at the onset of the transition from a low-temperature vacancy-ordered state to defec t perovskite, except for SrCo0.8Fe0.2O3¿¿. In the latter case only a slight anomaly is found in the Arrhenius plot of th e oxygen permeability at 790°C. The comparatively high oxygen flux through SrCo0.8Fe0.2O3¿¿ observed at intermediate tempe ratures is interpreted in terms of a two-phase mixture of a vacancy-ordered state and disordered perovskite, while above 790°C the sample is single-phase of defect perovskite structure

Pictorial surface attitude and local depth comparisons

We measured local surface attitude for monocular pictorial relief and performed pairwise depth-comparison judgments on the same picture. Both measurements were subject to internal consistency checks. We found that both measurements were consistent with a relief (continuous pictorial surface) interpretation within the session-to-session scatter. We reconstructed the pictorial relief from both measurements separately, and found results that differed in detail but were quite similar in their basic structures. Formally, one expects certain geometrical identities that relate range and attitude data. Because we have independent measurements of both, we can attempt an empirical verification of such geometrical identities. Moreover, we can check whether the statistical scatter in the data indicates that, for example, the surface attitudes are derivable from a depth map or vice versa. We estimate that pairwise depth comparisons are an order of magnitude less precise than might be expected from the attitude data. Thus, the surface attitudes cannot be derived from a depth map as operationally defined by our methods, although the reverse is a possibility

An audio FIR-DAC in a BCD process for high power Class-D amplifiers

A 322 coefficient semi-digital FIR-DAC using a 1-bit PWM input signal was designed and implemented in a high voltage, audio power bipolar CMOS DMOS (BCD) process. This facilitates digital input signals for an analog class-D amplifier in BCD. The FIR-DAC performance depends on the ISI-resistant nature of this PWM-signal. An impulse response with only positive coefficients was chosen, because of its resistance to deadzone and mismatch. With a DAC current of 0.5 mA, the dynamic range is 111 dB (A-weighted), with SINAD = 103 dB (A-weighted). The current consumption is 1mA for the analog part and 4.8 mA for the digital part. The power consumption is 29 mW at V/sub dd/ = 5 V and the chip area is 2 mm/sup 2/ including the reference diode that can be shared by more channels

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In our study, for a small number of antonyms, we investigate whether they are cross-modally or ideaesthetically related to the space of colors. We analyze the affinities of seven antonyms (cold-hot, dull-radiant, dead-vivid, soft-hard, transparent-chalky, dry-wet, and acid-treacly) and their intermediate connotations (cool-warm, matt-shiny, numb-lively, mellow-firm, semi-transparent-opaque, semi-dry-moist, and sour-sweet) as a function of color. We find that some antonyms relate to chromatic dimensions, others to achromatic ones. The cold-hot antonym proves to be the most salient dimension. The dry-wet dimension coincides with the cold-hot dimension, with dry corresponding to hot and wet to cold. The acid-treacly dimension proves to be transversal to the cold-hot dimension; hence, the pairs mutually span the chromatic domain. The cold-hot and acid-treacly antonyms perhaps recall Hering's opponent color system. The dull-radiant, transparent-chalky, and dead-vivid pairs depend little upon chromaticity. Of all seven antonyms, only the soft-hard one turns out to be independent of the chromatic structure

Wat zijn gebruikers bereid te betalen? Uitbreiding mountainbikeroutes Utrechtse Heuvelrug

In Nationaal Park Utrechtse Heuvelrug ligt een aantal mountainbike routes. Verschillende belangenorganisaties zouden dit netwerk graag uitbreiden. Voor financiering wil men een beroep doen op de gebruikers van de routes Er is onderzocht in hoeverre dit uitgangspunt realistisch is en hoeveel de crossfietsers bereid zijn te betalen

Effect of enzyme therapy and prognostic factors in 69 adults with Pompe disease: An open-label single-center study

Abstract. Background: Enzyme replacement therapy (ERT) in adults with Pompe disease, a progressive neuromuscular disorder, is of promising but variable efficacy. We investigated whether it alters the course of disease, and also identified potential prognostic factors. Methods. Patients in this open-label single-center study were treated biweekly with 20 mg/kg alglucosidase alfa. Muscle strength, muscle function, and pulmonary function were assessed every 3-6 months and analyzed using repeated-measures ANOVA. Results: Sixty-nine patients (median age 52.1 years) were followed for a median of 23 months. Muscle strength increased after start of ERT (manual muscle testing 1.4 percentage points per year (pp/y); hand-held dynamometry 4.0 pp/y; both p < 0.001). Forced vital capacity (FVC) remained stable when measured in upright, but declined in supine position (-1.1 pp/y; p = 0.03). Muscle function did not improve in all patients (quick motor function test 0.7 pp/y; p = 0.14), but increased significantly in wheelchair-independent patients and those with mild and moderate muscle weakness.Relative to the pre-treatment period (49 patients with 14 months pre-ERT and 22 months ERT median follow-up), ERT affected muscle strength positively (man