Intumescent Flame Retardant Polyamide 11 Nanocomposites

Current polyamide 11 and 12 are lacking in fire retardancy and high strength/high heat resistance characteristics for a plethora of fabricated parts that are desired and required for performance driven applications. The introduction of selected nanoparticles such as surface modified montmorillonite (MMT) clay or carbon nanofibers (CNFs), combined with a conventional intumescent flame retardant (FR) additive into the polyamide 11/polyamide 12 (PA11/PA12) by melt processing conditions has resulted in the preparation of a family of intumescent polyamide nanocomposites. These intumescent polyamide 11 and 12 nanocomposites exhibit enhanced polymer performance characteristics, i.e., fire retardancy, high strength and high heat resistance and are expected to expand the market opportunities for polyamide 11 and polyamide 12 polymer manufacturers. The objective of this research is to develop improved polyamide 11 and 12 polymers with enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering (SLS) rapid manufacturing (RM). In the present study, a nanophase was introduced into the polyamide 11 and combining it with a conventional intumescent FR additive via twin screw extrusion. Arkema RILSAN® polyamide 11 molding polymer pellets were examined with two types of nanoparticles: chemically modified montmorillonite (MMT) organoclays, and carbon nanofibers (CNFs); and Clairant’s Exolit® OP 1230 intumescent FR additive were used to create a family of FR intumescent polyamide 11 nanocomposites. Transmission electron microscopy (TEM) was used to determine the degree of nanoparticles dispersion. Injection molded specimens were fabricated for physical, thermal, and flammability measurements. Thermal stability of these intumescent polyamide 11 nanocomposites was examined by TGA. Flammability properties were obtained using the Cone Calorimeter at an external heat flux of 35 kW/m 2 and UL 94 Test Method. Heat deflection temperatures (HDT) were also measured. TEM micrographs, physical, thermal, and flammability properties are presented. FR intumescent polyamide 11 nanocomposites properties are compared with polyamide 11 baseline polymer. Based on flammability and mechanical material performance, selective polymers including polyamide 11 nanocomposites and control polyamide 11 will be cryogenically ground into fine powders for SLS RM processing. SLS specimens will be fabricated for thermal, flammability, and mechanical properties characterization.Mechanical Engineerin

Lost and Found: A New Position and Infrared Counterpart for the X-ray Binary Scutum X-1

Using archival X-ray data, we find that the catalog location of the X-ray binary Scutum X-1 (Sct X-1) is incorrect, and that the correct location is that of the X-ray source AX J183528-0737, which is 15' to the west. Our identification is made on the basis of the 112-s pulse period for this object detected in an XMM-Newton observation, as well as spatial coincidence between AX J183528-0737 and previous X-ray observations. Based on the XMM-Newton data and archival RXTE data, we confirm secular spin-down over 17 years with period derivative Pdot~3.9e-9 s/s, but do not detect a previously reported X-ray iron fluorescence line. We identify a bright (Ks=6.55), red (J-Ks=5.51), optical and infrared counterpart to AX J183528-0737 from 2MASS, a number of mid-IR surveys, and deep optical observations, which we use to constrain the extinction to and distance of Sct X-1. From these data, as well as limited near-IR spectroscopy, we conclude that Sct X-1 is most likely a binary system comprised of a late-type giant or supergiant and a neutron star.Comment: 10 pages, 9 figures. Revised following referee's comments. Accepted to Ap

Predicting Responses of Geo-ecological Carbonate Reef Systems to Climate Change: A Conceptual Model and Review

Coral reefs provide critical ecological and geomorphic (e.g. sediment production for reef-fronted shoreline maintenance) services, which interact in complex and dynamic ways. These services are under threat from climate change, requiring dynamic modelling approaches that predict how reef systems will respond to different future climate scenarios. Carbonate budgets, which estimate net reef calcium carbonate production, provide a comprehensive ‘snap-shot’ assessment of reef accretionary potential and reef stability. These budgets, however, were not intended to account for the full suite of processes that maintain coral reef services or to provide predictive capacity on longer timescales (decadal to centennial). To respond to the dual challenges of enhancing carbonate budget assessments and advancing their predictive capacity, we applied a novel model elicitation and review method to create a qualitative geo-ecological carbonate reef system model that links geomorphic, ecological and physical processes. Our approach conceptualizes relationships between net carbonate production, sediment transport and landform stability, and rates knowledge confidence to reveal major knowledge gaps and critical future research pathways. The model provides a blueprint for future coral reef research that aims to quantify net carbonate production and sediment dynamics, improving our capacity to predict responses of reefs and reef-fronted shorelines to future climate change

Phase Locking, Devil's Staircases, Farey Trees, and Arnold Tongues in Driven Vortex Lattices with Periodic Pinning

Using numerical simulations, we observe phase locking, Arnold tongues, and Devil's staircases for vortex lattices driven at varying angles with respect to an underlying superconducting periodic pinning array. This rich structure should be observalble in transport measurments. The transverse $V(I)$ curves have a Devil's staircase structure, with plateaus occurring near the driving angles along symmetry directions of the pinning array. Each of the plateaus corresponds to a different dyanmical phase with a distinctive vortex structure and flow pattern.Comment: accepted to Physical Review Letter

Joint estimation of crown of thorns (Acanthaster planci) densities on the Great Barrier Reef

Crown-of-thorns starfish (CoTS; Acanthaster spp.) are an outbreaking pest among many Indo-Pacific coral reefs that cause substantial ecological and economic damage. Despite ongoing CoTS research, there remain critical gaps in observing CoTS populations and accurately estimating their numbers, greatly limiting understanding of the causes and sources of CoTS outbreaks. Here we address two of these gaps by (1) estimating the detectability of adult CoTS on typical underwater visual count (UVC) surveys using covariates and (2) inter-calibrating multiple data sources to estimate CoTS densities within the Cairns sector of the Great Barrier Reef (GBR). We find that, on average, CoTS detectability is high at 0.82 [0.77, 0.87] (median highest posterior density (HPD) and [95% uncertainty intervals]), with CoTS disc width having the greatest influence on detection. Integrating this information with coincident surveys from alternative sampling programs, we estimate CoTS densities in the Cairns sector of the GBR averaged 44 [41, 48] adults per hectare in 2014

Critical Currents and Vortex States at Fractional Matching Fields in Superconductors with Periodic Pinning

We study vortex states and dynamics in 2D superconductors with periodic pinning at fractional sub-matching fields using numerical simulations. For square pinning arrays we show that ordered states form at 1/1, 1/2, and 1/4 filling fractions while only partially ordered states form at other filling fractions, such as 1/3 and 1/5, in agreement with recent imaging experiments. For triangular pinning arrays we observe matching effects at filling fractions of 1/1, 6/7, 2/3, 1/3, 1/4, 1/6, and 1/7. For both square and triangular pinning arrays we also find that, for certian sub-matching fillings, vortex configurations depend on pinning strength. For weak pinning, ordering in which a portion of the vortices are positioned between pinning sites can occur. Depinning of the vortices at the matching fields, where the vortices are ordered, is elastic while at the incommensurate fields the motion is plastic. At the incommensurate fields, as the applied driving force is increased, there can be a transition to elastic flow where the vortices move along the pinning sites in 1D channels and a reordering transition to a triangular or distorted triangular lattice. We also discuss the current-voltage curves and how they relate to the vortex ordering at commensurate and incommensurate fields.Comment: 14 figure

AKARI and BLAST Observations of the Cassiopeia A Supernova Remnant and Surrounding Interstellar Medium

We use new large area far infrared maps ranging from 65 - 500 microns obtained with the AKARI and the Balloon-borne Large Aperture Submillimeter Telescope (BLAST) missions to characterize the dust emission toward the Cassiopeia A supernova remnant (SNR). Using the AKARI high resolution data we find a new "tepid" dust grain population at a temperature of ~35K and with an estimated mass of 0.06 solar masses. This component is confined to the central area of the SNR and may represent newly-formed dust in the unshocked supernova ejecta. While the mass of tepid dust that we measure is insufficient by itself to account for the dust observed at high redshift, it does constitute an additional dust population to contribute to those previously reported. We fit our maps at 65, 90, 140, 250, 350, and 500 microns to obtain maps of the column density and temperature of "cold" dust (near 16 K) distributed throughout the region. The large column density of cold dust associated with clouds seen in molecular emission extends continuously from the surrounding interstellar medium to project on the SNR, where the foreground component of the clouds is also detectable through optical, X-ray, and molecular extinction. At the resolution available here, there is no morphological signature to isolate any cold dust associated only with the SNR from this confusing interstellar emission. Our fit also recovers the previously detected "hot" dust in the remnant, with characteristic temperature 100 K.Comment: Accepted for publication in the Astrophysical Journal. Maps and related data are available at http://blastexperiment.info

Melting and transverse depinning of driven vortex lattices in the periodic pinning of Josephson junction arrays

We study the non-equilibrium dynamical regimes of a moving vortex lattice in the periodic pinning of a Josephson junction array (JJA) for {\it finite temperatures} in the case of a fractional or submatching field. We obtain a phase diagram for the current driven JJA as a function of the driving current I and temperature T. We find that when the vortex lattice is driven by a current, the depinning transition at $T_p(I)$ and the melting transition at $T_M(I)$ become separated even for a field for which they coincide in equilibrium. We also distinguish between the depinning of the vortex lattice in the direction of the current drive, and the {\it transverse depinning} in the direction perpendicular to the drive. The transverse depinning corresponds to the onset of transverse resistance in a moving vortex lattice at a given temperature $T_{tr}$. For driving currents above the critical current we find that the moving vortex lattice has first a transverse depinning transition at low T, and later a melting transition at a higher temperature, $T_{M}>T_{tr}$.Comment: 17 pages, 19 figure

Transplantation of canine olfactory ensheathing cells producing chondroitinase ABC promotes chondroitin sulphate proteoglycan digestion and axonal sprouting following spinal cord injury

Olfactory ensheathing cell (OEC) transplantation is a promising strategy for treating spinal cord injury (SCI), as has been demonstrated in experimental SCI models and naturally occurring SCI in dogs. However, the presence of chondroitin sulphate proteoglycans within the extracellular matrix of the glial scar can inhibit efficient axonal repair and limit the therapeutic potential of OECs. Here we have used lentiviral vectors to genetically modify canine OECs to continuously deliver mammalian chondroitinase ABC at the lesion site in order to degrade the inhibitory chondroitin sulphate proteoglycans in a rodent model of spinal cord injury. We demonstrate that these chondroitinase producing canine OECs survived at 4 weeks following transplantation into the spinal cord lesion and effectively digested chondroitin sulphate proteoglycans at the site of injury. There was evidence of sprouting within the corticospinal tract rostral to the lesion and an increase in the number of corticospinal axons caudal to the lesion, suggestive of axonal regeneration. Our results indicate that delivery of the chondroitinase enzyme can be achieved with the genetically modified OECs to increase axon growth following SCI. The combination of these two promising approaches is a potential strategy for promoting neural regeneration following SCI in veterinary practice and human patients