Dye-sensitized solar cells based on dimethylamino-π-bridge-pyranoanthocyanin dyes

UID/QUI/50006/2019 PTDC/QEQ-QFI/1971/2014 PD/BD/135087/2017 SFRH/BD/136556/2018 SFRH/BD/143309/2019 IF/00225/2015 DL57/2016 Program Contract (HC). UID/CTM/50025/2019 PTDC/CTM-ENE/5125/2014 CNPq 444061/2018-5 Universal grant 408181/2016-3The pyranoanthocyanins present in red wine display great potential as photosensitizers in bio-inspired Dye-Sensitized Solar Cells (DSSCs). Following a biomimetic approach, a series of amino-π-bridge-pyranoanthocyanin derivatives were employed as dye sensitizers in DSSCs. The dimethylamine group was selected to take advantage of its electron-donor character and the possibility of ‘dual-mode anchoring’ ([sbnd]OH vs. dimethylamino) to titanium dioxide. The increase in π-conjugation via insertion of C[dbnd]C bonds affected molecule flexibility, electron-donor ability and the pH-dependent equilibria of the pyranoanthocyanin derivatives. The current vs. potential properties of photoanodes using these dyes pointed to essential features of the relationship between power conversion efficiency and dye structure. These included the influences of the dimethylamine group, of π-conjugation and of substitution in ring B on the adsorption of the dyes to TiO2 and on the overall performance of the DSSCs prepared from them with and without added acid. An overall efficiency of 2.55% was obtained for the best performing compound, 4-(dimethylamino)-cinnamyl-pyranocyanidin-3-O-glucoside (JO3), which consolidates the importance of this family of compounds as potential dye-sensitizers for DSSC applications.authorsversionpublishe

Propriedades de ZrO2 (Y2 O3) reciclado proveniente da confecção de próteses dentárias

RESUMO O objetivo deste trabalho foi a recuperação de descartes de ZrO2(Y2O3) oriundos de laboratórios de próteses dentárias, a partir do seu reprocessamento. Os descartes de ZrO2(Y2O3) foram fragmentados, peneirados e calcinados a 900ºC. Pós com tamanho menor que 32μm foram prensados uniaxialmente a 100MPa e sinterizados em temperaturas entre 1400 e 1600ºC-120min. Análise de difração de raios X realizadas nos materiais calcinados indicaram a presença majoritária da fase ZrO2 tetragonal. Os compactos apresentaram densidade a verde próximo a 47% e as amostras sinterizadas tiveram sua densidade relativa variando entre 83,5% e 95%, para temperaturas de sinterização de 1400 e 1600ºC, respectivamente. Os resultados da análise de difração de raios X indicaram a presença da fase ZrO2 tetragonal, com dureza Vickers e tenacidade máxima obtidos para as amostras sinterizadas a 1600ºC, da ordem de 1100 HV e 5,7 MPa.m1/2 respectivamente

Relative rates of B meson decays into psi(2S) and J/psi mesons

We report on a study of the relative rates of B meson decays into psi(2S) and J/psi mesons using 1.3 fb^-1 of pbar p collisions at sqrt(s) = 1.96 TeV recorded by the D0 detector operating at the Fermilab Tevatron Collider. We observe the channels B^0_s -> psi(2S)phi, B^0_s -> J/psi phi, B^+/- -> psi(2S) K^+/-, and B^+/- -> J/psi K^+/- and we measure the relative branching fractions for these channels to be B(B^0_s -> psi(2S)phi)/B(B^0_s -> J/psi phi) = 0.55 +/- 0.11 (stat) +/- 0.07 (syst) +/- 0.06 (B), B(B^+/- -> psi(2S) K^+/-)/B(B^+/- -> J/psi K^+/-) = 0.65 +/- 0.04 (stat) +/- 0.03 (syst) +/- 0.07 (B) where the final error corresponds to the uncertainty in the J/psi and psi(2S) branching ratio into two muons.Comment: Published in Phys. Rev. D - Rapid Communicatio