Removal of volatile organic compounds by heterogeneous ozonation on microporous synthetic alumina silicate

A hybrid process combining adsorption and ozonation was examined as an alternative treatment for odorous volatile organic compounds (VOCs). Methyl ethyl ketone (MEK) was chosen to study the influence of operating parameters. Two synthetic aluminosilicates (faujasite-Y and ZSM-5) were tested for adsorption and reactivity with ozone. The adsorption equilibrium measurement on both adsorbents showed that adsorption performance depends on temperature but is not sensitive to relative humidity, due to the hydrophobic properties of the materials. Adsorbed VOCs were oxidized at low temperature when ozonated flow was sent to the reactor. Regeneration of the fixed bed was achieved at the same time, releasing mainly CO2 and H2O. Intermediates of oxidation, such as 2,3-butanedione and acetic acid, were identified, leading to incomplete mineralization. The influence of concentration and humidity are discussed. Four successive cycles were tested: after the first adsorption/ozonation cycle, the adsorption efficiency was not affected during subsequent cycles. These results show that the same sample of adsorbent can be used in the treatment process for a long time. Ozonation regeneration is a promising process for VOC removal

Application of high silica zeolite ZSM-5 in a hybrid treatment process based on sequential adsorption and ozonation for VOCs elimination

In this study, a hydrophobic synthetic zeolite, namely ZSM-5 is chosen as an adsorbent/catalyst for toluene removal. Experimental results showed that toluene adsorption onto ZSM-5 was favourable, following a Langmuir adsorption isotherm model. ZSM-5 zeolite was regenerated using gaseous ozone at low temperature. Adsorbed toluene was oxidised, releasing mainly CO2 and H2O. Traces of oxidation by-products such as acetic acid and acetaldehyde were formed and remained adsorbed after the oxidativate regeneration with ozone. After four successive cycles of adsorption/ozonation, the adsorption efficiency was not affected (92%–99%). These results showed that volatile organic compound (VOC) removal by adsorption onto ZSM-5 zeolite followed by ozone regeneration could be used as a promising hybrid process for the control of VOC emissions in terms of efficiency

Transition metals-incorporated zeolites as environmental catalysts for indoor air ozone decomposition

The present study aimed to prepare catalysts of Fe- and Cu-loaded zeolite via ion-exchange technique using dilute solutions of metal nitrate precursors followed by calcination at 600°C in the air for 4 h. Commercial zeolite ZSM-5 with specific surface area of 400 m2/g and diameter particle of 1.2-2 mm was used as a parent support. The prepared catalysts were characterized by Fourier transform infrared spectroscopy analysis. The IR absorbed bands of Cu-ZSM-5 and Fe-ZSM-5 revealed a shift in the frequency and a reduction in the intensity framework. This indicates that both catalysts have a significant change in the number of the zeolite structure bonds. The catalytic activity of the prepared materials compared to the parent zeolite was evaluated for the catalytic ozone decomposition. The ozone stream of the initial concentration (13 g/m3) with air flow rate (Q) of 0.18 m3/h was passed through a glass jacket column reactor filled with a fixed bed of 40 g zeolites. It was showed that the ozone removal efficiency by Cu-ZSM-5 and Fe-ZSM-5 was obviously higher than that found with the parent ZSM-5. In terms of O3 removal efficiency, zeolite samples could be ranked as follows: Fe-ZSM-5 > Cu-ZSM-5> parent ZSM-5. The results revealed about 90% O3 removal efficiency for Fe-ZSM-5 and 70% for Cu-ZSM-5 as compared to nearly 40% for the parent zeolite. Consequently, the incorporation of Fe and Cu metals onto the zeolite surface plays a key role for enhancing the gaseous ozone eliminatio

Fe(III)NaYnano as efficient electrocatalyst for electrodegradation of Congo Red dye

Textile dyes are one of the most important contaminants of the superficial water resources. Their removal from water bodies constitutes a priority to guaranty water quality. Electrodegradation of Congo Red dye was carried out using modified electrodes prepared by the deposition of iron(III)-zeolite on Carbon Toray. The sample iron(III)-zeolite was prepared by ion-exchange method with a solution of iron(III) using NaYnano as parent zeolite, with small particles, 150 nm. Fe(III)NaYnano was characterized by SEM/EDX and XRD techniques. The introduction of iron by ion exchange method do not modified the morphology of the zeolite but affect the zeolite structure, as prove by the structural characterization results from XRD. However, cyclic voltammetry studies show that iron-zeolite modified electrode is stable in the experimental conditions. The complete degradation of Congo Red dye was achieved by electrochemical route without the use of acid and hydrogen peroxide in reactional medium.rasmus grant. This work has been developed under the scope of the projects: BioTecNorte(operation NORTE-01-0145-FEDER-000004), PTDC/AAGTEC/5269/2014, and Centre of Chemistry (UID/QUI/00686/2013 and UID/QUI/0686/2016)info:eu-repo/semantics/publishedVersio

Toluene, Methanol and Benzaldehyde removal from gas streams by adsorption onto natural clay and faujasite-Y type Zeolite

A great number of pollution problems come as a result of the emission of Volatile Organic Compounds (VOCs) into the environment and their control becomes a serious challenge for the global chemical industry. Adsorption is a widely used technique for the removal of VOCs due to its high efficiency, low cost, and convenient operation. In this study, the feasibility to use a locally available clay, as adsorbent material to control VOCs emissions is evaluated. Natural clay is characterised by different physical-chemical methods and adsorptive interaction features between VOCs and natural clay are identified. Toluene (T), methanol (M) and benzaldehyde (B) are used here as representatives of three different kinds of VOCs. Adsorption isotherms onto natural clay and faujasite-Y type zeolite (Fau Y) are obtained at room temperature. According to Langmuir model data, maximum adsorption capacities (qm) of Fez natural clay and zeolite toward methanol (M), toluene (T) and benzaldehyde (B) at 300 K are 8, 0.89 and 3.1 mmol g-1, and 15, 1.91 and 13.9 mmol g-1 respectively. In addition, the effect of temperature on the adsorption of toluene onto natural clay is evaluated in the range from 300 to 323K. An increase on temperature reduces the adsorption capacity of natural clay toward toluene, indicating that an exothermic physical adsorption process takes place. The enthalpy of adsorption of toluene onto Fez natural clay was found to be -54 kJ mol-1. A preliminary cost analysis shows that natural clay could be used as an alternative low cost adsorbent in the control of VOCs from contaminated gas streams with a cost of US$0.02 kg-1 compared to Fau Y zeolite with US$ 10 kg-1

Raw clays from Morocco for degradation of pollutants by Fenton-like reaction for water treatment

Three raw clays from Morocco were used as heterogeneous catalysts for Fenton-like oxidation of organic pol-lutants in water. The selected pollutants were two dyes used in the textile industry, Congo Red (CR) and Tar-trazine (Tar, known also as a food coloring compound, E102) and Caffeine (Caf), a stimulant drug present in popular beverages such as coffee and tea, commonly used in Morocco. Two different processes were used for their degradation: (i) Fenton-like reaction; and (ii) electro-Fenton-like reaction. Process (i) was used for Tar and Caf degradation in the presence of clays from different region of Morocco (Middle Atlas -ClayMA, Fez -ClayF, and Ourika -ClayO), the best results being obtained with ClayO and ClayMA, on which 60.0% and 23.4% of conversion and 41.0% and 20.5% of mineralization were achieved for Tar and Caf, respectively. Process (ii) was used for degrading CR by clay-modified electrodes (CME) using the rawclays from Fez and Ourika regions (ClayF and ClayO). The stability of the CME was assessed by cyclic voltammetry studies, which proved that they are stable in the experimental conditions used. The electrodegradation of CR dye, performed without hydrogen peroxide in the reaction medium, achieve 67.0% of mineralization at the end of electrolysis (2 h)

Experimental investigation of tar arresting techniques and their evaluation for product syngas cleaning from bubbling fluidized bed gasifier

© 2019 Elsevier Ltd Hazardous waste products along with the syngas produced from biomass gasification are one of the major problems of today world. Tar and other solid contaminants removal from syngas are necessary as it is widely used for the production of energy in thermal and power sectors. The raw syngas can be clean up by directly controlling the operating parameters and applying cleaning units. This study aimed to analyze bubbling fluidized bed gasifier and focuses on investigating the novel tar reducing techniques. Different cleaning units; char bed, woodchip bed and mop fan were used to arrest tar directly from producer gas. For the first time, a novel strategical technique of mop fan based on water spray was evaluated. Results showed that tar arrest with bio-char is unsuccessful due to the burning of bed while the average concentration of tar captured by woodchips and mop fan with or without water spray was 0.459 mg/L, 0.987 mg/L and 0.617 mg/L respectively. Furthermore, the concentration of naphthalene and phenanthrene reduced significantly by 96.46% and 99.27% with water spray based mop fan. Overall tar arresting percentage efficiency with small woodchip, large woodchip, mop fan without water and mop fan with water spray was 22.5% < 29.4% < 60.54% < 89.61% respectively. Hence, these investigations lead to the important findings that mop fan with water spray can be deployed directly to capture contaminants, to prevent the production of waste and to increase the efficiencies of clean syngas for the safer use in the power sector

Evaluation of the potential of volatile organic compound (di-methyl benzene) removal using adsorption on natural minerals compared to commercial oxides

AIR:SURFACES+DBIThis study is dedicated to the investigation of the potential of volatile organic compounds (VOC) adsorption over low cost natural minerals (bentonite and diatomite). The performances of these solids, in terms of adsorption/desorption properties, were compared to commercial adsorbents, such as silica, alumina and titanium dioxide. The solids were first characterized by different physico-chemical methods and di-methyl benzene (dMB) was selected as model VOC pollutant for the investigation of adsorptive characteristics. The experiments were carried out with a fixed bed reactor under dynamic conditions using Fourier Transform InfraRed spectrometer to measure the evolution of dMB concentrations in the gaseous stream at the outlet of the reactor. The measured breakthrough curves yields to adsorbed amounts at saturation that has been used to obtain adsorption isotherms. The latters were used for determination of the heat involved in the adsorption process and estimation of its values using the isosteric method. Furthermore, the performances of the studied materials were compared considering the adsorption efficiency/cost ratio (C) 2013 Elsevier B.V. All rights reserved