Tests of prototype PCM 'sails' for office cooling

This is the post-print version of the final paper published in Applied Thermal Engineering. The published article is available from the link below. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. Copyright @ 2010 Elsevier B.V.PCM modules, constructed from a paraffin/LDPE composite, were tested in an occupied London office, in summer. Design variations tested the effect on heat transfer of a black paint or aluminium surface, the effect of different phase transition zones and the effect of discharging heat inside or outside. The modules’ temperatures were monitored along with airflow rate, air temperature and globe temperature. Their small size meant any effect on room temperature was negligible. Using DSC measurements of the PCMs’ thermophysical properties, in conjunction with the environmental measurements, a semi-empirical model of the modules was constructed in FLUENT using an enthalpy-porosity formulation to model phase change. Good validation was obtained for all modules using the temperature measurements with notable divergence when maximum liquid fraction was reached. The model was validated by the temperature measurements and used to generate mean liquid fraction and surface heat transfer rate profiles for performance comparisons. The broad phase transition zones of the PCMs results in wasted latent heat capacity. Black modules transfer heat and exhaust latent storage capacity significantly quicker than aluminium modules, due to radiant exchange. Discharging heat outside leads to an increase in thermal storage capacity and a higher rate of heat absorption.Buro Happold Engineers and the EPSRC

Investigating the impact and reaction pathway of toluene on a SOFC running on syngas

The integration of solid oxide fuel cells (SOFCs) with gasification systems have theoretically been shown to have a great potential to provide highly efficient distributed generation energy systems that can be fuelled by biomass including municipal solid waste. The syngas produced from the gasification of carbonaceous material is rich in hydrogen, carbon monoxide and methane that can fuel SOFCs. However, other constituents such as tar can cause catalyst deactivation, and blockage of the diffusion pathways. This work examines the impact of increasing concentrations of toluene as a model tar in a typical syngas composition fed to a NiO-GDC/TZ3Y/8YSZ/LSM-LSM SOFC membrane electrode assembly operating at 850°C and atmospheric pressure. Results suggest that up to 20 g/Nm3 of toluene and a low fuel utilisation factor (c.a. 17%) does not negatively impact cell performance and rather acts to increase the available hydrogen by undergoing reformation. At these conditions carbon deposition does occur, detected through EDS analysis, but serves to decrease the ASR rather than degrade the cell. Alternatively, the cell operating with 32 g/Nm3 toluene and with a fuel utilisation of 66.7% is dramatically affected through increased ASR which is assumed to be caused by increased carbon deposition. In order to test for the presence of tar products at the anode exhaust samples have been captured using an absorbing filter with results from HS-GC/MS analysis showing the presence of toluene only. © 2014 Hydrogen Energy Publications, LLC

Predicted and in situ performance of a solar air collector incorporating a translucent granular aerogel cover

This is the post-print version of the Article. The official published version can be accessed from the link below - Copyright @ 2012 ElsevierThere is an opportunity to improve the efficiency of flat plate solar air collectors by replacing their conventional glass covers with lightweight polycarbonate panels filled with high performance aerogel insulation. The in situ performance of a 5.4m2 solar air collector containing granular aerogel is simulated and tested. The collector is incorporated into the external insulation of a mechanically ventilated end terrace house, recently refurbished in London, UK. During the 7 day test period, peak outlet temperatures up to 45 °C are observed. Resultant supply and internal air temperatures peak at 25–30 and 21–22 °C respectively. Peak efficiencies of 22–36% are calculated based on the proposed design across a range of cover types. Measured outlet temperatures are validated to within 5% of their predicted values. Estimated outputs range from 118 to 166 kWh/m2/year for collectors with different thickness granular aerogel covers, compared to 110 kWh/m2/year for a single glazed collector, 140 k h/m2/year for a double glazed collector and 202 kWh/m2/year for a collector incorporating high performance monolithic aerogel. Payback periods of 9–16 years are calculated across all cover types. An efficiency up to 60% and a payback period as low as 4.5 years is possible with an optimised collector incorporating a 10 mm thick granular aerogel cover.This work is supported by the EPSRC, Brunel University, Buro Happold Ltd. and the Technology Strategy Board

Solar hydrogen system for cooking applications: Experimental and numerical study

This paper describes the development of a semi-empirical numerical model for a solar hydrogen system consisting of a proton exchange membrane electrolyser (PEM) powered by photovoltaic panels to produce hydrogen as fuel for cooking applications, focussing on Jamaica as a suitable case-study. The model was developed in TRNSYS and includes a novel numerical component based on FORTRAN to model the operation of the PEM electrolyser. The numerical component was developed based on operational data from a purpose constructed small-scale experimental rig. The numerical model was calibrated using data from the experimental rig powered by operational data from a photovoltaic panel system in the UK and predicted photovoltaic panel power data from Jamaica. For the test conditions, experiments indicated an electrolysis maximum efficiency of 63.6%. The calibrated model was used to develop a case study analysis for a small community in Jamaica with a daily cooking demand of 39.6kWh or 1.7kg of H2 gas. Simulations indicate that the H2 production plan is sufficient for the cooking needs of the case-study.This project is partly funded by ACP Caribbean & Pacific Research Programme for Sustainable Development of the European Union (EuropeAid/130381/D/ACT/ACP)

Performance testing of thermal and photovoltaic thermal solar collectors

This work details a methodology to characterize the performance of solar thermal and photovoltaic thermal (PVT) collectors using an indoor solar simulator. In this study, several cases have been compared to show that the methodology can be used to extract fundamental performance characteristics from a solar collector. In the first case, a serpentine collector was compared against a header riser collector using the same mass flow rate. It was found that the header riser was less efficient, with a 34% increase in the overall loss coefficient. The experimental results were compared with commonly used empirical models and showed a close agreement. In the second case, the impact on performance of using a polycarbonate cover is presented. The results show that the optical efficiency of the collector is reduced by 12% when using a cover, however, because the loss coefficient is reduced by 53%, the covered collector performs better when there is a large temperature difference between the absorber and the ambient. The third case investigates the combined performance of a PVT collector, that produces both heat and electricity from a single device. By placing photovoltaic (PV) laminates on top of the serpentine absorber, the thermal efficiency is reduced by 15%. When electricity is generated by laminates, the thermal efficiency is reduced by a further 3.5%, this drop in thermal efficiency is a result of the incident radiation producing electricity before reaching the thermal absorber. The combined efficiency of the PVT collectors was compared at controlled inlet temperatures. The serpentine design had the highest combined efficiency of 61% with 8% electricity at the lowest inlet temperature (21°C). The dominant form of loss in the PVT system is temperature driven, as the thermal efficiency decreases, electricity generation makes up a larger percentage of the combined output. This study highlights the potential for manufacturers of bespoke thermal absorbers and PV devices to combine their products into a single PVT device that could achieve improved efficiency over a given roof area