A chiral Mn(IV) complex and its supramolecular assembly: synthesis, characterization and properties

The open air reaction of the chiral Schiff base ligand H2L, prepared by the condensation of L-phenylalaninol and 5-bromosalicylaldehyde, with MnII(CH3COO)2·4H2O yielded dark brown complex [MnIVL2]·0·5 DMF (1). Compound 1 was characterized by elemental analysis, IR, UV-visible, CD and EPR spectroscopy, cyclic voltammetry and room temperature magnetic moment determination. Single-crystal X-ray analysis revealed that compound 1 crystallises in the monoclinic P21 space group with six mononuclear [MnIV L2] units in the asymmetric unit along with three solvent DMF molecules. In the crystal structure, each Mn(IV) complex, acting as the building unit, undergoes supramolecular linking through C-H···0 bonds leading to an intricate hydrogen bonding network

Ejection of cool plasma into the hot corona

We investigate the processes that lead to the formation, ejection and fall of a confined plasma ejection that was observed in a numerical experiment of the solar corona. By quantifying physical parameters such as mass, velocity, and orientation of the plasma ejection relative to the magnetic field, we provide a description of the nature of this particular phenomenon. The time-dependent three-dimensional magnetohydrodynamic (3D MHD) equations are solved in a box extending from the chromosphere to the lower corona. The plasma is heated by currents that are induced through field line braiding as a consequence of photospheric motions. Spectra of optically thin emission lines in the extreme ultraviolet range are synthesized, and magnetic field lines are traced over time. Following strong heating just above the chromosphere, the pressure rapidly increases, leading to a hydrodynamic explosion above the upper chromosphere in the low transition region. The explosion drives the plasma, which needs to follow the magnetic field lines. The ejection is then moving more or less ballistically along the loop-like field lines and eventually drops down onto the surface of the Sun. The speed of the ejection is in the range of the sound speed, well below the Alfven velocity. The plasma ejection is basically a hydrodynamic phenomenon, whereas the rise of the heating rate is of magnetic nature. The granular motions in the photosphere lead (by chance) to a strong braiding of the magnetic field lines at the location of the explosion that in turn is causing strong currents which are dissipated. Future studies need to determine if this process is a ubiquitous phenomenon on the Sun on small scales. Data from the Atmospheric Imaging Assembly on the Solar Dynamics Observatory (AIA/SDO) might provide the relevant information.Comment: 12 pages, 10 figure

Investigation of mass flows in the transition region and corona in a three-dimensional numerical model approach

The origin of solar transition region redshifts is not completely understood. Current research is addressing this issue by investigating three-dimensional magneto-hydrodynamic models that extend from the photosphere to the corona. By studying the average properties of emission line profiles synthesized from the simulation runs and comparing them to observations with present-day instrumentation, we investigate the origin of mass flows in the solar transition region and corona. Doppler shifts were determined from the emission line profiles of various extreme-ultraviolet emission lines formed in the range of $T=10^4-10^6$ K. Plasma velocities and mass flows were investigated for their contribution to the observed Doppler shifts in the model. In particular, the temporal evolution of plasma flows along the magnetic field lines was analyzed. Comparing observed vs. modeled Doppler shifts shows a good correlation in the temperature range $\log(T$/[K])=4.5-5.7, which is the basis of our search for the origin of the line shifts. The vertical velocity obtained when weighting the velocity by the density squared is shown to be almost identical to the corresponding Doppler shift. Therefore, a direct comparison between Doppler shifts and the model parameters is allowed. A simple interpretation of Doppler shifts in terms of mass flux leads to overestimating the mass flux. Upflows in the model appear in the form of cool pockets of gas that heat up slowly as they rise. Their low temperature means that these pockets are not observed as blueshifts in the transition region and coronal lines. For a set of magnetic field lines, two different flow phases could be identified. The coronal part of the field line is intermittently connected to subjacent layers of either strong or weak heating, leading either to mass flows into the loop or to the draining of the loop.Comment: 7 pages, 7 figure

The Magellan/IMACS Catalog of Optical Supernova Remnant Candidates in M83

We present a new optical imaging survey of supernova remnants in M83, using data obtained with the Magellan I 6.5m telescope and IMACS instrument under conditions of excellent seeing. Using the criterion of strong [S II] emission relative to Halpha, we confirm all but three of the 71 SNR candidates listed in our previous survey, and expand the SNR candidate list to 225 objects, more than tripling the earlier sample. Comparing the optical survey with a new deep X-ray survey of M83 with Chandra, we find 61 of these SNR candidates to have X-ray counterparts. We also identify an additional list of 46 [O III] -selected nebulae for follow-up as potential ejecta-dominated remnants, seven of which have associated X-ray emission that makes them strong candidates. Some of the other [O III]-bright objects could also be normal ISM-dominated supernova remnants with shocks fast enough to doubly ionize oxygen, but with Halpha and [S II] emission faint enough to have been missed. A few of these objects may also be H II regions with abnormally high [O III] emission compared with the majority of M83 H II regions, compact nebulae excited by young Wolf-Rayet stars, or even background AGN. The supernova remnant Halpha luminosity function in M83 is shifted a factor of ~ 4.5x higher than for M33 supernova remnants, indicative of a higher mean ISM density in M83. We describe the search technique used to identify the supernova remnant candidates and provide basic information and finder charts for the objects.Comment: 40 pages, 15 figures, accepted for ApJ

Proper motions and membership probabilities of stars in the region of globular cluster NGC 6809

NGC 6809 is a luminous metal-poor halo globular cluster that is relatively easy to study due to its proximity and low concentration. Because of its high Galactic latitude (b = -23deg), interstellar reddening and contamination is not very high. We aim to determine the relative proper motion and membership probability of the stars in the wide area of globular cluster NGC 6809. To target cluster members reliably during spectroscopic surveys and both spatial and radial distributions in the cluster outskirts without including field stars, a good proper motion and membership probability catalogue of NGC 6809 is required.The archival data of two epochs with a time-base line of 7.1 years have been collected with Wide Field Imager (WFI) mounted on the 2.2m MPG/ESO telescope. The CCD images of both epochs have been reduced using the astrometric techniques as described in Anderson et al. (2006). The calibrated UBVI magnitudes have been derived using Stetson's secondary standard stars. We derived the relative proper motion and membership probabilities for \sim 12600 stars in the field of globular cluster NGC 6809. The measurement error in proper motions for the stars of V \sim 17 mag is 2.0 mas/yr, gradually increasing up to \sim 3 mas/yr at V = 20 mag. We also provide the membership probability for the published different types of sources in NGC 6809. An electronic catalogue with proper motion and membership probability for the stars will be available to the astronomical community.Comment: Accepted for publication in The A&A. 11 pages. 11 figures,5 Table

Late-Type Red Supergiants: Too Cool for the Magellanic Clouds?

We have identified seven red supergiants (RSGs) in the Large Magellanic Cloud (LMC) and four RSGs in the Small Magellanic Cloud (SMC), all of which have spectral types that are considerably later than the average type observed in their parent galaxy. Using moderate-resolution optical spectrophotometry and the MARCS stellar atmosphere models, we determine their physical properties and place them on the H-R diagram for comparison with the predictions of current stellar evolutionary tracks. The radial velocities of these stars suggest that they are likely all members of the Clouds rather than foreground dwarfs or halo giants. Their locations in the H-R diagram also show us that those stars are cooler than the current evolutionary tracks allow, appearing to the right of the Hayashi limit, a region in which stars are no longer in hydrodynamic equilibrium. These stars exhibit considerable variability in their V magnitudes, and three of these stars also show changes in their effective temperatures (and spectral types) on the time-scales of months. One of these stars, [M2002] SMC 055188, was caught in an M4.5 I state, as late as that seen in HV 11423 at its recent extreme: considerable later, and cooler, than any other supergiant in the SMC. In addition, we find evidence of variable extinction due to circumstellar dust and changes in the stars' luminosities, also consistent with our recent findings for HV 11423 - when these stars are hotter they are also dustier and more luminous. We suggest that these stars have unusual properties because they are in an unstable (and short-lived) evolutionary phase.Comment: 26 pages, 6 figures; submitted to the Astrophysical Journa

Optical properties of structurally-relaxed Si/SiO2_2 superlattices: the role of bonding at interfaces

We have constructed microscopic, structurally-relaxed atomistic models of Si/SiO$_2$ superlattices. The structural distortion and oxidation-state characteristics of the interface Si atoms are examined in detail. The role played by the interface Si suboxides in raising the band gap and producing dispersionless energy bands is established. The suboxide atoms are shown to generate an abrupt interface layer about 1.60 \AA thick. Bandstructure and optical-absorption calculations at the Fermi Golden rule level are used to demonstrate that increasing confinement leads to (a) direct bandgaps (b) a blue shift in the spectrum, and (c) an enhancement of the absorption intensity in the threshold-energy region. Some aspects of this behaviour appear not only in the symmetry direction associated with the superlattice axis, but also in the orthogonal plane directions. We conclude that, in contrast to Si/Ge, Si/SiO$_2$ superlattices show clear optical enhancement and a shift of the optical spectrum into the region useful for many opto-electronic applications.Comment: 11 pages, 10 figures (submitted to Phys. Rev. B