Friedel–Crafts addition of indoles to nitrones promoted by trimethylsilyl trifluoromethanesulfonate

N-alkylindoles undergo Friedel–Crafts addition to aryl and secondary alkyl nitrones in the presence of trimethylsilyl trifluoromethanesulfonate and a trialkylamine to produce 3-(1- (silyloxyamino)alkyl)indoles. Spontaneous conversion to the bisindolyl(aryl)methanes, which is thermodynamically favored for nitrones derived from aromatic aldehydes, is suppressed under the reaction conditions. The silyloxyamino group can be deprotected with tetrabutylammonium fluoride to yield the hydroxylamine

Developing a Drift Rate Distribution for Technosignature Searches of Exoplanets

A stable-frequency transmitter with relative radial acceleration to a receiver will show a change in received frequency over time, known as a "drift rate''. For a transmission from an exoplanet, we must account for multiple components of drift rate: the exoplanet's orbit and rotation, the Earth's orbit and rotation, and other contributions. Understanding the drift rate distribution produced by exoplanets relative to Earth, can a) help us constrain the range of drift rates to check in a Search for Extraterrestrial Intelligence (SETI) project to detect radio technosignatures and b) help us decide validity of signals-of-interest, as we can compare drifting signals with expected drift rates from the target star. In this paper, we modeled the drift rate distribution for $\sim$5300 confirmed exoplanets, using parameters from the NASA Exoplanet Archive (NEA). We find that confirmed exoplanets have drift rates such that 99\% of them fall within the $\pm$53 nHz range. This implies a distribution-informed maximum drift rate $\sim$4 times lower than previous work. To mitigate the observational biases inherent in the NEA, we also simulated an exoplanet population built to reduce these biases. The results suggest that, for a Kepler-like target star without known exoplanets, $\pm$0.44 nHz would be sufficient to account for 99\% of signals. This reduction in recommended maximum drift rate is partially due to inclination effects and bias towards short orbital periods in the NEA. These narrowed drift rate maxima will increase the efficiency of searches and save significant computational effort in future radio technosignature searches.Comment: 15 pages, 8 figure

The Breakthrough Listen Search for Intelligent Life: A 3.95-8.00 GHz Search for Radio Technosignatures in the Restricted Earth Transit Zone

We report on a search for artificial narrowband signals of 20 stars within the restricted Earth Transit Zone as a part of the ten-year Breakthrough Listen (BL) search for extraterrestrial intelligence. The restricted Earth Transit Zone is the region of the sky from which an observer would see the Earth transit the Sun with an impact parameter of less than 0.5. This region of the sky is geometrically unique, providing a potential way for an extraterrestrial intelligence to discover the Solar System. The targets were nearby (7-143 pc) and the search covered an electromagnetic frequency range of 3.95-8.00 GHz. We used the Robert C. Byrd Green Bank Telescope to perform these observations with the standard BL data recorder. We searched these data for artificial narrowband ($\sim$Hz) signals with Doppler drift rates of $\pm 20$ Hz s$^{-1}$. We found one set of potential candidate signals on the target HIP 109656 which was then found to be consistent with known properties of anthropogenic radio frequency interference. We find no evidence for radio technosignatures from extraterrestrial intelligence in our observations. The observing campaign achieved a minimum detectable flux which would have allowed detections of emissions that were $10^{-3}$ to $0.88$ times as powerful as the signaling capability of the Arecibo radar transmitter, for the nearest and furthest stars respectively. We conclude that at least $8\%$ of the systems in the restricted Earth Transit Zone within 150 pc do not possess the type of transmitters searched in this survey. To our knowledge, this is the first targeted search for extraterrestrial intelligence of the restricted Earth Transit Zone. All data used in this paper are publicly available via the Breakthrough Listen Public Data Archive (http://seti.berkeley.edu/bldr2).Comment: 17 pages, 8 figures, submitted to Ap

Games people play with brands: An application of Transactional Analysis to marketplace relationships.

Relationships have been normalised in marketing theory as mutuality beneficial, long-term dyads. This obscures their emotional content, ignores critical conceptualisations of corporate exploitation, and fails to capture the range of possible marketplace relationship forms. In this paper we offer Berne’s (1964) Transactional Analysis (TA) as a way to uncover the biographical psychology that informs marketplace relationship structures and their accompanying emotions, and to provide a critique of such arrangements. We first explain TA, its origins, its relationship with psychoanalysis, its limitations, and contemporary extensions beyond therapy. We then present the structural basis of marketplace relationships from a TA perspective, before illustrating how TA Game Analysis can be applied through an analysis of the iPhone and related mobile phone contracts, and the Games If I didn’t Love Apple and Smallprint. Finally we discuss the implications of such an approach for transforming market practices based on recognition of Marketplace Games and their modification

Exotic trees

We discuss the scaling properties of free branched polymers. The scaling behaviour of the model is classified by the Hausdorff dimensions for the internal geometry: d_L and d_H, and for the external one: D_L and D_H. The dimensions d_H and D_H characterize the behaviour for long distances while d_L and D_L for short distances. We show that the internal Hausdorff dimension is d_L=2 for generic and scale-free trees, contrary to d_H which is known be equal two for generic trees and to vary between two and infinity for scale-free trees. We show that the external Hausdorff dimension D_H is directly related to the internal one as D_H = \alpha d_H, where \alpha is the stability index of the embedding weights for the nearest-vertex interactions. The index is \alpha=2 for weights from the gaussian domain of attraction and 0<\alpha <2 for those from the L\'evy domain of attraction. If the dimension D of the target space is larger than D_H one finds D_L=D_H, or otherwise D_L=D. The latter result means that the fractal structure cannot develop in a target space which has too low dimension.Comment: 33 pages, 6 eps figure

HATS-8b: A Low-Density Transiting Super-Neptune

HATS-8b is a low density transiting super-Neptune discovered as part of the HATSouth project. The planet orbits its solar-like G dwarf host (V=14.03 $\pm$ 0.10 and T$_{eff}$ =5679 $\pm$ 50 K) with a period of 3.5839 d. HATS-8b is the third lowest mass transiting exoplanet to be discovered from a wide-field ground based search, and with a mass of 0.138 $\pm$ 0.019 M$_J$ it is approximately half-way between the masses of Neptune and Saturn. However HATS-8b has a radius of 0.873 (+0.123,-0.075) R$_J$, resulting in a bulk density of just 0.259 $\pm$ 0.091 g.cm$^{-3}$. The metallicity of the host star is super-Solar ([Fe/H]=0.210 $\pm$ 0.080), arguing against the idea that low density exoplanets form from metal-poor environments. The low density and large radius of HATS-8b results in an atmospheric scale height of almost 1000 km, and in addition to this there is an excellent reference star of near equal magnitude at just 19 arcsecond separation on the sky. These factors make HATS-8b an exciting target for future atmospheric characterization studies, particularly for long-slit transmission spectroscopy.Comment: 11 pages, 7 figures, accepted for publication in A

HATS-7b: A Hot Super Neptune Transiting a Quiet K Dwarf Star

IW ../submit_V2/abstract.txt ( Row 1 Col 1 6:48 Ctrl-K H for help We report the discovery by the HATSouth network of HATS-7b, a transiting Super-Neptune with a mass of 0.120+/-0.012MJ, a radius of 0.563+/-(0.046,0.034)RJ, and an orbital period of 3.1853days. The host star is a moderately bright (V=13.340+/-0.010mag, K_S=10.976+/-0.026mag) K dwarf star with a mass of 0.849+/-0.027Msun , a radius of 0.815+/-(0.049,-0.035)Rsun, and a metallicity of [Fe/H]=+0.250+/-0.080. The star is photometrically quiet to within the precision of the HATSouth measurements and has low RV jitter. HATS-7b is the second smallest radius planet discovered by a wide-field ground-based transit survey, and one of only a handful of Neptune-size planets with mass and radius determined to 10% precision. Theoretical modeling of HATS-7b yields a hydrogen-helium fraction of 18+/-4% (rock-iron core and H2-He envelope), or 9+/-4% (ice core and H2-He envelope), i.e.it has a composition broadly similar to that of Uranus and Neptune, and very different from that of Saturn, which has 75% of its mass in H2-He. Based on a sample of transiting exoplanets with accurately (<20%) determined parameters, we establish approximate power-law relations for the envelopes of the mass-density distribution of exoplanets. HATS-7b, which, together with the recently discovered HATS-8b, is one of the first two transiting super-Neptunes discovered in the Southern sky, is a prime target for additional follow-up observations with Southern hemisphere facilities to characterize the atmospheres of Super-Neptunes (which we define as objects with mass greater than that of Neptune, and smaller than halfway between that of Neptune and Saturn, i.e. 0.054 MJ<Mp<0.18 MJ).Comment: 11 pages, accepted for publication by Ap

HAT-P-57b: A Short-Period Giant Planet Transiting A Bright Rapidly Rotating A8V Star Confirmed Via Doppler Tomography

We present the discovery of HAT-P-57b, a P = 2.4653 day transiting planet around a V = 10.465 +- 0.029 mag, Teff = 7500 +- 250 K main sequence A8V star with a projected rotation velocity of v sin i = 102.1 +- 1.3 km s^-1. We measure the radius of the planet to be R = 1.413 +- 0.054 R_J and, based on RV observations, place a 95% confidence upper limit on its mass of M < 1.85 M_J . Based on theoretical stellar evolution models, the host star has a mass and radius of 1.47 +- 0.12 M_sun, and 1.500 +- 0.050 R_sun, respectively. Spectroscopic observations made with Keck-I/HIRES during a partial transit event show the Doppler shadow of HAT-P-57b moving across the average spectral line profile of HAT-P- 57, confirming the object as a planetary system. We use these observations, together with analytic formulae that we derive for the line profile distortions, to determine the projected angle between the spin axis of HAT-P-57 and the orbital axis of HAT-P-57b. The data permit two possible solutions, with -16.7 deg < lambda < 3.3 deg or 27.6 deg < lambda < 57.4 deg at 95% confidence, and with relative probabilities for the two modes of 26% and 74%, respectively. Adaptive optics imaging with MMT/Clio2 reveals an object located 2.7" from HAT-P-57 consisting of two point sources separated in turn from each other by 0.22". The H and L -band magnitudes of the companion stars are consistent with their being physically associated with HAT-P-57, in which case they are stars of mass 0.61 +- 0.10 M_sun and 0.53 +- 0.08 M_sun. HAT-P-57 is the most rapidly rotating star, and only the fourth main sequence A star, known to host a transiting planet.Comment: 18 pages, 14 figures, 5 tables, accepted for publication in A

HATS-15 b and HATS-16 b: Two massive planets transiting old G dwarf stars

We report the discovery of HATS-15 b and HATS-16 b, two massive transiting extrasolar planets orbiting evolved ($\sim 10$ Gyr) main-sequence stars. The planet HATS-15 b, which is hosted by a G9V star ($V=14.8$ mag), is a hot Jupiter with mass of $2.17\pm0.15\, M_{\mathrm{J}}$ and radius of $1.105\pm0.0.040\, R_{\mathrm{J}}$, and completes its orbit in nearly 1.7 days. HATS-16 b is a very massive hot Jupiter with mass of $3.27\pm0.19\, M_{\mathrm{J}}$ and radius of $1.30\pm0.15\, R_{\mathrm{J}}$; it orbits around its G3 V parent star ($V=13.8$ mag) in $\sim2.7$ days. HATS-16 is slightly active and shows a periodic photometric modulation, implying a rotational period of 12 days which is unexpectedly short given its isochronal age. This fast rotation might be the result of the tidal interaction between the star and its planet.Comment: 16 pages, 8 figures, submitted to PAS