152 research outputs found
3D porous Li3V2(PO4)3/hard carbon composites for improving the rate performance of lithium ion batteries
A 3D porous Li3V2(PO4)3/hard carbon composite delivers a capacity of 98 mA h g−1 after 1000 cycles at 10C.</p
Graphene-like carbon sheet/Fe3O4 nanocomposites derived from soda papermaking black liquor for high performance lithium ion batteries
Alkali lignins and its degradation products in the soda papermaking black liquor (SPBL) are renewable resource with the highest natural carbon content. In this work we convert SPBL into the high-performance carbon-based nanocomposite anodes. The unique functional groups of lignin biomass induce spontaneous formation of graphene-like carbon sheet (GCS) in-situ doped SiC/S. The lamellar GCS/FeO nanocomposite (GCS/FO-NC) is facilely prepared via one-step in-situ thermo-chemical method at 700\ua0°C, in which donut shaped FeO nanoparticles with superlattices and inner surface are homogeneously embedded in the interlayer of GCS and are also anchored on its surface. The GCS/FO-NC anode exhibits a ultrahigh first discharge specific capacity of 3829\ua0mAh\ua0g at 50\ua0mA\ua0g in a coin-type Li ion battery, which is more than 4 times the theoretical capacity (924\ua0mAh\ua0g) of FeO and 5 times that of the graphene anode (744\ua0mAh. g). Even at a high current density (1000\ua0mA\ua0g), it still exhibits a high reversible capacity (750\ua0mAh\ua0g) after 1400 discharge/charge cycles. More importantly, the removal efficiency of chemical oxygen demand of SPBL is up to 83.4% during the synthesis process, which reduce its load to environment and synthetic cost of carbon-based nanocomposite anodes
Pulse Shape Discrimination Techniques in Scintillating CsI(Tl) Crystals
There are recent interests with CsI(Tl) scintillating crystals for Dark
Matter experiments. The key merit is the capability to differentiate nuclear
recoil (nr) signatures from the background -events due to
ambient radioactivity on the basis of their different pulse shapes. One of the
major experimental challenges is to perform such pulse shape analysis in the
statistics-limited domain where the light output is close to the detection
threshold. Using data derived from measurements with low energy 's and
nuclear recoils due to neutron elastic scatterings, it was verified that the
pulse shapes between -events are different. Several methods of
pulse shape discrimination are studied, and their relative merits are compared.
Full digitization of the pulse shapes is crucial to achieve good
discrimination. Advanced software techniques with mean time, neural network and
likelihood ratios give rise to satisfactory performance, and are superior to
the conventional Double Charge method commonly applied at higher energies.
Pulse shape discrimination becomes effective starting at a light yield of about
20 photo-electrons. This corresponds to a detection threshold of about 5 keV
electron-equivalence energy, or 4050 keV recoil kinetic energy, in realistic
experiments.Comment: 20 pages, 7 figure
Measurement of the Intrinsic Radiopurity of Cs-137/U-235/U-238/Th-232 in CsI(Tl) Crystal Scintillators
The inorganic crystal scintillator CsI(Tl) has been used for low energy
neutrino and Dark Matter experiments, where the intrinsic radiopurity is an
issue of major importance. Low-background data were taken with a CsI(Tl)
crystal array at the Kuo-Sheng Reactor Neutrino Laboratory. The pulse shape
discrimination capabilities of the crystal, as well as the temporal and spatial
correlations of the events, provide powerful means of measuring the intrinsic
radiopurity of Cs-137 as well as the U-235, U-238 and Th-232 series. The event
selection algorithms are described, with which the decay half-lives of Po-218,
Po-214, Rn-220, Po-216 and Po-212 were derived. The measurements of the
contamination levels, their concentration gradients with the crystal growth
axis, and the uniformity among different crystal samples, are reported. The
radiopurity in the U-238 and Th-232 series are comparable to those of the best
reported in other crystal scintillators. Significant improvements in
measurement sensitivities were achieved, similar to those from dedicated
massive liquid scintillator detector. This analysis also provides in situ
measurements of the detector performance parameters, such as spatial
resolution, quenching factors, and data acquisition dead time.Comment: 28 pages, 12 figure
Studies of Prototype CsI(Tl) Crystal Scintillators for Low-Energy Neutrino Experiments
Crystal scintillators provide potential merits for the pursuit of low-energy
low-background experiments. A CsI(Tl) scintillating crystal detector is being
constructed to study low-energy neutrino physics at a nuclear reactor, while
projects are underway to adopt this technique for dark matter searches. The
choice of the geometrical parameters of the crystal modules, as well as the
optimization of the read-out scheme, are the results of an R&D program.
Crystals with 40 cm in length were developed. The detector requirements and the
achieved performance of the prototypes are presented. Future prospects for this
technique are discussed.Comment: 32 pages, 14 figure
Direct Measurements of the Branching Fractions for and and Determinations of the Form Factors and
The absolute branching fractions for the decays and
are determined using singly
tagged sample from the data collected around 3.773 GeV with the
BES-II detector at the BEPC. In the system recoiling against the singly tagged
meson, events for and events for decays are observed. Those yield
the absolute branching fractions to be and . The
vector form factors are determined to be
and . The ratio of the two form
factors is measured to be .Comment: 6 pages, 5 figure
Ultrastrong conductive in situ composite composed of nanodiamond incoherently embedded in disordered multilayer graphene
Traditional ceramics or metals cannot simultaneously achieve ultrahigh strength and high electrical conductivity. The elemental carbon can form a variety of allotropes with entirely different physical properties, providing versatility for tuning mechanical and electrical properties in a wide range. Here, by precisely controlling the extent of transformation of amorphous carbon into diamond within a narrow temperature–pressure range, we synthesize an in situ composite consisting of ultrafine nanodiamond homogeneously dispersed in disordered multilayer graphene with incoherent interfaces, which demonstrates a Knoop hardness of up to ~53 GPa, a compressive strength of up to ~54 GPa and an electrical conductivity of 670–1,240 S m(–1) at room temperature. With atomically resolving interface structures and molecular dynamics simulations, we reveal that amorphous carbon transforms into diamond through a nucleation process via a local rearrangement of carbon atoms and diffusion-driven growth, different from the transformation of graphite into diamond. The complex bonding between the diamond-like and graphite-like components greatly improves the mechanical properties of the composite. This superhard, ultrastrong, conductive elemental carbon composite has comprehensive properties that are superior to those of the known conductive ceramics and C/C composites. The intermediate hybridization state at the interfaces also provides insights into the amorphous-to-crystalline phase transition of carbon
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