Vapor Pressure of Ionic Liquids

We argue that the extremely low vapor pressures of room temperature ionic liquids near their triple points are due to the combination of strong ionic characters and of low melting temperatures.Comment: Initially submitted manuscript of article M. Bier and S. Dietrich, Mol. Phys. 108, 211 (2010) [Corrigendum: Mol. Phys. 108, 1413 (2010)

Astronomy: Starbursts near and far

Observations of intensely bright star-forming galaxies both close by and in the distant Universe at first glance seem to emphasize their similarity. But look a little closer, and differences emerge.Comment: 6 pages including 1 figur

Precision reconstruction of the cold dark matter-neutrino relative velocity fromN-body simulations

Discovering the mass of neutrinos is a principle goal in high energy physics and cosmology. In addition to cosmological measurements based on two-point statistics, the neutrino mass can also be estimated by observations of neutrino wakes resulting from the relative motion between cold dark matter (CDM) and neutrinos. Such a detection relies on an accurate reconstruction of the CDM-neutrino relative velocity which is affected by nonlinear structure growth and galaxy bias. We investigate our ability to reconstruct this relative velocity using large N-body simulations where we evolve neutrinos as distinct particles alongside the CDM. We find that the CDM velocity power spectrum is overpredicted by linear theory whereas the neutrino velocity power spectrum is underpredicted. The magnitude of the relative velocity observed in the simulations is found to be lower than what is predicted in linear theory. Since neither the CDM nor the neutrino velocity fields are directly observable from galaxy or 21 cm surveys, we test the accuracy of a reconstruction algorithm based on halo density fields and linear theory. Assuming prior knowledge of the halo bias, we find that the reconstructed relative velocities are highly correlated with the simulated ones with correlation coefficients of 0.94, 0.93, 0.92 and 0.88 for neutrinos of mass 0.05, 0.1, 0.2 and 0.4 eV. We confirm that the relative velocity field reconstructed from large scale structure observations such as galaxy or 21 cm surveys can be accurate in direction and, with appropriate scaling, magnitude

Phylogeny of Prokaryotes and Chloroplasts Revealed by a Simple Composition Approach on All Protein Sequences from Complete Genomes Without Sequence Alignment

The complete genomes of living organisms have provided much information on their phylogenetic relationships. Similarly, the complete genomes of chloroplasts have helped to resolve the evolution of this organelle in photosynthetic eukaryotes. In this paper we propose an alternative method of phylogenetic analysis using compositional statistics for all protein sequences from complete genomes. This new method is conceptually simpler than and computationally as fast as the one proposed by Qi et al. (2004b) and Chu et al. (2004). The same data sets used in Qi et al. (2004b) and Chu et al. (2004) are analyzed using the new method. Our distance-based phylogenic tree of the 109 prokaryotes and eukaryotes agrees with the biologists tree of life based on 16S rRNA comparison in a predominant majority of basic branching and most lower taxa. Our phylogenetic analysis also shows that the chloroplast genomes are separated to two major clades corresponding to chlorophytes s.l. and rhodophytes s.l. The interrelationships among the chloroplasts are largely in agreement with the current understanding on chloroplast evolution

High Fidelity Tape Transfer Printing Based On Chemically Induced Adhesive Strength Modulation

Transfer printing, a two-step process (i.e. picking up and printing) for heterogeneous integration, has been widely exploited for the fabrication of functional electronics system. To ensure a reliable process, strong adhesion for picking up and weak or no adhesion for printing are required. However, it is challenging to meet the requirements of switchable stamp adhesion. Here we introduce a simple, high fidelity process, namely tape transfer printing(TTP), enabled by chemically induced dramatic modulation in tape adhesive strength. We describe the working mechanism of the adhesion modulation that governs this process and demonstrate the method by high fidelity tape transfer printing several types of materials and devices, including Si pellets arrays, photodetector arrays, and electromyography (EMG) sensors, from their preparation substrates to various alien substrates. High fidelity tape transfer printing of components onto curvilinear surfaces is also illustrated

What a difference a term makes:the effect of educational attainment on marital outcomes in the UK

Abstract In the past, students in England and Wales born within the first 5 monthsof the academic year could leave school one term earlier than those born later inthe year. Focusing on women, those who were required to stay on an extra termmore frequently hold some academic qualification. Using having been required tostay on as an exogenous factor affecting academic attainment, we find that holding alow-level academic qualification has no effect on the probability of being currentlymarried for women aged 25 or above, but increases the probability of the husbandholding some academic qualification and being economically active.33 Halama

Increased entropy of signal transduction in the cancer metastasis phenotype

Studies into the statistical properties of biological networks have led to important biological insights, such as the presence of hubs and hierarchical modularity. There is also a growing interest in studying the statistical properties of networks in the context of cancer genomics. However, relatively little is known as to what network features differ between the cancer and normal cell physiologies, or between different cancer cell phenotypes. Based on the observation that frequent genomic alterations underlie a more aggressive cancer phenotype, we asked if such an effect could be detectable as an increase in the randomness of local gene expression patterns. Using a breast cancer gene expression data set and a model network of protein interactions we derive constrained weighted networks defined by a stochastic information flux matrix reflecting expression correlations between interacting proteins. Based on this stochastic matrix we propose and compute an entropy measure that quantifies the degree of randomness in the local pattern of information flux around single genes. By comparing the local entropies in the non-metastatic versus metastatic breast cancer networks, we here show that breast cancers that metastasize are characterised by a small yet significant increase in the degree of randomness of local expression patterns. We validate this result in three additional breast cancer expression data sets and demonstrate that local entropy better characterises the metastatic phenotype than other non-entropy based measures. We show that increases in entropy can be used to identify genes and signalling pathways implicated in breast cancer metastasis. Further exploration of such integrated cancer expression and protein interaction networks will therefore be a fruitful endeavour.Comment: 5 figures, 2 Supplementary Figures and Table

Free-standing graphene films embedded in epoxy resin with enhanced thermal properties

The poor thermal conductivity of polymer composites has long been a deterrent to their increased use in high-end aerospace or defence applications. This study describes a new approach for the incorporation of graphene in an epoxy resin, through the addition of graphene as free-standing film in the polymeric matrix. The electrical and thermal conductivity of composites embedding two different free-standing graphene films was compared to composites with embedded carbon nanotube buckypapers (CNT-BP). Considerably higher thermal conductivity values than those achieved with conventional dispersing methods of graphene or CNTs in epoxy resins were obtained. The characterisation was complemented with a study of the structure at the microscale by cross-sectional scanning electron microscopy (SEM) images and a thermogravimetric analysis (TGA). The films are preconditioned in order to incorporate them into the composites, and the complete manufacturing process proposed allows the production and processing of these materials in large batches. The high thermal conductivity obtained for the composites opens the way for their use in demanding thermal management applications, such as electronic enclosures or platforms facing critical temperature loads.European Defence Agency tender No 17.ESI.OP.066. Study on the Impact of Graphene on Defence Application

Distributed Proximity-Aware Peer Clustering in BitTorrent-Like Peer-to-Peer Networks

International Conference on Embedded and Ubiquitous Computing (EUC 2006), Seoul, Korea, 1-4 Aug 2006In this paper, we propose a hierarchical architecture for grouping peers into clusters in a large-scale BitTorrent-like underlying overlay network in such a way that clusters are evenly distributed and that the peers within are relatively close together. We achieve this by constructing the CBT (Clustered BitTorrent) system with two novel algorithms: a peer joining algorithm and a super-peer selection algorithm. Proximity and distribution are determined by the measurement of distances among peers. Performance evaluations demonstrate that the new architecture achieves better results than a randomly organized BitTorrent network, improving the system scalability and efficiency while retaining the robustness and incentives of original BitTorrent paradigm.Department of Computin