A high energy output and low onset temperature nanothermite based on three-dimensional ordered macroporous nano-NiFe2O4

Three-dimensional ordered macroporous (3DOM) Al/NiFe2O4 nanothermite has been obtained by colloidal crystal templating method combined with magnetron sputtering processing. Owing to the superior material properties and unique 3DOM structural characteristics of composite metal oxides, the heat output of the Al/NiFe2O4 nanothermite is up to 2921.7 J g− 1, which is more than the values of Al/NiO and Al/Fe2O3 nanothermites in literature. More importantly, by comparison to the other two nanothermites, the onset temperature of 298.2 °C from Al/NiFe2O4 is remarkably low, which means it can be ignited more easily. Laser ignition experiment indicate that the synthesized Al/NiFe2O4 nanothermite can be easily ignited by laser. In addition, the preparation process is highly compatible with the MEMS technology. These exciting achievements have great potential to expand the scope of nanothermite applications

3D ordered macroporous NiO/Al nanothermite film with significantly improved higher heat output, lower ignition temperature and less gas production

The performances of nanothermites largely rely on a meticulous design of nanoarchitectures and the close assembly of components. Three-dimensionally ordered macroporous (3DOM) NiO/Al nanothermite film has been successfully fabricated by integrating colloidal crystal template (CCT) method and controllable magnetron sputtering. The as-prepared NiO/Al film shows uniform structure and homogeneous dispersity, with greatly improved interfacial contact between fuel and oxidizer at the nanoscale. The total heat output of 3DOM NiO/Al nanothermite has reached 2461.27 J·g−1 at optimal deposition time of 20 min, which is significantly more than the values of other NiO/Al structural systems that have been reported before. Intrinsic reduced ignition temperature (onset temperature) and less gas production render the wide applications of 3DOM NiO/Al nanothermite. Moreover, this design strategy can also be readily generalized to realize diverse 3DOM structured nanothermites

The Clinical and Genetic Features of Co-occurring Epilepsy and Autism Spectrum Disorder in Chinese Children

There is still no comprehensive description of the general population regarding clinical features and genetic etiology for co-occurring epilepsy and autism spectrum disorder (ASD) in Chinese children. This study was a retrospective study of children diagnosed with epilepsy and ASD from January 1st, 2015, to May 1st, 2018, at the Children's Hospital of Fudan University. A total of 117 patients met the inclusion criteria, and 103 subjects were eligible. Among them, 88 underwent genetic testing, and 47 children (53.4%) were identified as having pathogenic or likely pathogenic variants: 39 had single gene mutations (83.0%, 39/47), and eight had copy number variants (17.0%, 8/47), with SCN1A (14.9%, 7/47) and MECP2 (10.6%, 5/47) gene mutations being the most common. Mutations in other genes encoding voltage-gated ion channels including SCN2A, CACNA1A, CACNA1H, CACNA1D, and KCNQ2 were also common, but the number of individual cases for each gene was small. Epilepsy syndrome and epilepsy-associated syndrome were more common (P = 0.014), and higher rates of poly-therapy (P = 0.01) were used in the positive genetic test group than in the negative group. There were no statistically significant differences in drug-refractory epilepsy, ASD severity, or intellectual disability between the positive genetic test group and the negative genetic group. These data strongly indicate the need for ASD screening in children with epilepsy with voltage-gated ion channel gene variants for better diagnosis and early intervention

Knowledge Creation Process and Sustainable Competitive Advantage: the Role of Technological Innovation Capabilities

This study examines the relationship between the knowledge creation process and technological innovation capabilities, and analyzes their effect on a firm’s sustainable competitive advantage using a knowledge-based view theoretical framework. We conduct structural equation modeling analyses using survey data from 315 Chinese industrial firms to test the direct and indirect effects of the knowledge creation process on sustainable competitive advantage. Technological innovation capabilities—operationalized to reflect the dimensions of process innovation capability and product innovation capability—are used as the mediating variable for explaining the relationship between the knowledge creation process and sustainable competitive advantage. The results indicate that the knowledge creation process does not have a significant direct effect on sustainable competitive advantage. Rather, the knowledge creation process can only influence the sustainable competitive advantage through the mediating effect of technological innovation capabilities completely. Consequently, the knowledge creation process favors the development of technological innovation capabilities for processes and products, because processes and products can lead to a sustainable competitive advantage

Smart City Development and Residents’ Well-Being

The development of smart cities has greatly improved the living and working environment of urban residents, but whether it can enhance the happiness of urban residents is a controversial topic. In this study, we investigate residents’ experiences of obtaining information, services and networks in smart cities from the aspects of safety, usefulness and convenience, and empirically explore their relationship with residents’ subjective well-being (SWB). The results show that residents’ safety, usefulness and convenience experiences of obtaining information, services and networks in smart cities all have positive impacts on their SWB, and the relationship between residents’ safety experience and SWB is, to a certain extent, mediated by their usefulness and convenience experiences

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Data from: Gap initiation with 20.35 mm: an initiator integrating the Al/CuOx multilayer film and traditional electronic plug to enhance the ignition ability

IIn order to enhance the ignition ability and reliability of traditional electronic initiators, a novel electronic initiator has been designed to integrate with a nanothermite multilayer film and an electrode plug. The Al/CuOx nanothermite multilayer film with different thickness is deposited on the surface of electrode plug by magnetron sputtering which used Pt-W wire as electronic resistance. The exothermicity of Al/CuOx nanothermite multilayer film is so favorable that the ignition ability of electronic initiator is significantly improved. The fully firing-voltage sensitivity of the electronic initiator is 10.8 V. The thickness of Al/CuOx multilayer film has negligible effects on the ignition time and ignition energy, but leads to great impacts on the function time, the maximum length of combustion flame and ignition ability. The electrical ignition experiments have exhibited outstanding ignition ability, since the electronic initiator can easily fire the insensitive ignition composition of boron-potassium nitrate (B-KNO3) tablet in a gap of 20.35 mm. It proves that this novel propose of remolding the tradition electronic ignition devices will distinctly improve the ignition ability and reliability of electronic initiator

In Situ Electrochemical Construction of CuN₃@CuCl Hybrids for Controllable Energy Release and Self-Passivation Ability

Advanced energetic materials (EMs) play a crucial role in the advancement of microenergetic systems as actuation parts, igniters, propulsion units, and power. The sustainable electrosynthesis of EMs has gained momentum and achieved substantial improvements in the past decade. This study presents the facile synthesis of a new type of high-performance CuN3@CuCl hybrids via a co-electrodeposition methodology utilizing porous Cu as the sacrificial template. The composition, morphology, and energetic characteristics of the CuN3@CuCl hybrids can be easily tuned by adjusting the deposition times. The resulting hybrids demonstrate remarkable energy output (1120 J·g–1) and good laser-induced initiating ability. As compared with porous CuN3, the uniform doping of inert CuCl enhances the electrostatic safety of the hybridized material without compromising its overall energetic characteristics. Notably, the special oxidizing behavior of CuCl gradually lowers the susceptibility of the hybrid material to laser and electrostatic stimulation. This has significant implications for the passivation or self-destruction of highly sensitive EMs. Overall, this study pioneers a new path for the development of MEMS-compatible EMs, facilitating further microenergetic applications