Magnetic properties of undoped Cu2O fine powders with magnetic impurities and/or cation vacancies

Fine powders of micron- and submicron-sized particles of undoped Cu2O semiconductor, with three different sizes and morphologies have been synthesized by different chemical processes. These samples include nanospheres 200 nm in diameter, octahedra of size 1 micron, and polyhedra of size 800 nm. They exhibit a wide spectrum of magnetic properties. At low temperature, T = 5 K, the octahedron sample is diamagnetic. The nanosphere is paramagnetic. The other two polyhedron samples synthesized in different runs by the same process are found to show different magnetic properties. One of them exhibits weak ferromagnetism with T_C = 455 K and saturation magnetization, M_S = 0.19 emu/g at T = 5 K, while the other is paramagnetic. The total magnetic moment estimated from the detected impurity concentration of Fe, Co, and Ni, is too small to account for the observed magnetism by one to two orders of magnitude. Calculations by the density functional theory (DFT) reveal that cation vacancies in the Cu2O lattice are one of the possible causes of induced magnetic moments. The results further predict that the defect-induced magnetic moments favour a ferromagnetically coupled ground state if the local concentration of cation vacancies, n_C, exceeds 12.5%. This offers a possible scenario to explain the observed magnetic properties. The limitations of the investigations in the present work, in particular in the theoretical calculations, are discussed and possible areas for further study are suggested.Comment: 20 pages, 5 figures 2 tables, submitted to J Phys Condense Matte

Observational Constraints on First-Star Nucleosynthesis. I. Evidence for Multiple Progenitors of CEMP-no Stars

We investigate anew the distribution of absolute carbon abundance, $A$(C) $= \log\,\epsilon$(C), for carbon-enhanced metal-poor (CEMP) stars in the halo of the Milky Way, based on high-resolution spectroscopic data for a total sample of 305 CEMP stars. The sample includes 147 CEMP-$s$ (and CEMP-r/s) stars, 127 CEMP-no stars, and 31 CEMP stars that are unclassified, based on the currently employed [Ba/Fe] criterion. We confirm previous claims that the distribution of $A$(C) for CEMP stars is (at least) bimodal, with newly determined peaks centered on $A$(C)$=7.96$ (the high-C region) and $A$(C)$=6.28$ (the low-C region). A very high fraction of CEMP-$s$ (and CEMP-r/s) stars belong to the high-C region, while the great majority of CEMP-no stars reside in the low-C region. However, there exists complexity in the morphology of the $A$(C)-[Fe/H] space for the CEMP-no stars, a first indication that more than one class of first-generation stellar progenitors may be required to account for their observed abundances. The two groups of CEMP-no stars we identify exhibit clearly different locations in the $A$(Na)-$A$(C) and $A$(Mg)-$A$(C) spaces, also suggesting multiple progenitors. The clear distinction in $A$(C) between the CEMP-$s$ (and CEMP-$r/s$) stars and the CEMP-no stars appears to be $as\ successful$, and$likely\ more\ astrophysically\ fundamental$, for the separation of these sub-classes as the previously recommended criterion based on [Ba/Fe] (and [Ba/Eu]) abundance ratios. This result opens the window for its application to present and future large-scale low- and medium-resolution spectroscopic surveys.Comment: 26pages, 7 figures, and 3 Tables ; Accepted for publication in ApJ; added more data and corrected minor inconsistencies existed in the compiled data of the previous studie

2-((E)-{(S)-(6-Meth­oxy­quinolin-4-yl)[(2S)-8-vinyl­quinuclidin-2-yl]methyl­imino}­meth­yl)phenol

The title compound, C27H29N3O2, adopts an E configuration with respect to the C=N bond. The molecular structure is stabilized by inter­molecular O—H⋯N inter­actions between a hy­droxy H atom and the N atom on the quinoline ring

Loss of the tumor suppressor, Tp53, enhances the androgen receptor-mediated oncogenic transformation and tumor development in the mouse prostate.

Recent genome analysis of human prostate cancers demonstrated that both AR gene amplification and TP53 mutation are among the most frequently observed alterations in advanced prostate cancer. However, the biological role of these dual genetic alterations in prostate tumorigenesis is largely unknown. In addition, there are no biologically relevant models that can be used to assess the molecular mechanisms for these genetic abnormalities. Here, we report a novel mouse model, in which elevated transgenic AR expression and Trp53 deletion occur simultaneously in mouse prostatic epithelium to mimic human prostate cancer cells. These compound mice developed an earlier onset of high-grade prostatic intraepithelial neoplasia and accelerated prostate tumors in comparison with mice harboring only the AR transgene. Histological analysis showed prostatic sarcomatoid and basaloid carcinomas with massive squamous differentiation in the above compound mice. RNA-sequencing analyses identified a robust enrichment of the signature genes for human prostatic basal cell carcinomas in the above prostate tumors. Master regulator analysis revealed SOX2 as a transcriptional regulator in prostatic basal cell tumors. Elevated expression of SOX2 and its downstream target genes were detected in prostatic tumors of the compound mice. Chromatin immunoprecipitation analyses implicate a coregulatory role of AR and SOX2 in the expression of prostatic basal cell signature genes. Our data demonstrate a critical role of SOX2 in prostate tumorigenesis and provide mechanistic insight into prostate tumor aggressiveness and progression mediated by aberrant AR and p53 signaling pathways

Fabrication of submicron structures in nanoparticle/polymer composite by holographic lithography and reactive ion etching

We report on the fabrication of nanoparticle/polymer submicron structures by combining holographic lithography and reactive ion etching. Silica nanoparticles are uniformly dispersed in a (SU8) polymer matrix at a high concentration, and in situ polymerization (cross-linking) is used to form a nanoparticle/polymer composite. Another photosensitive SU8 layer cast upon the nanoparticle/SU8 composite layer is structured through holographic lithography, whose pattern is finally transferred to the nanoparticle/SU8 layer by the reactive ion etching process. Honeycomb structures in a submicron scale are experimentally realized in the nanoparticle/SU8 composite.This work was supported in part by the US Air Force Office for Scientific Research and in part by National Basic Research Program 973 of China No. 2004CB719800

Low-Energy Electron Scattering from c-C4F8

Electron collision cross-sections of c-C4F8 were investigated at low energies by using the R-matrix method. The static exchange (SE), static exchange with polarization (SEP), and close-coupling (CC) models of the R-matrix method were used for the calculation of the scattering cross-section. The shape resonance was detected with all the models at around 3~4 eV, and a Feshbach resonance was detected with the SEP model at 7.73 eV, in good agreement with the previous theoretical calculation. The resonance detected was also associated with the experimental dissociative electron attachment of c-C4F8, which displayed the resonances at the same energy range. The cross-sections calculated are important for plasma modeling and applications

Entropy of the FRW cosmology based on the brick wall method

The brick wall method in calculations of the entropy of black holes can be applied to the FRW cosmology in order to study the statistical entropy. An appropriate cutoff satisfying the covariant entropy bound can be chosen so that the entropy has a definite bound. Among the entropy for each of cosmological eras, the vacuum energy-dominated era turns out to give the maximal entropy which is in fact compatible with assumptions from the brick wall method.Comment: 10 pages, 2 figure