3,809 research outputs found
Unusual structural tuning of magnetism in cuprate perovskites
Understanding the structural underpinnings of magnetism is of great
fundamental and practical interest. Se_{1-x}Te_{x}CuO_{3} alloys are model
systems for the study of this question, as composition-induced structural
changes control their magnetic interactions. Our work reveals that this
structural tuning is associated with the position of the supposedly dummy atoms
Se and Te relative to the super-exchange (SE) Cu--O--Cu paths, and not with the
SE angles as previously thought. We use density functional theory,
tight-binding, and exact diagonalization methods to unveil the cause of this
surprising effect and hint at new ways of engineering magnetic interactions in
solids.Comment: 4 pages, with 4 postscript figures embedded. Uses REVTEX4 and
graphicx macro
Hydrogen Absorption Properties of Metal-Ethylene Complexes
Recently, we have predicted [Phys. Rev. Lett. 97, 226102 (2006)] that a
single ethylene molecule can form stable complexes with light transition metals
(TM) such as Ti and the resulting TMn-ethylene complex can absorb up to ~12 and
14 wt % hydrogen for n=1 and 2, respectively. Here we extend this study to
include a large number of other metals and different isomeric structures. We
obtained interesting results for light metals such as Li. The ethylene molecule
is able to complex with two Li atoms with a binding energy of 0.7 eV/Li which
then binds up to two H2 molecules per Li with a binding energy of 0.24 eV/H2
and absorption capacity of 16 wt %, a record high value reported so far. The
stability of the proposed metal-ethylene complexes was tested by extensive
calculations such as normal-mode analysis, finite temperature first-principles
molecular dynamics (MD) simulations, and reaction path calculations. The phonon
and MD simulations indicate that the proposed structures are stable up to 500
K. The reaction path calculations indicate about 1 eV activation barrier for
the TM2-ethylene complex to transform into a possible lower energy
configuration where the ethylene molecule is dissociated. Importantly, no
matter which isometric configuration the TM2-ethylene complex possesses, the TM
atoms are able to bind multiple hydrogen molecules with suitable binding energy
for room temperature storage. These results suggest that co-deposition of
ethylene with a suitable precursor of TM or Li into nanopores of light-weight
host materials may be a very promising route to discovering new materials with
high-capacity hydrogen absorption properties
The effects of charmonium on the properties of the hidden charm poles in effective field theory
In this study, the properties of the hidden charm poles are
analyzed under the variation of the bare 2P charmonium mass within the
effective field theory proposed in Ref. \cite{Cincioglu:2016fkm}. The main
focus of the current work is on the pole trajectory of the
charmonium dressed by the meson loops. It is shown that having a
bare charmonium pole above or below the two-meson threshold has radically
different phenomenologies, also depending on how close the pole is to the
threshold.Comment: 16 pages, 2 figure
Towards a Microscopic Model of Magnetoelectric Interactions in Ni3V2O8
We develop a microscopic magnetoelectric coupling in NiVO (NVO)
which gives rise to the trilinear phenomenological coupling used previously to
explain the phase transition in which magnetic and ferroelectric order
parameters appear simultaneously. Using combined neutron scattering
measurements and first-principles calculations of the phonons in NVO, we
determine eleven phonons which can induce the observed spontaneous
polarization. Among these eleven phonons, we find that a few of them can
actually induce a significant dipole moment. Using the calculated atomic
charges, we find that the required distortion to induce the observed dipole
moment is very small (~0.001 \AA) and therefore it would be very difficult to
observe the distortion by neutron-powder diffraction. Finally, we identify the
derivatives of the exchange tensor with respect to atomic displacements which
are needed for a microscopic model of a spin-phonon coupling in NVO and which
we hope will be obtained from a fundamental quantum calculation such as LDA+U.
We also analyze two toy models to illustrate that the Dzyaloskinskii-Moriya
interaction is very important for coexisting of magnetic and ferroelectric
order but it is not the only mechanism when the local site symmetry of the
system is low enough.Comment: 20 pages, 10 figure
Anisotropic Spin Hamiltonians due to Spin-Orbit and Coulomb Exchange Interactions
This paper contains the details of Phys. Rev. Lett. 73, 2919 (1994) and, to a
lesser extent, Phys. Rev. Lett. 72, 3710 (1994). We treat a Hubbard model which
includes all the 3d states of the Cu ions and the 2p states of the O ions. We
also include spin-orbit interactions, hopping between ground and excited
crystal field states of the Cu ions, and rather general Coulomb interactions.
Our analytic results for the spin Hamiltonian, H, are corroborated by numerical
evaluations of the energy splitting of the ground manifold for two holes on
either a pair of Cu ions or a Cu-O-Cu complex. In the tetragonal symmetry case
and for the model considered, we prove that H is rotationally invariant in the
absence of Coulomb exchange. When Coulomb exchange is present, each bond
Hamiltonian has full biaxial anisotropy, as expected for this symmetry. For
lower symmetry situations, the single bond spin Hamiltonian is anisotropic at
order t**6 for constant U and at order t**2 for nonconstant U. (Constant U
means that the Coulomb interaction between orbitals does not depend on which
orbitals are involved.)Comment: 50 pages, ILATEX Version 2.09 <13 Jun 1989
Field Dependence of Electronic Specific Heat in Two-Band Superconductors
The vortex structure is studied in light of MgB theoretically based on a
two-band superconducting model by means of Bogoliubov-de Gennes framework. The
field dependence of the electronic specific heat coefficient is
focused. The exponent in is shown to
become smaller by adjusting the gap ratio of the two gaps on the major and
minor bands. The observed extremely small value could be
explained reasonably well in this two-band model with the gap ratio .Comment: 5 pages, 4 figures, to be published in J. Phys. Soc. Jp
Stability analysis of second order pulsed Raman laser in dispersion managed systems
8siWavelength tunable synchronous pulse sources are highly desirable for spectroscopy and optical diagnostics. The common method to generate short pulses in the fiber is the use of nonlinear induced spectral broadening which result in soliton shaping in anomalous dispersion regime. However, to generate ultra-short pulses, broadband gain mechanism is also required. In recent years, Raman fiber lasers have retrieved strong interest due to their capability of serving as pump sources in gain-flattened amplifiers for optical communication systems. The fixed-wavelength Raman lasers have been widely studied in the last years, but recently, much focus has been on the multi wavelength tunable Raman fiber lasers which generate output Stokes pulses in a broad wavelength range by so called cascaded stimulated Raman scattering. In this paper we investigate synchronous 1st and 2nd order pulsed Raman lasers that can achieve frequency spacing of up to 1000cm-1 that is highly desired for CARS microscopy. In particular, analytical and numerical analysis of pulsed stability derived for Raman lasers by using dispersion managed telecom fibers and pumped by 1530nm fiber lasers. We show the evolution of the 1st and 2nd order Stokes signals at the output for different pump power and SMF length (determines the net anomalous dispersion) combinations. We investigated the stability of dispersion managed synchronous Raman laser up to second order both analytically and numerically. The results show that the stable 2nd order Raman Stokes pulses with 0.04W to 0.1W peak power and 2ps to 3.5ps pulse width can be achieved in dispersion managed systemopenopenS. K. Kalyoncu; S. Gao; E.K. Tien; Y. Huang; D. Yildirim; E. Adas; S. Wabnitz; O. BoyrazS. K., Kalyoncu; S., Gao; E. K., Tien; Y., Huang; D., Yildirim; E., Adas; Wabnitz, Stefan; O., Boyra
Magnetic anisotropies and general on--site Coulomb interactions in the cuprates
This paper derives the anisotropic superexchange interactions from a Hubbard
model for excitations within the copper 3d band and the oxygen 2p band of the
undoped insulating cuprates. We extend the recent calculation of Yildirim et
al. [Phys. Rev. B {\bf VV}, pp, 1995] in order to include the most general
on--site Coulomb interactions (including those which involve more than two
orbitals) when two holes occupy the same site. Our general results apply when
the oxygen ions surrounding the copper ions form an octahedron which has
tetragonal symmetry (but may be rotated as in lanthanum cuprate). For the
tetragonal cuprates we obtain an easy--plane anisotropy in good agreement with
experimental values. We predict the magnitude of the small in--plane anisoComment: 25 pages, revte
Vibrations of the cubane molecule: inelastic neutron scattering study and theory
Cataloged from PDF version of article.Cubane (C8H8) is an immensely strained molecule whose C-C-C bond angle is 90 degrees rather than 109.5 degrees as expected for sp(3) bonding of carbon. We have measured the intramolecular vibrational spectrum of cubane using inelastic neutron scattering. The neutron data are used to test the transferability of various phenomenological potentials and tight-binding models to this highly strained molecule. Unlike these models, first-principles calculations of the INS spectrum (both energy and intensity) agree well with the experimental data. (C) 1999 Published by Elsevier Science B.V. All rights reserved
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