Fractional crystallization causes the iron isotope contrast between mid-ocean ridge basalts and abyssal peridotites

The iron isotope contrast between mid-ocean ridge basalts and abyssal peridotites is far greater than can be explained by mantle melting alone. Here we investigate a suite of mid-ocean ridge magma chamber rocks sampled by the Ocean Drilling Project Hole 735B in the Atlantis Bank of the Indian Ocean. We report major and trace element geochemistry from these rocks and measure their iron isotope compositions to investigate the potential role of fractional crystallization during melt evolution. We observe a large range of δ56Fe that defines a significant inverse curvilinear correlation with bulk rock MgO/FeOT. These data confirm that δ56Fe in the melt increases as fractional crystallization proceeds but, contrary to expectation, δ56Fe continues to increase even when oxides begin to crystallize. We conclude that iron isotope fractionation through fractional crystallization during the evolution of mid-ocean ridge basalts from abyssal peridotites reconciles the disparity in isotopic compositions between these two lithologies

Production of Glycopeptide Derivatives for Exploring Substrate Specificity of Human OGA Toward Sugar Moiety.

O-GlcNAcase (OGA) is the only enzyme responsible for removing N-acetyl glucosamine (GlcNAc) attached to serine and threonine residues on proteins. This enzyme plays a key role in O-GlcNAc metabolism. However, the structural features of the sugar moiety recognized by human OGA (hOGA) remain unclear. In this study, a set of glycopeptides with modifications on the GlcNAc residue, were prepared in a recombinant full-length human OGT-catalyzed reaction, using chemoenzymatically synthesized UDP-GlcNAc derivatives. The resulting glycopeptides were used to evaluate the substrate specificity of hOGA toward the sugar moiety. This study will provide insights into the exploration of probes for O-GlcNAc modification, as well as a better understanding of the roles of O-GlcNAc in cellular physiology

Planimetría de alta resolución del dolmen de Menga (Antequera, Málaga) mediante escaneado láser terrestre, levantamiento 3D y fotogrametría

Dielectric metasurfaces can achieve flexible beam manipulations. Herein, we study dielectric metasurfaces with different refractive indices, periods, incident angles, and cross-sectional shapes to determine the metasurface working mechanisms. Perfect transmission mainly depends on multipolar interference that can be used to control the transmission modes through the hybrid periods, hybrid cross sections, and multilayers. Perfect reflection is strongly influenced by the period of the metasurface and occurs only when the period is shorter than incident wavelength, which can be attributed to the lattice coupling. Furthermore, lattice coupling can be classified into two types with distinct properties: vertical mode and horizontal mode coupling. The vertical mode appears when the effective wavelength matches the feature size, whereas the horizontal mode only appears when the incident wavelength is close to the period. The horizontal mode is sensitive to the incident angle. The revealed functioning mechanisms enable further practical applications of metasurfaces

Beam Manipulation Mechanisms of Dielectric Metasurfaces

Dielectric metasurfaces can achieve flexible beam manipulations. Herein, we study dielectric metasurfaces with different refractive indices, periods, incident angles, and cross-sectional shapes to determine the metasurface working mechanisms. Perfect transmission mainly depends on multipolar interference that can be used to control the transmission modes through the hybrid periods, hybrid cross sections, and multilayers. Perfect reflection is strongly influenced by the period of the metasurface and occurs only when the period is shorter than incident wavelength, which can be attributed to the lattice coupling. Furthermore, lattice coupling can be classified into two types with distinct properties: vertical mode and horizontal mode coupling. The vertical mode appears when the effective wavelength matches the feature size, whereas the horizontal mode only appears when the incident wavelength is close to the period. The horizontal mode is sensitive to the incident angle. The revealed functioning mechanisms enable further practical applications of metasurfaces

Low-degree melt metasomatic origin of heavy Fe isotope enrichment in the MORB mantle

Studies of mid-ocean ridge basalts (MORB) show a variable Fe isotope composition of the oceanic upper mantle. To test a recent hypothesis that heavy Fe isotope enrichment in the MORB mantle results from the same process of incompatible element enrichment, we conduct an Fe isotope study of well-characterized MORB samples from a magmatically robust segment (OH-1) of the Mid-Atlantic Ridge (MAR) at ∼ 35°N. The data show large Fe isotope variation (Fe = +0.03 to +0.18‰) that correlates well with the abundances and ratios of more-to-less incompatible elements and with Sr-Nd-Hf isotopes. Our findings in support of the hypothesis can be detailed as follows: (1) the oceanic upper mantle has a heterogeneous Fe isotope composition on varying small spatial scales with isotopically heavy Fe (high-Fe) preferentially associated with pyroxenite lithologies; (2) such lithologies, which are also enriched in the progressively more incompatible elements, are of low-degree (low-F) melt metasomatic origin; (3) with all the conceivable processes considered, the low-F melt metasomatism takes place at the lithosphere-asthenosphere boundary (LAB) beneath ocean basins through crystallization of incipient (Low-F) melt in the seismic low velocity zone (LVZ) at the base of the growing oceanic lithosphere (i.e., LAB) over the Earth's history since the onset of plate tectonics, forming composite lithologies with geochemically enriched pyroxenite veins dispersed in the depleted peridotite matrix; (4) such mantle of composite lithology when transported to beneath the present-day ocean ridges will undergo decompression melting and produce MORB melts with geochemical trends of “melting-induced mixing” as observed at the MAR and global MORB; (5) we predict all this to be a globally common process and widespread