Disorder-Enhanced Dimensionless Thermoelectric Figure of Merit zT of Non-stoichiometric Organic Conductor (TTT)2I3+δ (δ ≤ 0.1)

Sample dependence of dimensionless thermoelectric figure of merit (zT) and power factor (PF) were determined for the non-stoichiometric organic conductor (TTT)2I3+δ (TTT = tetrathiatetracene, δ ≤ 0.1) with the simultaneous measurement of the electrical resistivity (ρ), thermopower (S) and thermal conductivity on small single crystals. Both the zT and PF show large sample dependence between 10 and 310 K, even though all the samples have nearly stoichiometric composition of TTT : I3- ~ 2 : 1 (δ ∼ 0). It was found that both the electrical conductivity (σ = 1/ρ) and S increase at room temperature as disorder — that is phase mismatch among the iodine chains — becomes more pronounced. This behavior contrasts the usual tendency that the S decreases as the σ increases in conventional conductors; and suggests a new strategy to improve the zT and PF by introducing an appropriate type of disorder

Wavefunction Analysis of STM Image: Surface Reconstruction of Organic Charge Transfer Salts

In this chapter, the wavefunction analysis is demonstrated, applied to the organic charge transfer salts composed of electron donor and electron acceptor molecules. Scanning tunneling microscopy (STM) images of the surface donor layers in the three charge transfer salts, α-(BEDT-TTF)2I3, β-(BEDT-TTF)2I3, and (EDO-TTF)2PF6, are analyzed with the atomic π electron orbitals of sulfur, oxygen, and carbon atoms. We have deduced three different kinds of surface molecular reconstructions as follows: (1) charge redistribution in α-(BEDT-TTF)2I3, (2) translational reconstruction up to 0.1 nm in β-(BEDT-TTF)2I3, and (3) rotational reconstruction transforming the 1D axis from the a axis to the b axis in (EDO-TTF)2PF6. Finally, it is concluded that the surface reconstruction is ascribed to the additional gain of the cohesive energy of the π electron system, provoked by the reduced steric hindrance with the anions of the missing outside double layer. The investigations of the surface states provide not only interesting behaviors of the surface cation layer, but also important insights into the electronic states of a lot of similar charge transfer crystals, as demonstrated in α-(BEDT-TTF)2I3

Spin frustration in antiperovskite systems: (TTF˙+or TSF˙+)3[(Mo6X14)2−Y−]

Two novel antiperovskite charge-transfer (CT) solids composed of a tetraselenafulvalene radical cation (TSF˙+), a dianionic molybdenum cluster unit [Mo6X14]2−, and a halogen anion (Y−) (X, Y = Cl, Br) were prepared by electrocrystallization. Their crystal structures and magnetic properties with regard to spin frustration are discussed together with those of isostructural tetrathiafulvalene (TTF) CT solids previously reported. Both TSF and TTF salts have an apex sharing distorted octahedral spin lattice with a rhombohedral R[3 with combining macron] space group. The calculated overlap integrals based on the crystal structures and insulating nature of the TSF salts indicate that they are Mott insulators. Their spin susceptibilities obeyed the Curie–Weiss law and exhibited an antiferromagnetic ordering at lower temperatures for the TSF salts (Néel temperature, TN = 3.0 K for X = Y = Cl and 5.5 K for X = Y = Br) than the TTF salts. The Curie–Weiss temperatures (|ΘCW| ∼ 1.6–6.3 K) for the TSF salts are lower than those of the TTF salts. For the TSF salts, spin-flop behavior was detected at 3.2 T for X = Y = Cl and 1.5 T for X = Y = Br at 1.9 K. Due to both the distortion of the octahedral geometry of the spin lattice and the anisotropic molecular orientation, the geometrical spin frustrations in TSF and TTF systems are weakened

Peraturan Bersama Menteri Agama dan Menteri dalam Negeri Nomor 08 dan 09 Tahun 2006 Tentang Pendirian Rumah Ibadat (Kajian dalam Perspektif Hak Asasi Manusia )

Pundamental 1945 Constitution as the rule has been set explicitly for religious freedom in the run by followers, who belong to one human rights has, but in reality the persecution of religious life and often inevitable. Between religious persecution can come from various directions such as harassing each other, mutual intimidate(violence) and that most often occurs between religious persecution that is prihal establishment synagogue. Therefore, in terms of the establishment of the synagogue there must be government intervention to regulate it, if in this case given the freedom and without any clear rules, the sectarian conflict will not be able to avoid. One step from the government to avoid conflict in the establishment of the synagogue is to be issued the Joint Decree of the Minister of Religious Affairs and the Minister of Home Affairs Number 08 and Number 09 Year 2006 About the Construction of Houses of Worship that aims to create harmony and peace between religious and have certainty Strong law

Ultrafast gigantic photo-response in (EDO-TTF)2PF6 initiated by 10-fs laser pulses

We photo-exited a charge-ordered organic salt (EDO-TTF)2PF6 with sub-10-fs optical pulses. The photo-induced metallic phase appeared within 80-fs after pumping, characterized by large changes in reflectivity (DELTA R/R~0.8) followed by strong coherent phonon modulatio