Current conduction in Schottky barrier diodes with poly(propylene glycol)-b-polystyrene block copolymer interfacial layer

Polymeric materials have gained great importance in electron devices. There has been considerable number of studies on block copolymers due to enhanced features that appear after co-polymerization. In this study, poly (propylene glycol)-b-polystyrene block copolymer has been synthesized and Schottky barrier diodes (SBDs) have been fabricated with this block copolymer. Current-voltage (I-V) measurements have been conducted at room temperature in order to investigate electrical characteristics and current conductions governing in these SBDs. Series resistance and shunt resistance of the SBDs have been calculated using Ohm’s law. Ideality factor, reverse saturation current and zero-bias barrier height of the SBDs have been extracted from the forward-bias I-V data. Fabricated SBDs exhibited high rectifying ratio of the order 104. Also, current conduction mechanisms and the density of interface states in the SBDs have been investigated. Calculated values of density of interface states in the SBDs are on the order of 1013 which is acceptable for this kind of SBDs having polymeric interfacial layer

2-Chloro-7,8,9,10-tetra­hydro­cyclo­hepta­[b]indol-6(5H)-one

In the title mol­ecule, C13H12ClNO, the dihedral angle between the benzene and pyrrole rings is 1.38 (9)°. The cyclo­heptene ring adopts a distorted twist chair and sofa conformation. Inter­molecular N—H⋯O hydrogen bonds form an R 2 2(10) loop in the crystal packing. Further, weak C—H⋯O and C—H⋯π (involving the benzene ring) inter­actions are found in the crystal structure

5-(Thio­phen-2-ylmeth­yl)-1,3,4-thia­diazol-2-amine

In the title mol­ecule, C7H7N3S2, the dihedral angle between the thio­phene and thia­diazole rings is 72.99 (5)°; the two rings are oriented so that the S atoms in each ring are on the same side. In the crystal, the three-dimensional network involves strong N—H⋯O hydrogen bonds, as well as C—H⋯π and π–π stacking inter­actions [centroid–centroid distances = 3.654 (1) and 3.495 (1) Å]

La banque de Finlande, les banques privées et les établissements hypothécaires en 1912

Suomen virallinen tilasto (SVT