Giant Rashba splitting of quasi-1D surface states on Bi/InAs(110)-(2×\times1)

Electronic states on the Bi/InAs(110)-(2$\times$1) surface and its spin-polarized structure are revealed by angle-resolved photoelectron spectroscopy (ARPES), spin-resolved ARPES, and density-functional-theory calculation. The surface state showed quasi-one-dimensional (Q1D) dispersion and a nearly metallic character; the top of the hole-like surface band is just below the Fermi level. The size of the Rashba parameter ($\alpha_{\rm R}$) reached quite a large value ($\sim$5.5 eV\AA). The present result would provide a fertile playground for further studies of the exotic electronic phenomena in 1D or Q1D systems with the spin-split electronic states as well as for advanced spintronic devices.Comment: 8 pages (double column), 7 figures and 1 tabl

Evidence of non-thermal X-ray emission from radio lobes of Cygnus A

Using deep Chandra ACIS observation data for Cygnus A, we report evidence of non-thermal X-ray emission from radio lobes surrounded by a rich intra-cluster medium (ICM). The diffuse X-ray emission, which are associated with the eastern and western radio lobes, were observed in a 0.7--7 keV Chandra$ ACIS image. The lobe spectra are reproduced with not only a single-temperature Mekal model, such as that of the surrounding ICM component, but also an additional power-law (PL) model. The X-ray flux densities of PL components for the eastern and western lobes at 1 keV are derived as 77.7^{+28.9}_{-31.9} nJy and 52.4^{+42.9}_{-42.4} nJy, respectively, and the photon indices are 1.69^{+0.07}_{-0.13} and 1.84^{+2.90}_{-0.12}, respectively. The non-thermal component is considered to be produced via the inverse Compton (IC) process, as is often seen in the X-ray emission from radio lobes. From a re-analysis of radio observation data, the multiwavelength spectra strongly suggest that the seed photon source of the IC X-rays includes both cosmic microwave background radiation and synchrotron radiation from the lobes. The derived parameters indicate significant dominance of the electron energy density over the magnetic field energy density in the Cygnus A lobes under the rich ICM environment.Comment: 8 pages, 5 figures, accepted for publication in Ap

Dynamic experimental investigation on the volatilization behavior of lead and cadmium in the simulated Municipal Solid Waste (MSW) influenced by sulfur compounds during incineration

In China, coal, often with a high level of sulfur, is always mixed with municipal solid waste (MSW) in waste incineration plants due to the low heating value and high moisture content of MSW. The influence of sulfur compounds on the volatilization of heavy metals in MSW is of great concern for China’s waste incineration plants. In this study, the continuous dynamic volatilization process of Pb and Cd is investigated by adding different forms of sulfur compounds, elemental sulfur (S), and sodium sulfate (Na2SO4), to the simulated MSW in a laboratory incinerator, at both 1 and 3 wt %, respectively. The experimental results show that the added S begins to affect the volatilization of Pb and Cd at about 700 °C; adding S can lead up to 49.6% reduction in the volatilization of Pb, as the produced sulfur dioxide is promoting the formation of a condensed sulfate phase, and part of Pb is fixed in the form of PbS in the bottom ash. But for Cd, adding S causes up to 15.9% increase in its volatilization as S seizes part of O2 in the air, which is conducive to forming the reducing atmosphere. In the reducing atmosphere, CdO can be easily reduced to Cd, which volatilizes more easily than CdO at high temperatures. In fact, in the reducing atmosphere, the volatilization of Cd far outweighs the volatilization of Pb at 700–800 °C. On the other hand, adding Na2SO4 almost has no influence on the volatilization of lead and cadmium below 900 °C

Time-, spin-, and angle-resolved photoemission spectroscopy with a 1-MHz 10.7-eV pulse laser

We describe a setup of time-, spin-, and angle-resolved photoemission spectroscopy (tr-SARPES) employing a 10.7-eV ($\lambda$=115.6 nm) pulse laser at 1-MHz repetition rate as a probe photon source. This equipment effectively combines technologies of a high-power Yb:fiber laser, ultraviolet-driven harmonic generation in Xe gas, and a SARPES apparatus equipped with very-low-energy-electron-diffraction (VLEED) spin detectors. A high repetition rate (1 MHz) of the probe laser allows experiments with the photoemission space-charge effects significantly reduced, despite a high flux of 10$^{13}$ photons/s on the sample. The relatively high photon energy (10.7 eV) also brings the capability of observing a wide momentum range that covers the entire Brillouin zone of many materials while ensuring high momentum resolution. The experimental setup overcomes a low efficiency of spin-resolved measurements, which gets even more severe for the pump-probed unoccupied states, and affords for investigating ultrafast electron and spin dynamics of modern quantum materials with energy and time resolutions of 25 meV and 360 fs, respectively.Comment: 11 pages, 7 figure

Origins of thermal spin depolarization in half-metallic ferromagnet CrO2_2

Using high-resolution spin-resolved photoemission spectroscopy, we observed a thermal spin depolarization to which all spin-polarized electrons contribute. Furthermore we observed a distinct minority spin state near the Fermi level and a corresponding depolarization that seldom contributes to demagnetization. The origin of this depolarization has been identified as the many-body effect characteristics of half-metallic ferromagnets. Our investigation opens an experimental field of itinerant ferromagnetic physics focusing on phenomena with sub-meV energy scale.Comment: 19 pages, 10 figure

Nature of the Dirac gap modulation and surface magnetic interaction in axion antiferromagnetic topological insulator MnBi2Te4A

Modification of the gap at the Dirac point (DP) in axion antiferromagnetic topological insulator MnBi2Te4 and its electronic and spin structure have been studied by angle- and spin-resolved photoemission spectroscopy (ARPES) under laser excitation at various temperatures (9-35 K), light polarizations and photon energies. We have distinguished both large (60-70 meV) and reduced (< 20 meV) gaps at the DP in the ARPES dispersions, which remain open above the Neel temperature (T-N = 24.5 K). We propose that the gap above T-N remains open due to a short-range magnetic field generated by chiral spin fluctuations. Spin-resolved ARPES, XMCD and circular dichroism ARPES measurements show a surface ferromagnetic ordering for the "large gap" sample and apparently significantly reduced effective magnetic moment for the "reduced gap" sample. These observations can be explained by a shift of the Dirac cone (DC) state localization towards the second Mn layer due to structural disturbance and surface relaxation effects, where DC state is influenced by compensated opposite magnetic moments. As we have shown by means of ab-initio calculations surface structural modification can result in a significant modulation of the DP gap.The authors acknowledge support by the Saint Petersburg State University (Grant No. 51126254), Russian Science Foundation (Grant No. 18-12-00062 in part of the photoemission measurements and Grant No. 18-12-00169 in part of the electronic band structure calculations) and by Russian Foundation of Basic Researches (Grants Nos. 18-52-06009 and 20-32-70179) and Science Development Foundation under the President of the Republic of Azerbaijan (Grant No. EI F-BGM-4-RFTF1/2017-21/04/1-M-02). A. Kimura was financially supported by KAKENHI (Grants No. 17H06138, No. 17H06152, and No. 18H03683). S.V.E. and E.V.C. acknowledge support by the Fundamental Research Program of the State Academies of Sciences (line of research III.23.2.9). The authors kindly acknowledge the HiSOR staff and A. Harasawa at ISSP for technical support and help with the experiment. The ARPES measurements at HiSOR were performed with the approval of the Proposal Assessing Committee (Proposal Numbers: 18BG027 and 19AG048). XAS and XMCD measurements were performed at BL23SU of SPring-8 (Proposal Nos. 2018A3842 and 2018B3842) under the Shared Use Program of JAEA Facilities (Proposal Nos. 2018A-E25 and 2018B-E24) with the approval of Nanotechnology Platform project supported by MEXT, Japan (Proposal Nos. A-18-AE-0020 and A-18-AE-0042). M. M. Otrokov acknowledges the support by Spanish Ministerio de Ciencia e Innovacion (Grant no. PID2019-103910GB-I00). K. Yaji was financially supported by KAKENHI (Grants No. 18K03484)

Nature of the Dirac gap modulation and surface magnetic interaction in axion antiferromagnetic topological insulator MnBi2_2Te4_4

Modification of the gap at the Dirac point (DP) in antiferromagnetic (AFM) axion topological insulator MnBi$_2$Te$_4$ and its electronic and spin structure has been studied by angle- and spin-resolved photoemission spectroscopy (ARPES) under laser excitation with variation of temperature (9-35~K), light polarization and photon energy. We have distinguished both a large (62-67~meV) and a reduced (15-18~meV) gap at the DP in the ARPES dispersions, which remains open above the N\'eel temperature ($T_\mathrm{N}=24.5$~K). We propose that the gap above $T_\mathrm{N}$ remains open due to short-range magnetic field generated by chiral spin fluctuations. Spin-resolved ARPES, XMCD and circular dichroism ARPES measurements show a surface ferromagnetic ordering for large-gap sample and significantly reduced effective magnetic moment for the reduced-gap sample. These effects can be associated with a shift of the topological DC state towards the second Mn layer due to structural defects and mechanical disturbance, where it is influenced by a compensated effect of opposite magnetic moments