Distribution of HNCO 505−404_{05}-4_{04} in Massive Star-forming Regions

The goal of this paper is to study the spatial distribution of HNCO in massive star-forming regions, and investigate its spatial association with infrared sources, as well as physical conditions in region of HNCO emission. We have mapped nine massive star-forming regions in HNCO 5$_{05}-4_{04}$ with the Purple Mountain Observatory 13.7m telescope. The C18O maps of these sources were obtained simultaneously. The HNCO emission shows compact distribution, with emission peak centred on water masers. Nearly all the HNCO clumps show signs of embedded mid-infrared or far-infrared sources. The FWHM sizes of HNCO clumps are significantly smaller than C18O clumps but rather similar to HC3N clumps. We also found good correlation between the integrated intensities, linewidths and LSR velocities of HNCO and HC3N emission, implying similar excitation mechanism of these two species. As such, collisional excitation is likely to be the dominant excitation mechanism for HNCO 5$_{05}-4_{04}$ emission in galactic massive star-forming regions.Comment: 9 pages, 4 figures, accepted by A&

The catalogues and mid-infrared environment of Interstellar OH Masers

Data for a number of OH maser lines have been collected from surveys. The posi- tions are compared to recent mid-infrared (MIR) surveys such as Spitzer-GLIMPSE and WISE, restricting the comparison to point sources. The colors and intensities of the IR sources are compared. There are many 18 cm OH masers, but far fewer in lines arising from higher energy levels. We also make a comparison with the 5 cm Class II methanol masers. We have divided the results into 3 subsamples: those associated with OH masers only, those associated with OH masers and Class II methanol masers, and those only associated with Class II methanol masers. There are no obvious dif- ferences in the color-color or color-magnitude results for the GLIMPSE point sources. However, according to the results from the WISE 22 {\mu}m survey, the sources associ- ated with OH masers are brighter than those associated with methanol masers. We interpret the presence of OH and methanol masers mark the locations of regions where stars are forming. The OH masers are located on the borders of sharp features found in the IR. These are referred to as bubbles. If the OH masers mark the positions of protostars, the result provides indirect evidence for triggered star formation caused by the expansion of the bubbles.Comment: 23 pages (11 pages online only), 12 figures, Accepted. Monthly Notices of the Royal Astronomical Society,201

Comparison of Gaia DR2 Parallaxes of Stars with VLBI Astrometry

We compare the parallaxes of stars from VLBI astrometry in the literature to those in the Gaia DR2 catalog. Our full sample contains young stellar objects, evolved AGB stars, pulsars and other radio stars. Excluding AGB stars, which show significant discrepancies between Gaia and VLBI parallaxes, and stars in binary systems, we obtain an average, systematic, parallax offset of $-75 \pm 29~\mu$as for Gaia DR2, consistent with their estimate of a parallax zero-point between $-100$ and 0 $\mu$as.Comment: Accepted by Ap

The Parallax of the Red Hypergiant VX Sgr with Accurate Tropospheric Delay Calibration

We report astrometric results of VLBI phase-referencing observations of 22 GHz \hho\ masers emission toward the red hypergiant \vxsgr, one of most massive and luminous red hypergiant stars in our Galaxy, using the Very Long Baseline Array. A background source, \Jtwoze, projected 4\d4 from the target \vxsgr, was used as the phase reference. For the low declinations of these sources, such a large separation normally would seriously degrade the relative astrometry. We use a two-step method of tropospheric delay calibration, which combines the VLBI geodetic-block (or GPS) calibration with an image-optimization calibration, to obtain a trigonometric parallax of $0.64\pm0.04$ mas, corresponding to a distance of 1.56$^{+0.11}_{-0.10}$ kpc. The measured proper motion of \vxsgr\ is $0.36\pm0.76$ and $-2.92\pm0.78$ \masy\ in the eastward and northward directions. The parallax and proper motion confirms that \vxsgr\ belong to the Sgr OB1 association. Rescaling bolometric luminosities in the literature to our parallax distance, we find the luminosity of \vxsgr~is $(1.95 \pm 0.62) \times 10^5$ \Lsun, where the uncertainty is dominated by differing photometry measurements.Comment: 16 pages, 10 figures, accepted by Ap

Extended ammonia observations towards the 'Integral-Shaped Filament'

Recent observations suggest a scenario in which filamentary structures in the ISM represent the first step towards clumps/cores and eventually star formation. The densest filaments would then fragment into prestellar cores owing to gravitational instability. We seek to understand the roles filamentary structures play in high-mass star formation. We mapped the integral-shaped filament (ISF) in NH3 (1, 1) and (2, 2). The whole filamentary structure is uniformly and fully sampled. We find that the morphology revealed by the map of velocity-integrated intensity of the NH3 (1, 1) line is closely associated with the dust ridge. We identify 6 "clumps" related to the well known OMC-1 to 5 and 11 "sub-clumps" within the map and they are separated not randomly but in roughly equal intervals along the ISF. The average spacing of clumps is 11.30'$\pm$1.31' (1.36$\pm$0.16 pc ) and the average spacing of sub-clumps is 7.18'$\pm$1.19' (0.86$\pm$0.14 pc). These spacings agree well with the predicted values of the thermal (0.86 pc) and turbulent sausage instability (1.43 pc) by adopting a cylindric geometry of the ISF with an inclination of $60^{\circ}$ with respect to the line of sight. We also find a velocity gradient of about 0.6 km s-1 pc-1 that runs along the ISF which likely arises from an overall rotation of the Orion A molecular cloud. The inferred ratio between rotational and gravitational energy is well below unity. Furthermore, fluctuations are seen in the centroid velocity diagram along the ISF. The OMC-1 to 5 clouds are located close to the local extrema of the fluctuations, which suggests that there exist gas flows associated with these clumps in the ISF. The derived NH3 (1, 1) and (2, 2) rotation temperatures in the OMC-1 are about 30-40 K. In OMC-2, OMC-3, and the northern part of OMC-4, we find higher and lower temperatures at the boundaries and in the interior, respectively.Comment: Accepted by A&A. 14 pages, 14 figure

Parallaxes for star forming regions in the inner Perseus spiral arm

We report trigonometric parallax and proper motion measurements of 6.7-GHz CH3OH and 22-GHz H2O masers in eight high-mass star-forming regions (HMSFRs) based on VLBA observations as part of the BeSSeL Survey. The distances of these HMSFRs combined with their Galactic coordinates, radial velocities, and proper motions, allow us to assign them to a segment of the Perseus arm with ~< 70 deg. These HMSFRs are clustered in Galactic longitude from ~30 deg to ~50, neighboring a dirth of such sources between longitudes ~50 deg to ~90 deg.Comment: 18 pages, 4 figures, accepted for publication in The Astronomical Journal. arXiv admin note: text overlap with arXiv:1312.385

Widespread Presence of Glycolaldehyde and Ethylene Glycol Around Sagittarius B2

We report the detection of widespread CH$_2$OHCHO and HOCH$_2$CH$_2$OH emission in Galactic center giant molecular cloud Sagittarius B2 using the Shanghai Tianma 65m Radio Telescope. Our observations show for the first time that the spatial distribution of these two important prebiotic molecules extends over 15 arc-minutes, corresponding to a linear size of approximately 36 pc. These two molecules are not just distributed in or near the hot cores. The abundance of these two molecules seems to decrease from the cold outer region to the central region associated with star-formation activity. Results present here suggest that these two molecules are likely to form through a low temperature process. Recent theoretical and experimental studies demonstrated that prebiotic molecules can be efficiently formed in icy grain mantles through several pathways. However, these complex ice features cannot be directly observed, and most constraints on the ice compositions come from millimeter observations of desorbed ice chemistry products. These results, combined with laboratory studies, strongly support the existence of abundant prebiotic molecules in ices.Comment: 20 pages, 7 figures, accepted by Ap

The radio properties of the OH megamaser galaxy IRAS 02524+2046

We present results from VLBI observations of continuum and OH line emission in IRAS 02524+2046 and also arcsecond-scale radio properties of this galaxy using VLA archive data. We found that there is no significant detection of radio continuum emission from VLBI observations. The arcsecond-scale radio images of this source show no clear extended emission, the total radio flux density at L and C band are around 2.9 mJy and 1.0 mJy respectively, which indicate a steep radio spectral index between the two band. Steep spectral index, low brightness temperature and high $q$-ratio (the FIR to the radio flux density), which are three critical indicators in classification of radio activity in the nuclei of galaxies, are all consistent with the classification of this source as a starburst galaxy from its optical spectrum. The high-resolution line profile show that both of \textbf{the 1665 and 1667 MHz OH maser} line have been detected which show three and two clear components respectively. The channel maps show that the maser emission are distributed in a region $\sim$ 210 pc $\times$ 90 pc, the detected maser components at different region show similar double spectral feature, which might be an evidence that this galaxy is at a stage of major merger as seen from the optical morphology.Comment: 13pages,9 figures, accepted by A&

Large-Scale Kinematics, Astrochemistry and Magnetic Field Studies of Massive Star-forming Regions through HC3N, HNC and C2H Mappings

We have mapped 27 massive star-forming regions associated with water masers using three dense gas tracers: HC3N 10-9, HNC 1-0 and C2H 1-0. The FWHM sizes of HNC clumps and C2H clumps are about 1.5 and 1.6 times higher than those of HC3N, respectively, which can be explained by the fact that HC3N traces more dense gas than HNC and C2H. We found evidence for increase in optical depth of C2H with `radius' from center to outer regions in some targets, supporting the chemical model of C2H. The C2H optical depth is found to decline as molecular clouds evolve to later stage, suggesting that C2H might be used as "chemical clock" for molecular clouds. Large-scale kinematic structure of clouds was investigated with three molecular lines. All these sources show significant velocity gradients. The magnitudes of gradient are found to increase towards the inner region, indicating differential rotation of clouds. Both the ratio of rotational to gravitational energy and specific angular momentum seem to decrease toward the inner region, implying obvious angular momentum transfer, which might be caused by magnetic braking. The average magnetic field strength and number density of molecular clouds is derived using the uniformly magnetic sphere model. The derived magnetic field strengths range from 3 to 88 \mu G, with a median value of 13 \mu G. The mass-to-flux ratio of molecular cloud is calculated to be much higher than critical value with derived parameters, which agrees well with numerical simulations.Comment: 56 pages, 24 figures, accepted by Ap

Phase Engineering of MXene Derivatives Via Molecular Design for High-Rate Sodium-Ion Batteries

Since 2019, research into MXene derivatives has seen a dramatic rise; further progress requires a rational design for specific functionality. Herein, through a molecular design by selecting suitable functional groups in the MXene coating, we have implemented the dual N doping of the derivatives, nitrogen-doped TiO2@nitrogen-doped carbon nanosheets (N-TiO2@NC), to strike a balance between the active anatase TiO2 at low temperatures, and carbon activation at high temperatures. The NH3 reduction environment generated at 400 °C as evidenced by the in situ pyrolysis SVUV-PIMS process is crucial for concurrent phase engineering. With both electrical conductivity and surface Na+ availability, the N-TiO2@NC achieves higher interface capacitive-like sodium storage with long-term stability. More than 100 mAh g−1 is achieved at 2 A g−1 after 5000 cycles. The proposed design may be extended to other MXenes and solidify the growing family of MXene derivatives for energy storage