A Gift is not Always a Gift: Gift Exchange in a Voucher Experiment

Different from traditional gift exchange experiments, we study a field experiment where a random subsample of participants in the Swiss Labor Force Survey was sent vouchers to be used in adult training courses. Importantly for our purposes, actual voucher redemption can be traced. This gives the unique opportunity to study whether gift exchange in the form of participation in future rounds of the survey depends on the perceived usefulness of the gift. We find that the group of voucher recipients as a whole has significantly higher response rates in the survey six months after the vouchers were sent out. There is considerable heterogeneity, though. Our results point to a long-lasting gift exchange relationship for the sub-group that had redeemed their vouchers. Contrary to this group, the individuals who did not redeem their vouchers, had a response pattern that was not significantly different from the voucher non-recipients.gift exchange, reciprocity, field experiment, long-run effects

Electronic structure of the molecule based magnet Cu PM(NO3)2 (H2O)2

We present density functional calculations on the molecule based S=1/2 antiferromagnetic chain compound Cu PM(NO3)2 (H2O)2; PM = pyrimidine. The properties of the ferro- and antiferromagnetic state are investigated at the level of the local density approximation and with the hybrid functional B3LYP. Spin density maps illustrate the exchange path via the pyrimidine molecule which mediates the magnetism in the one-dimensional chain. The computed exchange coupling is antiferromagnetic and in reasonable agreement with the experiment. It is suggested that the antiferromagnetic coupling is due to the possibility of stronger delocalization of the charges on the nitrogen atoms, compared to the ferromagnetic case. In addition, computed isotropic and anisotropic hyperfine interaction parameters are compared with recent NMR experiments

Laser Control of Dissipative Two-Exciton Dynamics in Molecular Aggregates

There are two types of two-photon transitions in molecular aggregates, that is, non-local excitations of two monomers and local double excitations to some higher excited intra-monomer electronic state. As a consequence of the inter-monomer Coulomb interaction these different excitation states are coupled to each other. Higher excited intra-monomer states are rather short-lived due to efficient internal conversion of electronic into vibrational energy. Combining both processes leads to the annihilation of an electronic excitation state, which is a major loss channel for establishing high excitation densities in molecular aggregates. Applying theoretical pulse optimization techniques to a Frenkel exciton model it is shown that the dynamics of two-exciton states in linear aggregates (dimer to tetramer) can be influenced by ultrafast shaped laser pulses. In particular, it is studied to what extent the decay of the two-exciton population by inter-band transitions can be transiently suppressed. Intra-band dynamics is described by a dissipative hierarchy equation approach, which takes into account strong exciton-vibrational coupling in the non-Markovian regime.Comment: revised version, fig. 8 ne

Coupling of frustrated Ising spins to magnetic cycloid in multiferroic TbMnO3

We report on diffraction measurements on multiferroic TbMnO3 which demonstrate that the Tb- and Mn-magnetic orders are coupled below the ferroelectric transition TFE = 28 K. For T < TFE the magnetic propagation vectors (tau) for Tb and Mn are locked so that tauTb = tauMn, while below TNTb = 7 K we find that tauTb and tauMn lock-in to rational values of 3/7 b* and 2/7 b*, respectively, and obey the relation 3tauTb - tauMn = 1. We explain this novel matching of wave vectors within the frustrated ANNNI model coupled to a periodic external field produced by the Mn-spin order. The tauTb = tauMn behavior is recovered when Tb magnetization is small, while the tauTb = 3/7 regime is stabilized at low temperatures by a peculiar arrangement of domain walls in the ordered state of Ising-like Tb spins.Comment: 5 pages, 3 figure

XMM-Newton observations of the BL Lac MS 0737+7441

We report on the XMM-Newton observations of the BL Lac object MS 0737.9+7441 during the performance verification phase. A simple power-law fit provides an adequate description of the integrated spectrum in the 0.2-10 keV energy band. The photon index is slightly steeper in the EPIC pn data with 2.38+-0.01 compared to the EPIC MOS data (2.28+-0.01). The difference is most probably due to the present uncertainties in the calibration of the EPIC MOS and EPIC pn data sets. We report evidence for intrinsic absorption in the distant BL Lac above the Galactic column N_H,Gal=3.2*10^20 cm^-2 which is N_H,fit(z=0.315)= (2.70+-0.20)*10^20cm^-2 in the EPIC pn data and N_H,fit(z=0.315)= (3.25+-0.25)*10^20cm^-2 in the EPIC MOS data assuming neutral gas and solar abundances. The flux variations are found to be of the order of 10 %.Comment: 4 pages, 4 Figures, accepted for publication in the special A&A Letters issue for XMM-Newto

Quantum spin chain as a potential realization of the Nersesyan-Tsvelik model

It is well established that long-range magnetic order is suppressed in magnetic systems whose interactions are low-dimensional. The prototypical example is the S-1/2 Heisenberg antiferromagnetic chain (S-1/2 HAFC) whose ground state is quantum critical. In real S-1/2 HAFC compounds interchain coupling induces long-range magnetic order although with a suppressed ordered moment and reduced N\'eel temperature compared to the Curie-Weiss temperature. Recently, it was suggested that order can also be suppressed if the interchain interactions are frustrated, as for the Nersesyan-Tsvelik model. Here, we study the new S-1/2 HAFC, (NO)[Cu(NO3)3]. This material shows extreme suppression of order which furthermore is incommensurate revealing the presence of frustration consistent with the Nersesyan-Tsvelik model