748 research outputs found
Fluorescence detection In aldehyde containing model systems: Relationship with fish deterioration
6 pΓ‘ginas, 4 tablas.[ES] En estudios previos se llevΓ³ a cabo la deteoeion de oempuestos
de interacciΓ³n a travΓ©s de sus propiedades fluorescentes a distintos
mΓ‘ximos de excitaciΓ³n/emisiΓ³n durante el procesamiento de pescado,
observΓ‘ndose un desplazamiento de la fluorescencia a longitudes de
onda mayores como resultado del incremento de la alteraciΓ³n. En el
presente trabajo se chequearon distintos tipos de aldehidos al objeto
de comparar su capacidad para formar compuestos fluorescentes de
distintas longitudes de onda en relaciΓ³n con el procesamiento de pescado.
Dichos aldehidos (formaldehido, FA; acetaldehido, AcH; propanal,
Pr; hexanal, Hex; 2-hexenal, Hx; benzaldehido, BzH) se hicieron
reaccionar con mΓΊsculo de sardina (Sardina pilchardus) desmenuzada
y con n-propilamina a 30Β°C en oscuridad durante 25 dΓas.
Con el aumento del tiempo de reacciΓ³n, todos los aldehidos estudiados
mostraron capacidad para producir un desplazamiento a
mayores longitudes de onda de la fluorescencia detectada. Sin
embargo se observaron distintas aptitudes, de acuerdo con la estructura
y la reactividad de cada aldehido. El desplazamiento fue
especialmente pronunciado en los casos de Hx y AcH, mientras
que fue bastante pequeΓ±o con FAy BzH. En una situaciΓ³n intermedia
se situaron Pr y Hex, en los que al igual que durante la alteraciΓ³n
de pescado, se observΓ³ un incremento en la relaciΓ³n
entre las fluorescencias detectadas a 393/463 nm y 327/415 nm
al avanzar el tiempo de reacciΓ³n.[EN] In previous studies interaction compounds formation was
accomplished by fluorescence detection at different excitation/
emission wavelength maxima during fish processing. Afluorescence
shift towards higher wavelength maxima was then obtained as a
result of damage increase. In the present work, different aldehydes
were tested in order to compare their ability in producing
fluorescent compounds with similar properties to the ones obtained
during fish processing. Aldehydes (formaldehyde, FA; acetaldehyde,
AcH; propanal, Pr; hexanal, Hex; 2-hexenal Hx; benzaldehyde,
BzH) were reacted in model systems with sardine (Sardina
pilchardus) muscle and with n-propylamine at 30Β°C in dark during
25 days.
Afluorescence shift was detected for all the aldehydes investigated
as long as the reaction time increased. Great differences were
observed between aldehydes, according to their chemical structure
and reactivity. A sharp shift was detected for Hx and AcH, while
little changes were observed in the cases of FA and BzH. As in the
case of fish processing, Pr and Hex showed an increasing ratio
between fluorescences detected at 393/463 nm and 327/415 nm
as long as the reaction time increased.Agradecemos a la Xunta de Galicia la ayuda financiera otorgada
(Proyecto FAIR (CEE) CT 95-111).Peer reviewe
ΠΡΠΎΠ΅ΠΊΡ Π³Π΅Π»ΠΈΠ΅Π²ΠΎΠΉ ΡΡΡΠ±ΠΈΠ½Ρ Π² ΡΠΎΡΡΠ°Π²Π΅ ΡΠ½Π΅ΡΠ³ΠΎΠ±Π»ΠΎΠΊΠ° ΠΠΠ‘ Ρ Π²ΡΡΠΎΠΊΠΎΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ½ΡΠΌ Π³Π°Π·ΠΎΠΎΡ Π»Π°ΠΆΠ΄Π°Π΅ΠΌΡΠΌ ΡΠ΅Π°ΠΊΡΠΎΡΠΎΠΌ
Π¦Π΅Π»ΡΡ ΡΠ°Π±ΠΎΡΡ ΡΠ²Π»ΡΠ΅ΡΡΡ ΡΠ°Π·ΡΠ°Π±ΠΎΡΠΊΠ° ΠΏΡΠΎΠ΅ΠΊΡΠ° Π³Π°Π·ΠΎΠ²ΠΎΠΉ ΡΡΡΠ±ΠΈΠ½Ρ Π΄Π»Ρ ΡΠ½Π΅ΡΠ³ΠΎΠ±Π»ΠΎΠΊΠ° Ρ Π²ΡΡΠΎΠΊΠΎΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ½ΡΠΌ Π³Π°Π·ΠΎΠΎΡ
Π»Π°ΠΆΠ΄Π°Π΅ΠΌΡΠΌ ΡΠ΅Π°ΠΊΡΠΎΡΠΎΠΌ. ΠΡΡ
ΠΎΠ΄Π½ΡΠΌΠΈ Π΄Π°Π½Π½ΡΠΌΠΈ Π΄Π»Ρ Π²ΡΠΏΠΎΠ»Π½Π΅Π½ΠΈΡ ΡΠ°Π±ΠΎΡΡ ΡΠ²Π»ΡΡΡΡΡ: Π²ΡΡΠΎΠΊΠΎΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ½ΡΠΉ Π³Π΅Π»ΠΈΠ΅Π²ΡΠΉ ΡΠ΅Π°ΠΊΡΠΎΡ Ρ ΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠΎΠΉ Π³Π°Π·Π° Π½Π° Π²ΡΡ
ΠΎΠ΄Π΅ ΠΈΠ· ΡΠ΅Π°ΠΊΡΠΎΡΠ° 1000 Β°Π‘, ΠΊΠΎΠ½ΡΡΡΡΠΊΡΠΈΠ²Π½ΡΠ΅ ΠΈ ΡΠ½Π΅ΡΠ³Π΅ΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΠΊΠΈ ΠΊΠΎΠΌΠΏΡΠ΅ΡΡΠΎΡΠ°, ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»Ρ ΠΏΡΠ΅Π΄Π΄ΠΈΠΏΠ»ΠΎΠΌΠ½ΠΎΠΉ ΠΏΡΠ°ΠΊΡΠΈΠΊΠΈ ΠΈ Π΄Π°Π½Π½ΡΠ΅ Π½Π°ΡΡΠ½ΠΎ-ΡΠ΅Ρ
Π½ΠΈΡΠ΅ΡΠΊΠΎΠΉ ΠΈ ΡΡΠ΅Π±Π½ΠΎΠΉ Π»ΠΈΡΠ΅ΡΠ°ΡΡΡΡ, ΠΏΠ΅ΡΠΈΠΎΠ΄ΠΈΡΠ΅ΡΠΊΠΈΡ
ΠΈΠ·Π΄Π°Π½ΠΈΠΉ.
Π’Π΅Ρ Π½ΠΈΡΠ΅ΡΠΊΠΈΠ΅ Ρ Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΠΊΠΈ ΠΏΠ½Π΅Π²ΠΌΠ°ΡΠΈΡΠ΅ΡΠΊΠΈΡ Π±ΡΡΠΈΠ»ΡΠ½ΡΡ ΠΌΠΎΠ»ΠΎΡΠΊΠΎΠ²
Π‘ΠΈΡΡΠ΅ΠΌΠ½ΠΈΠΉ ΠΏΡΠ΄Ρ ΡΠ΄ Π΄ΠΎ ΡΠΎΡΠΌΡΠ²Π°Π½Π½Ρ ΠΌΠ΅ΡΠΎΠ΄ΠΎΠ»ΠΎΠ³ΡΡ Π²ΠΈΠΊΠ»Π°Π΄Π°Π½Π½Ρ Π΅ΠΊΠΎΠ½ΠΎΠΌΡΡΠ½ΠΈΡ Π΄ΠΈΡΡΠΈΠΏΠ»ΡΠ½ Π² ΡΠΌΠΎΠ²Π°Ρ Π³Π»ΠΎΠ±Π°Π»ΡΠ·Π°ΡΡΡ ΡΠ° ΡΠ²ΡΠΎΠΏΠ΅ΠΉΡΡΠΊΠΎΡ ΡΠ½ΡΠ΅Π³ΡΠ°ΡΡΡ Π£ΠΊΡΠ°ΡΠ½ΠΈ
Improvement of Serviceability and Strength of Textile Reinforced Concrete by using Short Fibres
Nowadays, thin-walled load bearing structures can be realised using textile reinforced concrete (BRAMESHUBER and RILEM TC 201-TRC [1]). The required tensile strength is achieved by embedding several layers of textile. By means of the laminating technique the number of textile layers that can be included into the concrete could be increased. To further increase the first crack stress and the ductility as well as to optimize the crack development, fine grained concrete mixes with short fibres can be used. By a schematic stress-strain curve the demands on short fibres are defined. Within the scope of this study, short fibres made of glass, carbon, aramid and polyvinyl alcohol are investigated in terms of their ability to fit these requirements. On the basis of these results, the development of hybrid fibre mixes to achieve the best mechanical properties is described. Additionally, a conventional FRC with one fibre type is introduced. Finally, the fresh and hardened concrete properties as well as the influence of short fibres on the load bearing behaviour of textile reinforced concrete are discussed
Π Π²Π΅Π½ΡΠΈΠ»ΡΠ½ΠΎ-ΠΌΠ΅Ρ Π°Π½ΠΈΡΠ΅ΡΠΊΠΎΠΉ ΠΊΠΎΠΌΠΌΡΡΠ°ΡΠΈΠΈ ΠΌΠ°ΡΠΈΠ½ ΠΏΠΎΡΡΠΎΡΠ½Π½ΠΎΠ³ΠΎ ΡΠΎΠΊΠ°
Π‘ΡΠ°Π²Π½ΠΈΡΠ΅Π»ΡΠ½Π°Ρ Ρ Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΠΊΠ° ΡΠΎΡΡΠΎΠ² Π’ΠΎΠΌΡΠΊΠΎΠΉ ΠΎΠ±Π»Π°ΡΡΠΈ ΠΈ ΡΠ΅ΡΠΏΡΠ±Π»ΠΈΠΊΠΈ ΠΠ»ΡΠ°ΠΉ
Π Π΄Π°Π½Π½ΠΎΠΉ ΡΠ°Π±ΠΎΡΠ΅ Π±ΡΠ»Π° ΠΏΡΠΎΠ²Π΅Π΄Π΅Π½Π° ΡΡΠ°Π²Π½ΠΈΡΠ΅Π»ΡΠ½Π°Ρ Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΠΊΠ° ΡΠΎΡΡΠΎΠ² Π’ΠΎΠΌΡΠΊΠΎΠΉ ΠΎΠ±Π»Π°ΡΡΠΈ ΠΈ ΡΠ΅ΡΠΏΡΠ±Π»ΠΈΠΊΠΈ ΠΠ»ΡΠ°ΠΉ. ΠΠ»Ρ ΡΡΠΈΡ
ΡΠΎΡΡΠΎΠ² Π±ΡΠ»ΠΈ ΠΎΠΏΡΠ΅Π΄Π΅Π»Π΅Π½Ρ ΡΠ΅Ρ
Π½ΠΈΡΠ΅ΡΠΊΠΈΠΉ ΠΈ Π³ΡΡΠΏΠΏΠΎΠ²ΠΎΠΉ ΡΠΎΡΡΠ°Π²Ρ.
Π ΡΠ΅Π·ΡΠ»ΡΡΠ°ΡΠ΅ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΠΉ Π²ΡΡΠ²Π»Π΅Π½ΠΎ, ΡΡΠΎ ΡΠΎΡΡΠ° Ρ ΠΌΠ΅ΡΡΠΎΡΠΎΠΆΠ΄Π΅Π½ΠΈΠΉ Π’ΠΎΠΌΡΠΊΠΎΠΉ ΠΎΠ±Π»Π°ΡΡΠΈ ΠΈ ΡΠ΅ΡΠΏΡΠ±Π»ΠΈΠΊΠΈ ΠΠ»ΡΠ°ΠΉ ΠΎΡΠ»ΠΈΡΠ°ΡΡΡΡ ΠΏΠΎ ΡΡΠ΅ΠΏΠ΅Π½ΠΈ ΡΠ°Π·Π»ΠΎΠΆΠ΅Π½ΠΈΡ ΠΈ Π·ΠΎΠ»ΡΠ½ΠΎΡΡΠΈ. Π ΡΠΎΡΡΠ°Ρ
ΡΠ΅ΡΠΏΡΠ±Π»ΠΈΠΊΠΈ ΠΠ»ΡΠ°ΠΉ ΠΏΠΎΠ»ΡΡΠΈΠ»ΠΈ Π±ΠΎΠ»ΡΡΠ΅Π΅ ΡΠΎΠ΄Π΅ΡΠΆΠ°Π½ΠΈΠ΅ Π³ΡΠΌΠΈΠ½ΠΎΠ²ΡΡ
ΠΊΠΈΡΠ»ΠΎΡ ΠΈ Π»ΠΈΠ³Π½ΠΈΠ½Π° ΠΏΠΎ ΡΡΠ°Π²Π½Π΅Π½ΠΈΡ Ρ ΡΠΎΡΡΠ°ΠΌΠΈ Π’ΠΎΠΌΡΠΊΠΎΠΉ ΠΎΠ±Π»Π°ΡΡΠΈ .
ΠΡΠΎΠΌΠ΅ ΡΡΠΎΠ³ΠΎ, Π² ΡΠΎΡΡΠ°Ρ
ΡΠ΅ΡΠΏΡΠ±Π»ΠΈΠΊΠΈ ΠΠ»ΡΠ°ΠΉ Π²ΡΡΠ²Π»Π΅Π½ΠΎ Π½ΠΈΠ·ΠΊΠΎΠ΅ ΡΠΎΠ΄Π΅ΡΠΆΠ°Π½ΠΈΠ΅ Π±ΠΈΡΡΠΌΠΎΠ² ΠΈ ΡΠ³Π»Π΅Π²ΠΎΠ΄Π½ΠΎΠ³ΠΎ ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡΠ° ΠΈ ΠΏΠΎΠ²ΡΡΠ΅Π½Π½ΠΎΠ΅ ΡΠΎΠ΄Π΅ΡΠΆΠ°Π½ΠΈΠ΅ Π³ΡΠΌΠΈΠ½ΠΎΠ²ΡΡ
ΠΊΠΈΡΠ»ΠΎΡ ΠΈ Π»ΠΈΠ³Π½ΠΈΠ½Π°. Π£ΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΎ, ΡΡΠΎ Π½Π° Π±Π°Π·Π΅ ΠΌΠ΅ΡΡΠΎΡΠΎΠΆΠ΄Π΅Π½ΠΈΠΉ ΡΠ΅ΡΠΏΡΠ±Π»ΠΈΠΊΠΈ ΠΠ»ΡΠ°ΠΉ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½Π° ΠΎΡΠ³Π°Π½ΠΈΠ·Π°ΡΠΈΡ ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄ΡΡΠ²Π° Π³ΡΠΌΠΈΠ½ΠΎΠ²ΡΡ
ΠΊΠΈΡΠ»ΠΎΡ ΠΈ Π±ΠΈΡΡΠΌΠΎΠ² Π² ΠΎΠ³ΡΠ°Π½ΠΈΡΠ΅Π½Π½ΡΡ
ΡΠ°Π·ΠΌΠ΅ΡΠ°Ρ
.In this work the comparative characteristic of peats of the Tomsk region and Altai Republic has been carried out. For these peats, the technical and group compositions were determined.
As a result of the researches it is revealed that peats from deposits of the Tomsk region and Altai Republic differ on extent of decomposition and an ash-content. In peats of Altai Republic have received the bigger content of humic acids and a lignin in comparison with peats of the Tomsk region.
Besides, in peats of Altai Republic the low content of bitumens and a carbohydrate complex and the increased content of humic acids and a lignin is revealed. It is established that on the basis of fields of Altai Republic the organization of production of humic acids and bitumens in limited sizes is possible
ΠΠ΅ΡΠΎΠ΄Ρ ΠΎΠΏΡΠ΅Π΄Π΅Π»Π΅Π½ΠΈΡ ΡΠΎΡΡΠ°Π²Π° ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡΠΎΠ², Π½Π΅ΠΏΠΎΡΡΠ΅Π΄ΡΡΠ²Π΅Π½Π½ΠΎ ΡΡΠ°ΡΡΠ²ΡΡΡΠΈΡ Π² ΡΠ»Π΅ΠΊΡΡΠΎΠ΄Π½ΠΎΠΌ ΠΏΡΠΎΡΠ΅ΡΡΠ΅
ΠΠΎΠ·Π½Π°Π½ΠΈΠ΅ ΠΈ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΠ΅ ΠΊΠ°ΠΊ ΠΎΡΠ½ΠΎΠ²Π½ΡΠ΅ ΡΠ»Π΅ΠΌΠ΅Π½ΡΡ ΠΏΡΠΈ ΠΈΠ·ΡΡΠ΅Π½ΠΈΠΈ Π±ΡΠ΄ΡΡΠ΅Π³ΠΎ
The article gives the overview of cognitive practices in philosophy. The authoremphasizes that there is a correlation between cognition and education.Integration of this two sides of a social life gives a possibility forfurther development of society
The Concept of "Natureβs Human" in the boundaries ecology-futurologyβs investigation and obstacle they can to appear attached to his consideration
Π‘ΡΠ°ΡΡΡ ΠΏΡΠΈΡΠ²ΡΡΠ΅Π½Π° ΡΠΎΠ·ΡΠΎΠ±ΡΡ ΠΏΠΈΡΠ°Π½Π½Ρ "ΠΡΠ΄ΠΈΠ½Π° ΠΏΡΠΈΡΠΎΠ΄Π½Ρ" Ρ ΡΠ°ΠΌΠΊΠ°Ρ
Π΄ΠΎΡΠ»ΡΠ΄ΠΆΠ΅Π½Π½Ρ Π΅ΠΊΠΎΠ»ΠΎΠ³ΡΡΠ½ΠΎΡ ΡΡΡΡΡΠΎΠ»ΠΎΠ³ΡΡ ΡΠ° ΠΎΠΏΠΈΡΡ ΠΏΡΠΎΠ±Π»Π΅ΠΌ ΡΡ ΡΠΎΠ·ΡΠΌΡΠ½Π½Ρ.This article is dedicate working out of question about "Natureβs Human" in the boundaries ecology futurologyβs and describe problemβs attached to his understanding
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