Experimental Studies of NaCs

We present experimental studies of excited electronic states of the NaCs molecule that are currently underway in our laboratory. The optical-optical double resonance method is used to obtain Doppler-free excitation spectra for several excited states. These data are being used to obtain RydbergKlein-Rees (RKR) or Inverse Perturbation Approach (IPA) potential curves for these states. We are also trying to map the bound portion of the 1(a) 3Σ + potential using resolved laser-induced fluorescence and Fourier transform spectroscopy to record transitions into the shallow well. Bound-free spectra from single ro-vibrational levels of electronically excited states to the repulsive wall of the 1(a) 3Σ + state are also being recorded. Using the previously determined excited state potentials, we can fit the repulsive wall of the 1(a) 3Σ + state to reproduce the experimental spectra using LeRoy’s BCONT program. A slightly modified version of BCONT will also be used to fit the relative transition dipole moments, µe(R), as a function of internuclear separation R, for the various bound-free electronic transitions

Development of Enantioselective Palladium‐Catalyzed Alkene Carboalkoxylation Reactions for the Synthesis of Tetrahydrofurans

The Pd‐catalyzed coupling of γ‐hydroxyalkenes with aryl bromides affords enantiomerically enriched 2‐(arylmethyl)tetrahydrofuran derivatives in good yield and up to 96:4 e.r. This transformation was achieved through the development of a new TADDOL/2‐arylcyclohexanol‐derived chiral phosphite ligand. The transformations are effective with an array of different aryl bromides, and can be used for the preparation of products bearing quaternary stereocenters.The construction of enantiomerically enriched tetrahydrofurans is accomplished by asymmetric Pd‐catalyzed cross‐coupling reactions between γ‐hydroxyalkenes and aryl bromides. Use of a palladium catalyst supported by a new TADDOL‐derived chiral phosphite ligand provides the tetrahydrofuran products in good yield with up to 96:4 e.r. (see scheme).Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/115961/1/anie_201506884_sm_miscellaneous_information.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/115961/2/13390_ftp.pd

Methodology development for evaluation of selective-fidelity rotorcraft simulation

This paper addressed the initial step toward the goal of establishing performance and handling qualities acceptance criteria for realtime rotorcraft simulators through a planned research effort to quantify the system capabilities of 'selective fidelity' simulators. Within this framework the simulator is then classified based on the required task. The simulator is evaluated by separating the various subsystems (visual, motion, etc.) and applying corresponding fidelity constants based on the specific task. This methodology not only provides an assessment technique, but also provides a technique to determine the required levels of subsystem fidelity for a specific task

Inheritance of the Sex-Determining Factor in the Absence of a Complete Y Chromosome in 46,XX Human Males

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/71879/1/j.1749-6632.1987.tb25088.x.pd

Palladium‐Catalyzed Alkene Carboamination Reactions of Electron‐Poor Nitrogen Nucleophiles

Modified reaction conditions that facilitate Pd‐catalyzed alkene carboamination reactions of electron‐deficient nitrogen nucleophiles are reported. Pent‐4‐enylamine derivatives bearing N‐tosyl or N‐trifluoroacetyl groups are coupled with aryl triflates to afford substituted pyrrolidines in good yield. These reactions proceed via a mechanism involving anti‐aminopalladation of the alkene, which differs from previously reported analogous reactions of N‐aryl‐ and N‐Boc‐pentenylamines. The application of these conditions to a formal synthesis of (±)‐aphanorphine is also described.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/112250/1/2339_ftp.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/112250/2/adsc_201500334_sm_miscellaneous_information.pd

Heat pumping in nanomechanical systems

We propose using a phonon pumping mechanism to transfer heat from a cold to a hot body using a propagating modulation of the medium connecting the two bodies. This phonon pump can cool nanomechanical systems without the need for active feedback. We compute the lowest temperature that this refrigerator can achieve.Comment: 4 pages, 1 figure, published versio

Search for cold gas in z>2 damped Lyman-alpha systems: 21-cm and H_2 absorption

(Abridged) We present the results of a systematic GBT and GMRT survey for 21-cm absorption in a sample of 10 DLAs at 2<z_abs<3.4. Analysis of L-band VLBA images of the background QSOs are also presented. We detect 21-cm absorption in only one DLA (at z_abs = 3.1745 towards J1337+3152). Combining our data with the data from the literature (a sample of 28 DLAs) and assuming the measured core fraction at milliarcsecond scale to represent the gas covering factor, we find that the HI gas in DLAs at z> 2 is predominantly constituted by WNM. The detection rate of 21-cm absorption seems to be higher for systems with higher N(HI) or metallicity. However, no clear correlation is found between the integrated 21-cm optical depth (or spin temperature) and either N(HI), metallicity or velocity spread of the low ionization species. There are 13 DLAs in our sample for which high resolution optical spectra covering the expected wavelength range of H_2 absorption are available. We report the detection of H_2 molecules in the z_abs = 3.3871 21-cm absorber towards J0203+1134 (PKS 0201+113). In 8 cases, neither H_2 nor 21-cm absorption are detected. The lack of 21-cm and H_2 absorption in these systems can be explained if most of the HI in these DLAs originate from low density high temperature gas. In one case we have a DLA with 21-cm absorption not showing H_2 absorption. In two cases, both species are detected but do not originate from the same velocity component. In the remaining 2 cases 21-cm absorption is not detected despite the presence of H_2 with evidence for the presence of cold gas. All this is consistent with the idea that the H_2 components seen in DLAs are compact (with sizes of < 15 pc) and contain only a small fraction (i.e typically <10%) of the total N(HI) measured in the DLAs.Comment: Accepted for publication in MNRA