Chemical kinetic modeling of benzene and toluene oxidation behind shock waves

The oxidation of stoichiometric mixtures of benzene and toluene behind incident shock waves was studied for a temperature range from 1700 to 2800 K and a pressure range from 1.1 to 1.7 atm. The concentration of CO and CO2 produced were measured as well as the product of the oxygen atom and carbon monoxide concentrations. Comparisons between the benzene experimental data and results calculated by use of a reaction mechanism published in the open literature were carried out. With some additional reactions and changes in rate constants to reflect the pressure-temperature range of the experimental data, a good agreement was achieved between computed and experimental results. A reaction mechanism was developed for toluene oxidation based on analogous rate steps from the benzene mechanism. Measurements of NOx levels in an actual flame device, a jet-stirred combustor, were reproduced successfully by use of the reaction mechanism developed from the shock-tube experiments on toluene. These experimental measurements of NOx levels were reproduced from a computer simulation of a jet-stirred combustor

Interpolation Parameter and Expansion for the Three Dimensional Non-Trivial Scalar Infrared Fixed Point

We compute the non--trivial infrared $\phi^4_3$--fixed point by means of an interpolation expansion in fixed dimension. The expansion is formulated for an infinitesimal momentum space renormalization group. We choose a coordinate representation for the fixed point interaction in derivative expansion, and compute its coordinates to high orders by means of computer algebra. We compute the series for the critical exponent $\nu$ up to order twenty five of interpolation expansion in this representation, and evaluate it using \pade, Borel--\pade, Borel--conformal--\pade, and Dlog--\pade resummation. The resummation returns $0.6262(13)$ as the value of $\nu$.Comment: 29 pages, Latex2e, 2 Postscript figure

Knowledge and the artefact

This paper discusses ways that knowledge may be found in or through artefacts. One purpose is to suggest situations where artefacts might be central to a narrative, rather than secondary to a text. A second purpose is to suggest ways that design and production of artefacts might be instrumental in eliciting knowledge. Four general situations are proposed: (1) Simple Forms - an artefact demonstrates or describes a principle or technique. (2) Communication of Process - artefacts arising from a process make the process explicit. (3) Artefacts Within the Research - artefacts are instrumental in advancing the research by communicating ideas or information. (4) Knowledge Elicited by Artefacts - artefacts provide a stimulus or context which enables information to be uncovered. .</p

Oscillatory subglacial drainage in the absence of surface melt

The presence of strong diurnal cycling in basal water pressure records obtained during the melt season is well established for many glaciers. The behaviour of the drainage system outside the melt season is less well understood. Here we present borehole observations from a surge-type valley glacier in the St Elias Mountains, Yukon Territory, Canada. Our data indicate the onset of strongly correlated multi-day oscillations in water pressure in multiple boreholes straddling a main drainage axis, starting several weeks after the disappearance of a dominant diurnal mode in August 2011 and persisting until at least January 2012, when multiple data loggers suffered power failure. Jökulhlaups provide a template for understanding spontaneous water pressure oscillations not driven by external supply variability. Using a subglacial drainage model, we show that water pressure oscillations can also be driven on a much smaller scale by the interaction between conduit growth and distributed water storage in smaller water pockets, basal crevasses and moulins, and that oscillations can be triggered when water supply drops below a critical value. We suggest this in combination with a steady background supply of water from ground water or englacial drainage as a possible explanation for the observed wintertime pressure oscillations

Helicopter Anti-Torque System Using Strakes

A helicopter is disclosed with a system for controlling main-rotor torque which reduces the power and size requirements of conventional anti-torque means. The torque countering forces are generated by disrupting the main rotor downwash flowing around the fuselage. The downwash flow is separated from the fuselage surface by a strake positioned at a specified location on the fuselage. This location is determined by the particular helicopter wash pattern and fuselage configuration, generally being located between 20 deg before top dead center (TDC) and 80 deg from TDC on the fuselage side to which the main rotor blade approaches during rotation. The strake extends along the fuselage from the cabin section to the aft end and can be continuous or separated for aerodynamic surfaces such as a horizontal stabilizer

Patterns of gene expression in schistosomes: localization by whole mount in situ hybridization

rom the identification of genes to the characterization of their functions and interactions. Developmental biologists have long used whole mount in situ hybridization (WISH) to determine gene expression patterns, as a vital tool for formulating and testing hypotheses about function. This paper describes the application of WISH to the study of gene expression in larval and adult schistosomes. Fixed worms were permeablized by proteinase K treatment for hybridization with digoxygenin-labelled RNA probes, with binding being detected by alkaline phosphatase-coupled anti-digoxygenin antibodies, and BM Purple substrate. Discrete staining patterns for the transcripts of the molecules Sm29, cathepsin L, antigen 10.3 and chorion were observed in the tegument cell bodies, gut epithelium, oesophageal gland and vitelline lobules, respectively, of adult worms. Transcripts of the molecules SGTP4, GP18-22 and cathepsin L were localized to tegument cell bodies and embryonic gut, respectively, of lung schistosomula. We also showed that Fast Red TR fluorescent substrate can refine the pattern of localization permitting use of confocal microscopy. We believe that method of WISH will find broad application, in synergy with other emerging post-genomic techniques, such as RNA interference, to studies focused at increasing our molecular understanding of schistosomes

Extended Gas in Seyfert Galaxies: Near Infrared Observations of NGC 2110 and Circinus

We present results of near--IR long-slit spectroscopy in the J and K bands of the Seyfert 2 galaxies NGC 2110 and Circinus, investigating the gaseous distribution, excitation, reddening and kinematics. In NGC 2110, the emission line ratio [FeII]/Pa beta increases towards the nucleus (to ~ 7). The nuclear [Fe II]1.257 (microns) and Pa beta lines are broader (FWHM ~ 500 km/s) than the H2 (2.121) line (FWHM ~ 300 km/s). Both these results suggest that shocks, driven by the radio jet, are an important source of excitation of [Fe II]. The H2 excitation appears to be dominated by X-rays from the nucleus. In Circinus, both [FeII]/Pa beta and H2/Br gamma decrease from ~ 2 at 4 arcsec from the nucleus to nuclear values of ~ 0.6 and ~ 1, respectively, suggesting that the starburst dominates the nuclear excitation, while the AGN dominates the excitation further out (r > 2 arcsec). For both galaxies, the gaseous kinematics are consistent with circular rotation in the plane of the disk. Our rotation curves suggest that the nucleus (identified with the peak of the IR continuum) is displaced from the kinematic centre of the galaxies. This effect has been observed previously in NGC 2110 based on the kinematics of optical emission lines, but the displacement is smaller in the infrared, suggesting the effect is related to obscuration. The continuum J-K colours of the nuclear region indicate a red stellar population in NGC 2110 and a reddened young stellar population in Circinus. Right at the nucleus of both galaxies, the colours are redder, apparently a result of hot dust emission from the inner edge of a circumnuclear torus.Comment: 11 pages, 14 figures, accepted for publication in MNRA

The Nuclear Outflow in NGC 2110

We present a HST/STIS spectroscopic and optical/radio imaging study of the Seyfert NGC 2110 aiming to measure the dynamics and understand the nature of the nuclear outflow in the galaxy. Previous HST studies have revealed the presence of a linear structure in the Narrow-Line Region (NLR) aligned with the radio jet. We show that this structure is strongly accelerated, probably by the jet, but is unlikely to be entrained in the jet flow. The ionisation properties of this structure are consistent with photoionisation of dusty, dense gas by the active nucleus. We present a plausible geometrical model for the NLR, bringing together various components of the nuclear environment of the galaxy. We highlight the importance of the circum-nuclear disc in determining the appearance of the emission line gas and the morphology of the jet. From the dynamics of the emission line gas, we place constraints on the accelerating mechanism of the outflow and discuss the relative importance of radio source synchrotron pressure, radio jet ram pressure and nuclear radiation pressure in accelerating the gas. While all three mechanisms can account for the energetics of the emission line gas, gravitational arguments support radio jet ram pressure as the most likely source of the outflow.Comment: 15 pages, 7 figures; accepted to MNRA