Tuning of the luminescence in poly((silanylene)thiophene)s

Synthetic routes to alternating copolymers consisting of oligosilylene blocks and oligothiophene blocks (T-x; x = 1, 2, 3, 4, or 6 rings) are presented. Solubility requirements for obtaining acceptable molecular weights and, eventually, for film formation are met by the introduction of butyl groups replacing methyls on the silicon atoms and by employing T-6 blocks carrying two octyl substituents. Additionally, substituted oligothiophenes are synthesized as an aid in the interpretation of NMR, absorption, and fluorescence spectra. Regarding the electronic configuration of the oligothiophene blocks, NMR spectra show clear differences between plain oligothiophenes, end-substituted oligothiophenes, and polymers, indicative of pi-sigma interactions with the oligosilylene blocks and possible through-conjugation to adjacent blocks in polymers. Red shifts in optical spectra show a parallel trend across the various compounds based on the same oligothiophene unit, related to the stabilization of photoexcited states on the oligothiophene by the oligosilylene substituents. These effects are strong in T-2-based compounds and reduced fdr longer T-n. The main feature of the spectra is the decrease of the transition energies with the size of the oligothiophene blocks in the polymers. Since this effect is also found in fluorescence, it enables one to adjust the luminescence wavelength by choosing the proper block length (''chemical tuning''). Fluorescence quantum efficiencies in solution are found to be remarkably high in polymers based on T-2 blocks. Spin-coated films of T-2-based (or T-3-based) polymers show evidence of T-4 (T-6) impurity blocks that act as an exciton trap

The ATESP 5 GHz radio survey. II. Physical properties of the faint radio population

One of the most debated issues about sub-mJy radio sources, which are responsible for the steepening of the 1.4 GHz source counts, is the origin of their radio emission. Particularly interesting is the possibility of combining radio spectral index information with other observational properties to assess whether the sources are triggered by star formation or nuclear activity. The aim of this work is to study the optical and near infrared properties of a complete sample of 131 radio sources with S>0.4 mJy, observed at both 1.4 and 5 GHz as part of the ATESP radio survey. We use deep multi-colour (UBVRIJK) images, mostly taken in the framework of the ESO Deep Public Survey, to optically identify and derive photometric redshifts for the ATESP radio sources. Deep optical coverage and extensive colour information are available for 3/4 of the region covered by the radio sample. Typical depths of the images are U~25, B~26, V~25.4, R~25.5, I~24.3, 19.5<K_s<20.2, J<22.2. Optical/near infrared counterparts are found for ~78% (66/85) of the radio sources in the region covered by the deep multi-colour imaging, and for 56 of these reliable estimates of the redshift and type are derived. We find that many of the sources with flat radio spectra are characterised by high radio-to-optical ratios (R>1000), typical of classical powerful radio galaxies and quasars. Flat-spectrum sources with low R values are preferentially identified with early type galaxies, where the radio emission is most probably triggered by low-luminosity active galactic nuclei. Considering both early type galaxies and quasars as sources with an active nucleus, such sources largely dominate our sample (78%). Flat-spectrum sources associated with early type galaxies are quite compact (d<10-30 kpc), suggesting core-dominated radio emission.Comment: 15 pages, 13 figures, accepted for pubblication in A&

The ATESP Radio Survey II. The Source Catalogue

This paper is part of a series reporting the results of the Australia Telescope ESO Slice Project (ATESP) radio survey obtained at 1400 MHz with the Australia Telescope Compact Array (ATCA) over the region covered by the ESO Slice Project (ESP) galaxy redshift survey. The survey consists of 16 radio mosaics with ~8"x14" resolution and uniform sensitivity (1sigma noise level ~79 microJy) over the whole area of the ESP redshift survey (~26 sq. degrees at decl. -40 degr). Here we present the catalogue derived from the ATESP survey. We detected 2960 distinct radio sources down to a flux density limit of ~0.5 mJy (6sigma), 1402 being sub-mJy sources. We describe in detail the procedure followed for the source extraction and parameterization. The internal accuracy of the source parameters was tested with Monte Carlo simulations and possible systematic effects (e.g. bandwidth smearing) have been quantified.Comment: 14 pages, 14 Postscript figures, Accepted for publication in A&A Suppl. Corrected typos and added Journal Referenc

Surface Grafting of Poly(L-glutamates). 3. Block Copolymerization

This paper describes for the first time the synthesis of surface-grafted AB-block copolypeptides, consisting of poly(γ-benzyl L-glutamate) (PBLG) as the A-block and poly(γ-methyl L-glutamate) (PMLG) as the B-block. Immobilized primary amine groups of (γ-aminopropyl)triethoxysilane (APS) on silicon wafers initiated the ring-opening polymerization of N-carboxyanhydrides of glutamic acid esters (NCAs). After removal of the BLG-NCA monomer solution after a certain reaction time, the amine end groups of the formed PBLG blocks acted as initiators for the second monomers. This method provides the possibility of making layered structures of surface-grafted block copolymers with tuned properties. Ellipsometry and small-angle X-ray reflection (SAXR) measurements revealed the thickness of the polypeptide layers ranging from 45-100 Å of the first block to 140-270 Å for the total block copolypeptides. The chemical composition of the blocks was determined by X-ray photoelectron spectroscopy (XPS). In addition, Fourier transform infrared transmission spectroscopy (FT-IR) revealed that the polypeptide main chains of both blocks consisted of pure R-helices. The average orientation of the helices ranging from 22-42° with respect to the substrate within the first block to 31-35° in the second block could be derived with FT-IR as well.

A year in the life of GW170817: the rise and fall of a structured jet from a binary neutron star merger

We present the results of our year-long afterglow monitoring of GW170817, the first binary neutron star (NS) merger detected by advanced LIGO and advanced Virgo. New observations with the Australian Telescope Compact Array (ATCA) and the Chandra X-ray Telescope were used to constrain its late-time behavior. The broadband emission, from radio to X-rays, is well-described by a simple power-law spectrum with index ~0.585 at all epochs. After an initial shallow rise ~t^0.9, the afterglow displayed a smooth turn-over, reaching a peak X-ray luminosity of ~5e39 erg/s at 160 d, and has now entered a phase of rapid decline ~t^(-2). The latest temporal trend challenges most models of choked jet/cocoon systems, and is instead consistent with the emergence of a relativistic structured jet seen at an angle of ~22 deg from its axis. Within such model, the properties of the explosion (such as its blastwave energy E_K~2E50 erg, jet width theta_c~4 deg, and ambient density n~3E-3 cm^(-3)) fit well within the range of properties of cosmological short GRBs.Comment: 11 pages, 8 figures, 2 tables, MNRAS, in press. Final version, minor changes only relative to original submission dated 21 August 201

PoN-S : a systematic approach for applying the Physics of Notation (PoN)

Visual Modeling Languages (VMLs) are important instruments of communication between modelers and stakeholders. Thus, it is important to provide guidelines for designing VMLs. The most widespread approach for analyzing and designing concrete syntaxes for VMLs is the so-called Physics of Notation (PoN). PoN has been successfully applied in the analysis of several VMLs. However, despite its popularity, the application of PoN principles for designing VMLs has been limited. This paper presents a systematic approach for applying PoN in the design of the concrete syntax of VMLs. We propose here a design process establishing activities to be performed, their connection to PoN principles, as well as criteria for grouping PoN principles that guide this process. Moreover, we present a case study in which a visual notation for representing Ontology Pattern Languages is designed

Mogelijkheden voor ondersteunende en kleinschalige horeca op agrarische bedrijven binnen bestaande regelgeving

Het platteland trekt steeds meer recreanten en agrarische ondernemers en hun gezinsleden spelen hierop in met onder andere campings, rondleidingen op het bedrijf, verkoop van streekproducten en kleinschalige horeca. Gemeenten kiezen ervoor om ondersteunde horeca te stimuleren omdat deze bijdraagt aan de kwaliteit van het gebied. Diverse gemeenten hebben beleid opgesteld voor ondersteunende en kleinschalige horeca met afgeleide regelgeving, bijvoorbeeld ten behoeve van detailhandel. Dit biedt veel overeenkomsten en aanknopingspunten voor horeca op agrarische bedrijven

Electromechanical properties of an ultrathin layer of directionally aligned helical polypeptides

The electromechanical properties of a monomolecular film of poly-gamma-benzyl-L-glutamate (PBLG) 15 nanometers thick grafted at the carboxyl-terminal end to a flat aluminum surface were measured. The field-induced change in film thickness, dominated by a large inverse-piezoelectric effect, demonstrates that the "grafting-from" technique forces the chains into a parallel arrangement. The mechanical plate modulus of the film as determined by electrostriction agrees with the theoretical prediction for a single PBLG molecule along the chain axis. The experiments show that ultrathin polypeptide layers with large persistent polarization can be fabricated by the grafting approach

A Coordinated Radio Afterglow Program

We describe a ground-based effort to find and study afterglows at centimeter and millimeter wavelengths. We have observed all well-localized gamma-ray bursts in the Northern and Southern sky since BeppoSAX first started providing rapid positions in early 1997. Of the 23 GRBs for which X-ray afterglows have been detected, 10 have optical afterglows and 9 have radio afterglows. A growing number of GRBs have both X-ray and radio afterglows but lack a corresponding optical afterglow.Comment: To appear in Proc. of the 5th Huntsville Gamma-Ray Burst Symposium, 5 pages, LaTe