396 research outputs found
The Genesis Solar Wind Concentrator Target: Mass Fractionation Characterised by Neon Isotopes
The concentrator on Genesis provided samples of increased fluences of solar wind ions for precise determination of the oxygen isotopic composition. The concentration process caused mass fractionation as a function of the radial target position. This fractionation was measured using Ne released by UV laser ablation and compared with modelled Ne data, obtained from ion-trajectory simulations. Measured data show that the concentrator performed as expected and indicate a radially symmetric concentration process. Measured concentration factors are up to ∼30 at the target centre. The total range of isotopic fractionation along the target radius is 3.8%/amu, with monotonically decreasing 20Ne/22Ne towards the centre, which differs from model predictions. We discuss potential reasons and propose future attempts to overcome these disagreement
Adsorption of para-Hydrogen on Krypton pre-plated graphite
Adsorption of para-Hydrogen on the surface of graphite pre-plated with a
single layer of atomic krypton is studied thoretically by means of Path
Integral Ground State Monte Carlo simulations. We compute energetics and
density profiles of para-hydrogen, and determine the structure of the adsorbed
film for various coverages. Results show that there are two thermodynamically
stable monolayer phases of para-hydrogen, both solid. One is commensurate with
the krypton layer, the other is incommensurate. No evidence is seen of a
thermodynamically stable liquid phase, at zero temperature. These results are
qualitatively similar to what is seen for for para-hydrogen on bare graphite.
Quantum exchanges of hydrogen molecules are suppressed in this system.Comment: 12 pages, 6 figures, to appear in the proceedings of "Advances in
Computational Many-Body Physics", Banff, Alberta (Canada), January 13-16 200
"Because it is the Right Thing to Do'': Taking Stock of the Peer Reviewers’ Openness Initiative
Forces between electric charges in motion: Rutherford scattering, circular Keplerian orbits, action-at-a-distance and Newton's third law in relativistic classical electrodynamics
Standard formulae of classical electromagnetism for the forces between
electric charges in motion derived from retarded potentials are compared with
those obtained from a recently developed relativistic classical electrodynamic
theory with an instantaneous inter-charge force. Problems discussed include
small angle Rutherford scattering, Jackson's recent `torque paradox' and
circular Keplerian orbits. Results consistent with special relativity are
obtained only with an instantaneous interaction. The impossiblity of stable
circular motion with retarded fields in either classical electromagnetism or
Newtonian gravitation is demonstrated.Comment: 26 pages, 5 figures. QED and special relativity forbid retarded
electromagnetic forces. See also physics/0501130. V2 has typos corrected,
minor text modifications and updated references. V3 has further typos removed
and added text and reference
13C labeling experiments at metabolic nonstationary conditions: An exploratory study
<p>Abstract</p> <p>Background</p> <p>Stimulus Response Experiments to unravel the regulatory properties of metabolic networks are becoming more and more popular. However, their ability to determine enzyme kinetic parameters has proven to be limited with the presently available data. In metabolic flux analysis, the use of <sup>13</sup>C labeled substrates together with isotopomer modeling solved the problem of underdetermined networks and increased the accuracy of flux estimations significantly.</p> <p>Results</p> <p>In this contribution, the idea of increasing the information content of the dynamic experiment by adding <sup>13</sup>C labeling is analyzed. For this purpose a small example network is studied by simulation and statistical methods. Different scenarios regarding available measurements are analyzed and compared to a non-labeled reference experiment. Sensitivity analysis revealed a specific influence of the kinetic parameters on the labeling measurements. Statistical methods based on parameter sensitivities and different measurement models are applied to assess the information gain of the labeled stimulus response experiment.</p> <p>Conclusion</p> <p>It was found that the use of a (specifically) labeled substrate will significantly increase the parameter estimation accuracy. An overall information gain of about a factor of six is observed for the example network. The information gain is achieved from the specific influence of the kinetic parameters towards the labeling measurements. This also leads to a significant decrease in correlation of the kinetic parameters compared to an experiment without <sup>13</sup>C-labeled substrate.</p
Action at a distance as a full-value solution of Maxwell equations: basis and application of separated potential's method
The inadequacy of Li\'{e}nard-Wiechert potentials is demonstrated as one of
the examples related to the inconsistency of the conventional classical
electrodynamics. The insufficiency of the Faraday-Maxwell concept to describe
the whole electromagnetic phenomena and the incompleteness of a set of
solutions of Maxwell equations are discussed and mathematically proved. Reasons
of the introduction of the so-called ``electrodynamics dualism concept"
(simultaneous coexistence of instantaneous Newton long-range and
Faraday-Maxwell short-range interactions) have been displayed. It is strictly
shown that the new concept presents itself as the direct consequence of the
complete set of Maxwell equations and makes it possible to consider classical
electrodynamics as a self-consistent and complete theory, devoid of inward
contradictions. In the framework of the new approach, all main concepts of
classical electrodynamics are reconsidered. In particular, a limited class of
motion is revealed when accelerated charges do not radiate electromagnetic
field.Comment: ReVTeX file, 24pp. Small corrections which do not have influence
results of the paper. Journal reference is adde
Analysis of lead oxide (PbO) layers for direct conversion X-ray detection
Lead oxide (PbO) is a candidate direct conversion material for medical X-ray applications. We produced various samples and detectors with thick PbO layers. X-ray performance data such as dark current, charge generation yield and temporal behavior were evaluated on small samples. The influence of the metal contacts was studied in detail. We also covered large a-Si thin-film transistor (TFT)-plates with PbO. Imaging results from a large detector with an active area of 18 cm × 20 cm are presented. The detector has 960 × 1080 pixels with a pixel pitch of 184 ?m. The modulation transfer function at the Nyquist frequency of 2.72 linepairs/mm is 50%. Finally, a full size X-ray image is presented
Quantum Fluctuations Driven Orientational Disordering: A Finite-Size Scaling Study
The orientational ordering transition is investigated in the quantum
generalization of the anisotropic-planar-rotor model in the low temperature
regime. The phase diagram of the model is first analyzed within the mean-field
approximation. This predicts at a phase transition from the ordered to
the disordered state when the strength of quantum fluctuations, characterized
by the rotational constant , exceeds a critical value . As a function of temperature, mean-field theory predicts a range of
values of where the system develops long-range order upon cooling, but
enters again into a disordered state at sufficiently low temperatures
(reentrance). The model is further studied by means of path integral Monte
Carlo simulations in combination with finite-size scaling techniques,
concentrating on the region of parameter space where reentrance is predicted to
occur. The phase diagram determined from the simulations does not seem to
exhibit reentrant behavior; at intermediate temperatures a pronounced increase
of short-range order is observed rather than a genuine long-range order.Comment: 27 pages, 8 figures, RevTe
Quantum melting of incommensurate domain walls in two dimensions
Quantum fluctuations of periodic domain-wall arrays in two-dimensional
incommensurate states at zero temperature are investigated using the elastic
theory in the vicinity of the commensurate-incommensurate transition point.
Both stripe and honeycomb structures of domain walls with short-range
interactions are considered. It is revealed that the stripes melt and become a
stripe liquid in a large-wall-spacing (low-density) region due to dislocations
created by quantum fluctuations. This quantum melting transition is of second
order and characterized by the three-dimensional XY universality class.
Zero-point energies of the stripe and honeycomb structures are calculated. As a
consequence of these results, phase diagrams of the domain-wall solid and
liquid phases in adsorbed atoms on graphite are discussed for various
domain-wall masses. Quantum melting of stripes in the presence of long-range
interactions that fall off as power laws is also studied. These results are
applied to incommensurate domain walls in two-dimensional adsorbed atoms on
substrates and in doped antiferromagnets, e.g. cuprates and nickelates.Comment: 11 pages, 5 figure
Ba3Ga3N5 - A Novel Host Lattice for Eu2+ - Doped Luminescent Materials with Unexpected Nitridogallate Substructure
The alkaline earth nitridogallate Ba3Ga3N5 was synthesized from the elements in a sodium flux at 760°C utilizing weld shut tantalum ampules. The crystal structure was solved and refined on the basis of single-crystal X-ray diffraction data. Ba3Ga3N5 (space group C2/c (No. 15), a = 16.801(3), b = 8.3301(2), c = 11.623(2) Å, β = 109.92 (3)°, Z = 8) contains a hitherto unknown structural motif in nitridogallates, namely, infinite strands made up of GaN4 tetrahedra, each sharing two edges and at least one corner with neighboring GaN4 units. There are three Ba2+ sites with coordination numbers six or eight, respectively, and one Ba2+ position exhibiting a low coordination number 4 corresponding to a distorted tetrahedron. Eu2+ - doped samples show red luminescence when excited by UV irradiation at room temperature. Luminescence investigations revealed a maximum emission intensity at 638 nm (FWHM =2123 cm−1). Ba3Ga3N5 is the first nitridogallate for which parity allowed broadband emission due to Eu2+ - doping has been found. The electronic structure of both Ba3Ga3N5 as well as isoelectronic but not isostructural Sr3Ga3N5 was investigated by DFT methods. The calculations revealed a band gap of 1.53 eV for Sr3Ga3N5 and 1.46 eV for Ba3Ga3N5
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