1,553 research outputs found
Impact of variable loading conditions on fretting wear
Fretting is considered as a specific type of reciprocating sliding. It is defined as a small displacement amplitude oscillatory motion between two solids in contact, usually induced by vibrations. Depending on the loading conditions (displacement amplitudes, normal loading), fretting causes damage by surface fatigue and wear induced by debris formation. To prevent such damage, numerous hard coatings have been developed which improve the wear resistance of contacts. However, one difficulty is to estimate how long it will be before the coating wears through. Studies have been conducted to analyze the effect of displacement amplitude, normal force or ambient atmosphere, but usually under constant loading conditions. Such a situation is far from real operating components, where elements are subjected to variable loadings implying variable displacement amplitudes. To predict the durability of a coating under variable fretting displacements, wear depth is quantified as a function of the maximum accumulated dissipated energy density by derivation from a global energy wear approach. This model is compared to TiC vs. alumina fretting experiments. Very good correlation is observed between the prediction and the wear depth, independently of the applied variable amplitude sequences. An equivalent “Miner-Energy” wear model is introduced which permits the durability of the coating to be estimated
Fretting wear of TiN PVD coating under variable relative humidity conditions – development of a “composite” wear law
Fretting is defined as a small oscillatory displacement between two contacting bodies. The
interface is damaged by debris generation and its ejection from the contact area. The
application of hard coatings is an established solution to protect against fretting wear. For this
study the TiN hard coating manufactured by a PVD method has been selected, and tested
against a polycrystalline alumina smooth ball. A fretting test programme has been carried out
at a frequency of 5 Hz, 100 N normal load, 100 μm displacement amplitude and at five values
of relative humidity: 10, 30, 50, 70 and 90% at a temperature of 296 K. The intensity of the
wear process is shown to be significantly dependent on the environmental conditions. A
dissipated energy approach has been employed in this study to quantify wear rates of the hard
coating. The approach predicts wear kinetics under constant medium relative humidity in a
stable manner. It has been shown that an increase of relative humidity promotes the formation
of hydrate structures at the interface and modifies the third body rheology. This phenomenon
has been characterised by the evolution of wear kinetics associated with a significant variation
of the corresponding energy wear coefficient. Hence, a ‘composite’ wear law, integrating the
energy wear coefficient as a function of relative humidity, is introduced. It permits a
prediction of wear under variable relative humidity conditions from 10 to 90% within a single
fretting test. The stability of this approach is demonstrated by comparing various variable
relative humidity sequences
Development of a Wöhler-like approach to quantify the Ti(CxNy) coatings durability under oscillating sliding conditions
The selection of a proper material for the particular engineering application is a complex problem, as different materials offer unique properties and it is not possible to gather all useful characteristics in a single one. Hence, employment of different surface treatment processes is a widely used alternative solution. In many industrial applications, coating failure may be conducive to catastrophic consequences. Thus, to prevent the component damage it is essential to establish the coating endurance and indicate the safe running time of coated system. To this study PVD TiC, TiN and TiCN hard coatings have been selected and tested against polycrystalline alumina smooth ball. The series of fretting tests with reciprocating sliding at the frequency 5Hz have been carried out under 50-150N normal loads and under wide rage of constant as well as variable displacement amplitudes from 50µm to 200µm at a constant value of relative humidity of 50% at 296K temperature. To quantify the loss of material a dissipated energy approach has been applied where the wear depth evolution is referred to the cumulative density of friction work dissipated during the test. Different dominant damage mechanisms have been indicated for the investigated hard coatings, which is debris formation and ejection in case of TiC coating and progressive wear accelerated by cracking phenomena in case of TiN and TiCN coatings. Energy-Wöhler wear chart has been introduced, in which the critical 1 dissipated energy density corresponds to the moment when the substrate is reached after a given number of fretting cycles. Two different methods to determine the critical dissipated energy density are introduced and compared. The Energy-Wöhler approach has been employed not only to compare the global endurance of the investigated systems but also to compare the intrinsic wear properties of the coatings. It has been shown that the fretting wear process is accelerated by the stress-controlled spalling phenomenon below a critical residual thickness and a severe decohesion mechanism is activated. Finally the applicability of the investigated method to other coated systems subjected to wear under sliding conditions is discussed and analyzed. The perspectives of this new approach are elucidated
Order-disorder transition in nanoscopic semiconductor quantum rings
Using the path integral Monte Carlo technique we show that semiconductor
quantum rings with up to six electrons exhibit a temperature, ring diameter,
and particle number dependent transition between spin ordered and disordered
Wigner crystals. Due to the small number of particles the transition extends
over a broad temperature range and is clearly identifiable from the electron
pair correlation functions.Comment: 4 pages, 5 figures, For recent information on physics of small
systems see http://www.smallsystems.d
Optical Response of Grating-Coupler-Induced Intersubband Resonances: The Role of Wood's Anomalies
Grating-coupler-induced collective intersubband transitions in a
quasi-two-dimensional electron system are investigated both experimentally and
theoretically. Far-infrared transmission experiments are performed on samples
containing a quasi-two-dimensional electron gas quantum-confined in a parabolic
quantum well. For rectangular shaped grating couplers of different periods we
observe a strong dependence of the transmission line shape and peak height on
the period of the grating, i.e. on the wave vector transfer from the diffracted
beams to the collective intersubband resonance. It is shown that the line shape
transforms with increasing grating period from a Lorentzian into a strongly
asymmetric line shape. Theoretically, we treat the problem by using the
transfer-matrix method of local optics and apply the modal-expansion method to
calculate the influence of the grating. The optically uniaxial
quasi-two-dimensional electron gas is described in the long-wavelength limit of
the random-phase approximation by a local dielectric tensor, which includes
size quantization effects. Our theory reproduces excellently the experimental
line shapes. The deformation of the transmission line shapes we explain by the
occurrence of both types of Wood's anomalies.Comment: 28 pages, 7 figures. Physical Review B , in pres
Energy levels and far-infrared spectroscopy for two electrons in a semiconductor nanoring
The effects of electron-electron interaction of a two-electron nanoring on
the energy levels and far-infrared (FIR) spectroscopy have been investigated
based on a model calculation which is performed within the exactly numerical
diagonalization. It is found that the interaction changes the energy spectra
dramatically, and also shows significant influence on the FIR spectroscopy. The
crossings between the lowest spin-singlet and triplet states induced by the
coulomb interaction are clearly revealed. Our results are related to the
experiment recently carried out by A. Lorke et al. [Phys. Rev. Lett. 84, 2223
(2000)].Comment: 17 pages, 6 figures, revised and accepted by Phys. Rev. B (Dec. 15
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Extracellular vesicles swarm the cancer microenvironment: from tumor–stroma communication to drug intervention
Intercellular communication sets the pace for transformed cells to survive and to thrive. Extracellular vesicles (EVs), such as exosomes, microvesicles and large oncosomes, are involved in this process shuttling reciprocal signals and other molecules between transformed and stromal cells, including fibroblasts, endothelial and immune cells. As a result, these cells are adapted or recruited to a constantly evolving cancer microenvironment. Moreover, EVs take part in the response to anticancer therapeutics not least by promoting drug resistance throughout the targeted tumor. Finally, circulating EVs can also transport important molecules to remote destinations in order to prime metastatic niches in an otherwise healthy tissue. Although the understanding of EV biology remains a major challenge in the field, their characteristics create new opportunities for advances in cancer diagnostics and therapeutics
Predictors of olfactory improvement after endoscopic sinus surgery in chronic rhinosinusitis with nasal polyps
Objective. This study aimed to determine the predictors of olfactory improvement after endoscopic sinus surgery among patients with chronic rhinosinusitis with nasal polyps.
Method. This prospective cohort study included patients admitted to a university hospital between 2006 and 2012. Assessment using odour identification testing, a sinonasal symptom questionnaire, the Rhinosinusitis Disability Index and mucus biomarker levels was performed at various time points. Correlation of variables with identification score differences at six postoperative time points and at baseline was performed, followed by multiple linear regression to determine significant predictors at each of the six post-operative time points.
Results. Baseline absence of acute sinusitis, elevated serpin F2 and anterior rhinorrhoea predict early olfactory improvement, whereas baseline allergic rhinitis predicts late olfactory improvement. Baseline odour identification score was the strongest predictor across all time points. Conclusion. Patients with chronic rhinosinusitis and nasal polyps with worse disease or baseline olfactory function may benefit more from endoscopic sinus surgery in terms of olfactory improvement
Gamow Shell Model Description of Neutron-Rich Nuclei
This work presents the first continuum shell-model study of weakly bound
neutron-rich nuclei involving multiconfiguration mixing. For the
single-particle basis, the complex-energy Berggren ensemble representing the
bound single-particle states, narrow resonances, and the non-resonant continuum
background is taken. Our shell-model Hamiltonian consists of a one-body finite
potential and a zero-range residual two-body interaction. The systems with two
valence neutrons are considered. The Gamow shell model, which is a
straightforward extension of the traditional shell model, is shown to be an
excellent tool for the microscopic description of weakly bound systems. It is
demonstrated that the residual interaction coupling to the particle continuum
is important; in some cases, it can give rise to the binding of a nucleus.Comment: 4 pages, More realistic s.p. energies used than in the precedent
versio
Cryo-EM structures reveal intricate Fe-S cluster arrangement and charging in Rhodobacter capsulatus formate dehydrogenase
Metal-containing formate dehydrogenases (FDH) catalyse the reversible oxidation of formate to carbon dioxide at their molybdenum or tungsten active site. They display a diverse subunit and cofactor composition, but structural information on these enzymes is limited. Here we report the cryo-electron microscopic structures of the soluble Rhodobacter capsulatus FDH (RcFDH) as isolated and in the presence of reduced nicotinamide adenine dinucleotide (NADH). RcFDH assembles into a 360 kDa dimer of heterotetramers revealing a putative interconnection of electron pathway chains. In the presence of NADH, the RcFDH structure shows charging of cofactors, indicative of an increased electron load
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